气相色谱—质谱法测定蒸馏出的混合物中硼酸三甲酯

硼酸三甲酯是合成储氢材料硼氢化钠的重要原料,以硼酸、甲醇为原料合成硼酸三甲酯是目前硼酸三甲酯合成的重要方法之一。提供了一种测定硼酸、甲醇合成硼酸三甲酯蒸馏混合物中硼酸三甲酯成分、含量的测定方法,即气相色谱一质谱法(GC-MS)。该方法简单、快捷、准确。确定了优化的GC-MS测定条件,适合不同合成条件下蒸馏后混合物中硼酸三甲酯的定性、定量。测定结果表明,该方法对同一条件下合成混合物中硼酸三甲酯做测定分析,加标回收率在91.8%¹00.5%,相对标准偏差1.9%100.5%,相对标准偏差1.9%⁴.1%,检出限3.64 mg/mL。通过对16组不同工艺合成条件下混合物中硼酸三甲酯的测定分析,该方法重复性较好,较为稳定,对硼酸三甲酯检测分析具有重要意义。     

Suspended sediment load in the turbidity maximum zone at the Yangtze River Estuary:The trends and causes简

Based on the analysis of suspended sediment elements at estuaries, influence of human activities and estuarine regulation projects on the turbidity maximum zone was studied according to the measurement data between 1959 and 2011. It was found that human activi- ties had little effect on the seaward water while the sharp decrease of sediment volume and concentration in runoff led to the sharp decrease of turbidity maximum zone in the estuary. The concentration at outside sea and Hangzhou Bay did not change, and that along the Subei coast also decreased a little, which had no influence on the turbidity maximum zone. Com- pared with the concentration between 1959 and 1999, the peak of concentration moved up- stream in the estuary, and the concentration in 2000-2009 decreased by about 24.73% with a narrower variation range along the river to the sea. The suspended sediment concentration in North Passage was low in upstream and downstream because of the decrease of seaward sediment and coarsening of bed material, while it was relatively high in the middle due to the influence of sediment cross the north jetty.     

地质雷达在岩溶地区岩土工程勘察中的应用

安徽省沿江及皖南一带石灰岩分布广泛,岩溶发育,由于岩溶溶洞具有隐伏性强、空间分布规律性差、岩溶塌陷难以预测等特点,因此岩溶区岩土工程勘察必需查清岩溶发育规律。本文结合铜陵一带岩溶区岩土工程勘察中几个实例,阐述在岩溶发育区,采用地质雷达结合钻探综合勘察方法,高效准确查清构筑物基础范围内岩溶溶洞发育情况,提高岩溶区勘察效益和勘察进度。     

A fuzzy topology-based maximum likelihood classification

Classification is one of the most widely used remote sensing analysis techniques, with the maximum likelihood classification (MLC) method being a major tool for classifying pixels from an image. Fuzzy topology, in which the set concept is generalized from two values, {0, 1}, to the values of a continuous interval, [0, 1], is a generalization of ordinary topology and is used to solve many GIS problems, such as spatial information management and analysis. Fuzzy topology is induced by traditional thresholding and as such gives a decomposition of MLC classes.Presented in this paper is an image classification modification, by which induced threshold fuzzy topology is integrated into the MLC method (FTMLC). Hence, by using the induced threshold fuzzy topology, each image class in spectral space can be decomposed into three parts: an interior, a boundary and an exterior. The connection theory in induced fuzzy topology enables the boundary to be combined with the interior. That is, a new classification method is derived by integrating the induced fuzzy topology and the MLC method. As a result, fuzzy boundary pixels, which contain many misclassified and over-classified pixels, are able to be re-classified, providing improved classification accuracy. This classification is a significantly improved pixel classification method, and hence provides improved classification accuracy.     

地图自动着色算法研究与实践

从四色问题的抽象模型入手,通过对现有的搜索算法——遗传算法、模拟退火算法这两种算法的原理和流程进行了较为细致的分析,总结出它们在地图四色填充实现过程中的优点与不足之处,并进行比较,找出这两种算法的结合点进行算法的改进优化,将模拟退火算法引入遗传算法,使它们结合起来解决地图四色填充问题,从而形成相对优化的算法,以期达到更加优化的效果。     

基于空域最小二乘法求解GOCE卫星重力场的模拟研究

本文论述了最小二乘过程中有色噪声的处理方法,提出使用AR模型对GOCE梯度观测值中的有色噪声进行时域滤波,数值模拟结果验证了该方法的有效性。利用数值模拟验证了直接求逆方法和PCCG法求解大型法方程的有效性,后者的效率远远高于前者。联合加入噪声（有色噪声和白噪声）的卫星重力梯度张量径向分量观测值Vzz和SST观测值,分别使用空域最小二乘法和SA方法恢复了180阶全球重力场模型,前者求解重力场模型的大地水准面和重力异常在180阶次的精度分别为3.01cm和0.75mGal,优于SA方法求解模型的精度。     

Selecting the appropriate hydraulic model structure using low-resolution satellite imagery

This study aims at investigating the value added by an explicit representation of floodplain processes in hydraulic models, by comparing the results of a pure 1D model to the ones of an integrated 1D-2D model. The analysis is performed on a 96 km reach of the River Po (Italy). For this test site, two different model structures (1D and 1D-2D) are implemented and compared. The models are first calibrated using high water marks of a high magnitude event and then validated by means of a coarse resolution space-borne flood extent map of a low-magnitude event. The explicit inclusion of 2D features strongly improves the performance of the model, both in terms of accuracy and robustness. The possible causes of this behaviour are investigated and some statements are drawn based on the analysis of the features of the two flood events. Some general conclusions on the effect of the choice between 1D and 2D models arise from the analysis of the calibration-validation procedure. In this context a new measure of fit is proposed, to be used if binary (wet/dry) observations are available and is proven to be able to better distinguish among different sets of model parameters. Lastly, the study also shows the ability of timely low resolution satellite imagery to assist the selection of the most appropriate hydraulic model structure.     

考虑人体舒适度的大型火车站房楼盖振动控制研究

近年来,各地纷纷兴建大型火车站房,这类建筑中的楼盖大多为大跨、轻质和低阻尼结构,本文基于人体舒适度考虑,对这些大跨楼盖进行振动舒适度的分析。首先,建立某大型火车站房的整体有限元模型,研究这类建筑中大跨楼盖的振动特性;随后,对楼盖在各种不利工况人群荷载作用下的振动舒适度进行分析;最后,在已有研究的基础上,提出了大跨楼盖多重调谐质量阻尼器（Multiple Tuned Mass Dampers,简称MTMD）减振设计方法。结果表明,利用该方法设计MTMD减振系统,可以有效地控制大跨楼盖的竖向振动,各工况下的平均减振率可达34%,从而使结构在使用时满足人体舒适度的要求。     

基于阻尼器反力墙体系的特大型LNG储罐控制研究

特大型液化天然气（LNG）储罐的固有频率通常介于2~10 Hz之间,处于大部分地震运动的频率范围之内。在过去的几十年中,许多事故已经证明,储罐在地震作用下很容易遭破坏。使用隔震支座来减少储罐的地震作用已经被证明是非常有效的,但对于特大型LNG储罐,其连接组件对隔震层层间位移有严格限制,尤其是在软土场地中,桩水平抗力与隔震层位移是一对矛盾,普通隔震系统会在隔震层产生较大位移,导致特大型LNG储罐连接组件的设计非常困难。因此提出了一种由环形阻尼器反力墙、粘滞阻尼器以及安装于基桩顶端的隔震支座组成的新型隔震系统,反力墙独立设置于地基中,不与桩基连接,罐底的部分剪力直接向反力墙传递。以容量为16万m3的特大型LNG储罐为例,建立多自由度集中质量简化模型,以层间位移、桩基剪力作为性能指标进行了评价分析。结果显示,新型隔震系统对特大型LNG储罐隔震层位移及桩基剪力的控制非常有效。     

大渡河干海子滑坡稳定性研究

干海子滑坡位于大渡河流域,规模巨大。为研究该滑坡的稳定性,在对滑坡基本特征及变形破坏特征等深入研究的基础上,采用极限平衡法（Geo-slope软件）和有限差分法（FLAC-3D软件）对该滑坡的稳定性和应力应变特征进行了计算、模拟。稳定性计算模拟主要从深层、浅层及局部稳定三方面入手分析,计算模拟结果与滑坡的宏观地质现象均具有较高的吻合度。通过对该滑坡定性与定量的稳定性分析,判断其浅层滑体在暴雨工况下将处于极限平衡状态,而深层滑体在地震工况下依旧处于基本稳定状态,所得结论为下一步滑坡防治工作提供了翔实的依据。