A Three—Stage Metallogenic Model for Gold Deposits in Metamorphosed Microclastic Rocks

Gld deposits occurring in metamorphosed microcelastic rocks are distributed extensively at home and abroad.Some deposits of this type are of superlarge tonnage.The formation of gold deposits in metamorphosed microclastic rocks involves three stages:the sedimentary stage,the regionally metamorphic stage,and the ore-forming stage.At the first stage,microclastic sedimentary source rocks were developed in a relatively semi-enclosed reducing sea basin and were enriched in carbon,sulfur and gold.At the second stage,the gold adsorbed on organic matter and clay minerals was relesed and poorly concentrated during the destruction of organic matter and the depletion of clay minerals by regional metamorphism with increase temperature and pressure.At the third stage,a tectono-hydrothermal event took place.As a result,gold was leached from metamorphosed microclastic rocks,transported to ore depositional locus and/or mixed with gold of other sources in the course of migration,and finally precipitared as ores.Gold deposits of this type were eventually formed at the third stage,and they also can be classified as the orogenic belt type and the activation zone type.The gold deposits occurring in metamorphosed microcalastic rocks are the products of reworking processes and the influence of magmatism should be taken into consideration in some cases.     

甜水海地块晚寒武世花岗岩对原特提斯洋演化的启示：来自锆石年代学和地球化学的证据

笔者在甜水海地块中部麻扎地区新发现了晚寒武世花岗岩,并命名为苦鲁勒岩体。LA-ICP-MS锆石U-Pb定年表明其形成年龄为500.7±1.1~498.7±1.4Ma,属晚寒武世岩浆活动的产物。该花岗岩中无角闪石和白云母,具有高SiO_2(73.49%~77.47%)、中高K_2O(1.88%~4.14%)、低P_2O_5(0.02%~0.05%)的特征,铝饱和指数(A/CNK)为0.98~1.12;稀土总量偏高(∑REE=66.81×10~(-6)~135.43×10~(-6)),轻重稀土的分馏程度中等[(La/Yb)_N介于3.86~7.98之间,(La/Sm)_N介于3.46~4.22之间)],Eu具有明显负异常(δEu=0.35~0.66);微量元素以富集Rb、Th、U、K,亏损Nb、Ta、P、Ti、Sr为特征,属于准铝质到弱过铝质高分异I型花岗岩类。岩体中发育的辉绿岩、闪长岩暗色包体以及结合成岩过程判别图解,表明在苦鲁勒岩体的形成过程中可能有幔源物质的加入,很可能是岩浆经历了显著的基性岩浆混合事件后的结果。结合区域研究成果,认为苦鲁勒岩体很可能形成于原特提斯洋向南俯冲消减机制下的岩浆弧构造环境,推测在早古生代原特提斯洋存在双向俯冲。     

朝鲜半岛冠帽地块的基底属性:来自银德洞变质侵入杂岩的锆石U-Pb年代学和岩石地球化学证据

地体基底建造的甄别和表征是联结华北克拉通与朝鲜半岛早期演化历史的基本纽带。针对朝鲜半岛前寒武纪基底建造研究方面的薄弱环节,本文表征了冠帽地块清津地区银德洞出露的变质深成侵入杂岩。3个代表性样品的SIMS锆石U-Pb定年结果显示,早期中性片麻岩记录的岩浆侵入年龄为约2.53 Ga,晚期钾长花岗质片麻岩记录的岩浆侵入年龄为约2.51 Ga,表明银德洞变质杂岩形成于新太古代晚期。参考变质杂岩的岩石地球化学特征,其原岩组成可能包括石英闪长岩和钾长花岗岩,大体上可与全球典型的岩浆型紫苏花岗岩系列相类比。结合3个样品变化较大的锆石εH f(t)值(-1.7~+10.5),我们推测银德洞变质侵入杂岩可能形成于玄武质下地壳岩石的部分熔融及其后的结晶分异作用,代表了活动大陆边缘岩浆弧环境下的典型产物。银德洞变质杂岩归属于新太古代岩浆弧根部岩浆岩建造的研究认识,不仅为判定冠帽地块与华北克拉通东部的吉南和龙地块以及辽北清原地块之间的亲缘性提供了岩石学证据,而且暗示这些地块在新太古代共同处在一个类似于安第斯活动大陆边缘的构造环境。     

聚酰胺树脂富集分离—原子吸收法测定地质样品中钯

拟定了以聚酰胺树脂为吸附剂在静态和动态操作条件下，对微量钯的选择性吸附分离方法。实验表明，树脂在0.001-2.0mol/L的HCl介质中，对钯的吸附性能很好，饱和吸附容量为19.22-12.88mg/g，平均吸附率为98.40%，吸附到树脂中的钯可用中性30g/L硫脲溶液（静态)和50g/L 硫脲溶液（动态）解脱，平均解脱率为96.95%，富集倍数可达100倍。结合原子吸收光度法，可用于矿石中微量钯的富集分离和测定，标准加入回收试验，回收率为96.0%-103.0%，标样分离结果与推荐值相符。     

Early to Middle Jurassic (ca. 182–164 Ma) fractionated granitoids in the Korean Peninsula: Implication for the tectonomagmatic history of East Asia

The Jurassic granitoids (200–164 Ma) are distributed in the Korean Peninsula due to the Paleo-Pacific plate subduction. Early Jurassic (200–182 Ma) granitoids are mainly distributed in the southern Korean Peninsula. By contrast, Early to Middle Jurassic (182–164 Ma) granitoids are distributed in the central Korean Peninsula. In this study, we report detailed petrology, zircon U–Pb ages, and whole-rock geochemistry from the Seoul–Uijeongbu and Pocheon–Gimhwa pluton units in the central Korean Peninsula. The Seoul–Uijeongbu unit is dominated by biotite granite, with minor porphyritic biotite and garnet-biotite granite while the Pocheon–Gimhwa unit consists of biotite granite and porphyritic biotite granite, garnet-biotite granite, and two-mica granite. Zircon U–Pb age from those granites gives 180–167 Ma. The granitoids in the Pocheon-Gimhwa unit formed through fractional crystallization from biotite granite and porphyritic biotite granite to garnet-biotite granite, and two-mica granite based on gradually decreasing their Nb/Ta, Zr/Hf, and Eu/Eu* ratios. The strongly fractionated granitoids are garnet-biotite granite and two-mica granite. The LILE enrichment, Ta–Nb, Sr–P, and Eu–Ti troughs, and Ba depletion in most granitoids are similar to those of granitoids due to the subduction in the arc environment. Thus, these Jurassic granitoids (180–167 Ma) are mainly peraluminous granites with moderate crystal fractionation corresponding to I-type granite. Alkali feldspar granite associated with ore mineralization occurs in the Gwanaksan pluton from the southwestern Seoul–Uijeongbu unit. The alkali feldspar granite displays distinct negative Eu anomaly with high contents of Rb, Hf, Cs, and Nb compared with other granites. These characteristics imply that alkali feldspar granite experienced strong hydrothermal activity leading to feldspar ore mineralization compared to the other granites. The formation of a wide range of moderately evolved peraluminous granitoids is presumed to be related to rapid flat-subduction during 182–164 Ma, and the mineralization-related alkali feldspar granite indicates the termination of Jurassic granitoid magmatism in the central Korean Peninsula.