Assessment of potential transport of pollutants into the Barents Sea via sea ice--an observational approach

The present estimates of ice drift in the Arctic include utilization of satellite imagery data (special sensor microwave/imager) and a reconstruction of air pressure for the period 1899-1998. A significant part of the sea ice in the Arctic Ocean has its origin in the Kara Sea and melts in the Greenland and the Barents Sea (BS). Consequently there may be a particular risk of pollutants in the Kara Sea entering the food webs of the Greenland and BS. The ice export from the Kara Sea between 1988 and 1994 was about 208,000 km2 (154 km3) per year. The import of ice into the BS was during the same period 161,000 km2 (183 km3) per year while the ice drift through the Fram Strait into the Greenland Sea was 583,000 km2 (1859 km3) per year. Ice which formed adjacent to the Ob and Yenisey rivers in early January, drifted into the BS within two years (with a probability of about 50%.     

胜利油田火山岩辉石中岩浆包裹体成分及有关成因问题

对胜利油田火山岩中辉石及其中岩浆包裹体成分的研究表明：ＣＯ２气藏区和非ＣＯ２气藏区新生代火山岩辉石及其中岩浆包裹体成分有明显区别,前者中辉石为普通辉石,成分相对富ＳｉＯ２,而贫Ａｌ２Ｏ３、ＴｉＯ２、ＭｇＯ和挥发成分;而后者中辉石为透辉石,成分相对贫ＳｉＯ２和挥发份,而富Ａｌ２Ｏ３、ＴｉＯ２和ＭｇＯ。前者岩浆包裹体玻相中富含ＣＯ２,包裹体中的金属子矿物多为黄铁矿;而后者岩浆包裹体玻相中贫ＣＯ２;包裹     

西藏冈底斯带侏罗纪岩浆作用的时空分布 及构造环境

在新近完成的1：25万区域地质调查资料和相关研究成果的基础上,初步研究了西藏冈底斯带侏罗纪岩浆作用的分布特点及其年代学,并利用已有的地球化学数据重点分析了早期关注程度较低的侏罗纪花岗岩类岩浆作用的性质。目前在冈底斯弧背断隆带未发现侏罗纪火山岩;在冈底斯东部地区,早侏罗世岩浆活动几乎同时发生于南冈底斯（叶巴组火山岩和鸟郁、尼木花岗岩类）、冈底斯弧背断隆带（宁中、金达、布久花岗岩类）和北冈底斯（聂荣花岗岩类）,中晚侏罗世接奴群和拉贡塘组火山岩断续分布于北冈底斯,晚侏罗世岩浆活动零星分布于沙莫勒一麦拉一洛巴堆～米拉山断裂以北。将冈底斯侏罗纪岩浆活动置于时空框架内分析发现,南冈底斯和北冈底斯在侏罗纪时主要受俯冲作用的影响．而冈底斯弧背断隆带和中冈底斯自早侏罗世以来除了受到俯冲作用的影响外,还受到自东向西逐步扩展的碰撞作用的影响。结合古地磁重建资料和其他新发现．认为冈底斯带侏罗纪这种岩浆活动的特点可用班公湖一怒江洋壳向南、新特提斯洋壳向北的双向剪刀式（剪刀口向西张开）俯冲模式来解释。     

盐酸普鲁卡因诱导下海洋真菌Hypocrea lixii次级代谢化学成分

【目的】通过化学诱导方法从一株海洋真菌Hypocrea lixii中获得多样化的活性小分子化合物。【方法】对菌株在盐酸普鲁卡因的化学诱导作用下进行固体发酵,代谢产物采用硅胶减压柱层析、Sephadex LH-20以及pHPLC等手段分离纯化,对化合物运用NMR、MS等波谱学技术并比对文献进行结构鉴定,采用Ellman比色法及DPPH自由基清除法对化合物进行初步抗乙酰胆碱酯酶(AChE)和抗氧化活性测试。【结果】从海洋真菌Hypocrea lixii在盐酸普鲁卡因诱导下的发酵提取物中分离得到4个异黄酮类化合物,包括6'-O-crotonylgenistin(1)、Genistein(2)、Daidzein(3)和Genistin(4),以及对氨基苯甲酸甲酯(5)、对羟基苯丙酸(6)和胞嘧啶(7),其中化合物1和6为该种中首次报道,化合物5为生物转化来源首次报道,化合物2~4可能源自培养基。在100μmol/L剂量浓度下,化合物1~4对AChE的抑制以及DPPH自由基的清除活性均较弱,化合物5和6显示了相对强的AChE抑制活性,抑制率分别为40%和38%。【结论】盐酸普鲁卡因对该菌次级代谢产生了显著的影响,为深入研究该菌株化学诱导次级代谢产物提供基础。     

Chronology and Geochemistry of Volcanic Rocks in the Cretaceous Suifenhe Formation in Eastern Heilongjiang, China

Zircon U-Pb ages and geochemical data of volcanic rocks in the Suifenhe Formation in eastern Heilongjiang Province are reported, and their petrogenesis is discussed in this paper. The Suifenhe Formation mainly consists of basalt, andesite, and dacite. Zircon from andesite and dacite are euhedral in shape and show typical oscillatory zoning with high Th/U ratios (0.18-0.57), implying its magmatic origin. Zircon U-Pb dating results by laser ablation inductively coupled plasma mass spectrometer (LA-ICP-MS) indicate that the 206Pb/238U ages of zircons from andesite range within 105-106 Ma, yielding a weighted mean age of 105.5±0.8 Ma (n=14), and that 206Pb/238U ages of zircons from dacite are between 90-96 Ma, yielding a weighted mean age of 93.2±1.3 Ma (n =13). The volcanic rocks from the Suifenhe Formation are subalkaline series and show a calc-alkaline evolutionary trend with SiO2 content of 47.69%-65.47%, MgO contents of 1.42%-6.80% (Mg#= 45-53), and Na2O/K2O ratios of 1.83-3.63. They are characterized by enrichment in large ion lithophile elements (LILE) and light-rare-earth elements (LREE), depletion in heavy rare earth elements (HREE) and high field strength elements (HFSE) (e.g., Nb, Ta, Ti), and low initial 87Sr/86Sr ratios (0.7041-0.7057) and positiveεNd(t) values (039-4.08), implying that they could be derived from a depleted magma source. Taken together, these results suggest that the primary magma of the volcanic rocks might originate from partial melting of the mantle wedge metasomatized by fluids derived from subducted slab under a tectonic setting of active continental margin.     

张广才岭五道岭组火山岩的锆石U——Pb 年代学及地球化学特征

对张广才岭五道岭组火山岩进行锆石U--Pb LA--ICP--MS 年代学和岩石地球化学研究,以确定该组火山岩形成的时代和构造背景。选取样品中的锆石均呈自形--半自形晶,具有清晰的振荡生长环带和较高的Th /U 比值( 0. 52 ～ 2. 28) ,暗示其岩浆成因。测年结果显示,五道岭组火山岩形成于289 ± 3 Ma,是早二叠世岩浆活动的产物。火山岩的岩石组合为玄武岩--流纹岩,显示双峰式火山岩的特点,属于高钾钙碱性--钾玄岩系列,玄武岩具有富集Ｒb、K 等大离子亲石元素( LILE) ,亏损Nb、Ta 等高场强元素( HFSE) 的特征; 流纹岩呈负铕异常,富集Ｒb、Th、U 和K 等大离子亲石元素( LILE) ,亏损Nb、Ta 和Ti 等高场强元素( HFSE) 及Sr、P 元素,并显示A 型流纹岩的特点。结合该时期区域构造演化史,火山岩地球化学特征揭示了五道岭组火山岩的形成与岛弧环境下的局部伸展作用有关,这种构造背景是古亚洲洋板块俯冲于松嫩-张广才岭-佳木斯陆块之下造成的。     

滇东南富宁地区基性侵入岩及喷出岩时代

在滇东南富宁地区基性侵入岩、喷出岩较发育,前人将其划分为"半瓦型"侵入岩、"安定型"侵入岩和"龙康型"喷出岩3类,3类岩石普遍缺乏可靠的同位素年代学资料。在对富宁地区基性侵入岩、喷出岩进行区域地质调查的基础上,应用LAICP-MS技术对其进行锆石U-Pb测年,在半瓦型侵入岩和安定型侵入岩中分别获得了254.0±2.0Ma和244.2±4.4Ma的加权平均年龄,在龙康型喷出岩中获得251.9±3.0Ma和255.92±0.72Ma加权平均年龄。结合野外调查和综合研究,将富宁地区"安定型"侵入岩的时代界定于中三叠世,将"半瓦型"侵入岩和"龙康型"喷出岩的时代界定于晚二叠世。     

钦州湾-杭州湾构造结合带（南段） 地质演化和找矿方向

钦州湾-杭州湾结合带是位于扬子与华夏两大古陆块中间的巨型构造结合带。根据内部结构不均一性和演化历史的差异,钦-杭结合带可划分为3段：北（东）段、中段和南（西）段,分界线大致为北纬24°和北纬27°。中段与南岭带大体一致;北段指南岭以北地区,即绍兴-江山-萍乡一带;南段位于南岭以南区域,大致与云开-十万大山带相当。钦-杭结合带南段是华南大陆壳再造和矿产资源寻找的重要研究课题。它的地质演化与钦-杭结合带具有整体一致性,特别是具有一致的开-合历史。震旦系底部的粤西云浮大降坪块状硫化物矿床是海底喷流沉积的产物,它与信宜和陆川新元古代蛇绿岩等是南段洋壳存在的重要证据。在进一步的矿床勘查中,要重视斑岩型铜（钼）矿床的寻找。中酸性斑岩体来自于元古宙岛弧底部玄武质岩石（下地壳）在中生代时期的部分熔融,本质上该类矿床带有岛弧俯冲环境的基因。     

MARINE SOURCE ROCKS AND THEIR DEPOSITIONAL CONDITIONS OF MESOZOIC—CENOZOIC IN THE GAMBA—TINGRE BASIN,SOUTH TIBET:ORGANIC GEOCHEMICAL STUDY

MARINE SOURCE ROCKS AND THEIR DEPOSITIONAL CONDITIONS OF MESOZOIC—CENOZOIC IN THE GAMBA—TINGRE BASIN,SOUTH TIBET:ORGANIC GEOCHEMICAL STUDY1　FuJiamo ,ShengGuoying ,XuJiayou,et.al.ApplicationofbiologicalmarkersintheassessmentofpaleoenvironmentsofChinesenon marinesediments[J] .OrganicGeochemistry ,1990 ,16 :76 9～ 779. 2　JenkynsHC .Cretaceousanoxicevents:fromcontinentstooceans[J] .JournaloftheGeologicalSociety ,1980 ,137:171～188. …     

Evolution of the eastern margin of Korea: Constraints on the opening of the East Sea (Japan Sea)

We interpreted marine seismic profiles in conjunction with swath bathymetric and magnetic data to investigate rifting to breakup processes at the eastern Korean margin that led to the separation of the southwestern Japan Arc. The eastern Korean margin is rimmed by fundamental elements of rift architecture comprising a seaward succession of a rift basin and an uplifted rift flank passing into the slope, typical of a passive continental margin. In the northern part, rifting occurred in the Korea Plateau that is a continental fragment extended and partially segmented from the Korean Peninsula. Two distinguished rift basins (Onnuri and Bandal Basins) in the Korea Plateau are bounded by major synthetic and smaller antithetic faults, creating wide and considerably symmetric profiles. The large-offset border fault zones of these basins have convex dip slopes and demonstrate a zig-zag arrangement along strike. In contrast, the southern margin is engraved along its length with a single narrow rift basin (Hupo Basin) that is an elongated asymmetric half-graben. Analysis of rift fault patterns suggests that rifting at the Korean margin was primarily controlled by normal faulting resulting from extension rather than strike-slip deformation. Two extension directions for rifting are recognized: the Onnuri and Hupo Basins were rifted in the east-west direction; the Bandal Basin in the east–west and northwest–southeast directions, suggesting two rift stages. We interpret that the east–west direction represents initial rifting at the inner margin; while the Japan Basin widened, rifting propagated southeastward repeatedly from the Japan Basin toward the Korean margin but could not penetrate the strong continental lithosphere of the Korean Shield and changed the direction to the south, resulting in east–west extension to create the rift basins at the Korean margin. The northwest–southeast direction probably represents the direction of rifting orthogonal to the inferred line of breakup along the base of the slope of the Korea Plateau; after breakup the southwestern Japan Arc separated in the southeast direction, indicating a response to tensional tectonics associated with the subduction of the Pacific Plate in the northwest direction. No significant volcanism was involved in initial rifting. In contrast, the inception of sea floor spreading documents a pronounced volcanic phase which appears to reflect asthenospheric upwelling as well as rift-induced convection particularly in the narrow southern margin. We suggest that structural and igneous evolution of the Korean margin, although it is in a back-arc setting, can be explained by the processes occurring at the passive continental margin with magmatism influenced by asthenospheric upwelling.