Geochemical analysis of dump materials from the opencast Maritsa Iztok mines, Bulgaria, was carried out based on biomarker assemblages of hydrocarbon fractions. Organic matter (OM) and secondary transformations in three representative samples (massive black claystones and materials from the Iztok and Staroselets dump sites) were studied using geochemical proxies.A number of differences were recognised in the respective OM compositions of the samples compared to both published data and between the individual dump samples themselves. The ОM of the studied samples was found to be polar, but also contains some apolar compounds. It consists mainly of resins and asphalthenes. Claystone OM is of the dispersed type, with intense oxidative-reductive interactions in a lacustrine environment resulting in its transformation into an inert material. Dump sample kerogen is of Type II and mixed Type II/III. In all samples, “odd” numbered n-alkanes are found in higher amounts. Diterpenoids (С19, С20) with pimarane, abietane and phyllocladane skeletons are preponderant. Tri- and tetracyclic terpenoids and steranes have been identified in the black claystones OM only. Hopanes are present in low amounts in extractable OM from all three samples. Biomarkers indicate that black claystone OM is formed from aqueous flora, with a minor supply of gymnosperms (mainly G. Sequoia). Iztok Dump OM is structured by higher plants with an aqueous vegetation input. The Staroselets Dump OM formation is assigned to an active microbial reworking of aqueous vegetation and bacteria with a minor coniferous supply. Different geochemical parameters admit anoxic stratified bottom waters for the black claystones with an addition of deep water stagnation for Staroselets sample in a Maritsa Iztok Basin (MIB) aqueous environment.An attempt was also made to track the effect of secondary processes (oxidation, destruction, dearomatisation), temperature, water drainage and wash-out on dump materials. Leaching and weak degradation processes in the MIB dump environment are likely for a time span of ca. 40–50 years, considering the low percentage of short-chain n-alkanes, long-chain prevalence and low Pr/nC17 and Ph/nC18 ratios, with the Iztok Dump sample experiencing more advanced transformations. 相似文献
This study applies modern seismic geomorphology techniques to deep-water collapse features in the Orange Basin (Namibian margin, Southwest Africa) in order to provide unprecedented insights into the segmentation and degradation processes of gravity-driven linked systems. The seismic analysis was carried out using a high-quality, depth-migrated 3D volume that images the Upper Cretaceous post-rift succession of the basin, where two buried collapse features with strongly contrasting seismic expression are observed. The lower Megaslide Complex is a typical margin-scale, extensional-contractional gravity-driven linked system that deformed at least 2 km of post-rift section. The complex is laterally segmented into scoop-shaped megaslides up to 20 km wide that extend downdip for distances in excess of 30 km. The megaslides comprise extensional headwall fault systems with associated 3D rollover structures and thrust imbricates at their toes. Lateral segmentation occurs along sidewall fault systems which, in the proximal part of the megaslides, exhibit oblique extensional motion and define horst structures up to 6 km wide between individual megaslides. In the toe areas, reverse slip along these same sidewall faults, creates lateral ramps with hanging wall thrust-related folds up to 2 km wide. Headwall rollover anticlines, sidewall horsts and ramp anticlines may represent novel traps for hydrocarbon exploration on the Namibian margin.The Megaslide Complex is unconformably overlain by few hundreds of metres of highly contorted strata which define an upper Slump Complex. Combined seismic attributes and detailed seismic facies analysis allowed mapping of headscarps, thrust imbrications and longitudinal shear zones within the Slump Complex that indicate a dominantly downslope movement of a number of coalesced collapse systems. Spatial and stratal relationships between these shallow failures and the underlying megaslides suggest that the Slump Complex was likely triggered by the development of topography created by the activation of the main structural elements of the lower Megaslide Complex.This study reveals that gravity-driven linked systems undergo lateral segmentation during their evolution, and that their upper section can become unstable, favouring the initiation of a number of shallow failures that produce widespread degradation of the underlying megaslide structures. Gravity-driven linked systems along other margins are likely to share similar processes of segmentation and degradation, implying that the megaslide-related, hydrocarbon trapping structures discovered in the Namibian margin may be common elsewhere, making megaslides an attractive element of deep-water exploration along other gravitationally unstable margins. 相似文献
The stratigraphy of marine Plio-Pleistocene sediments from northeast Rhodes (Dodecanese islands, Greece) is revised in the light of facies mapping and the recognition of three major transgression–regression cycles. Before late Pliocene submergence, metamorphosed Mesozoic limestones formed a high-relief karstic landscape. During subsequent transgressions, subsiding basins with spectacular cliffed and bioeroded margins were infilled by a mosaic of carbonate-dominated sediments, sourced by high rates of carbonate productivity on narrow shelves rimming the basins and their drowning islands. Periods of relative sea-level fall superimposed a complex series of ‘fossil’ coastal geomorphological features such as cliffs, abrasion platforms, surf caves, notches, boulder beaches and palaeokarsts. These created the rugged present day topography of the island's northeast coast. Three main lithostratigraphic units, the Kritika, Rhodes and Lindos Acropolis Formations, are defined. The Rhodes and Lindos Acropolis Formations are subdivided into mappable facies groups rather than members, as the lithofacies are strongly diachronous. The Kritika and Rhodes Formations were each subaerially exposed and partly eroded before re-transgression. Although there is a general pattern of lithological succession, details vary across the study area and some facies groups are restricted in development, indicating differences in tectonic behaviour and palaeo-geomorphology between neighbouring basins. A preliminary process-response model is presented for the sedimentation history of the Rhodes and Lindos Acropolis Formations, using sedimentological, palaeontological, palaeoecological and ichnological data. 相似文献