Toxicities of antifouling biocide Irgarol 1051 and its major degraded product to marine primary producers

Irgarol 1051 (2-methythiol-4-tert-butylamino-6-cyclopropylamino-s-triazine) is an algaecide commonly used in antifouling paints. It undergoes photodegradation which yields M1 (2-methylthio-4-tert-butylamino-6-amino-s-triazine) as its major and most stable degradant. Elevated levels of both Irgarol and M1 have been detected in coastal waters worldwide; however, ecotoxicity effects of M1 to various marine autotrophs such as cyanobacteria are still largely unknown. This study firstly examined and compared the 96 h toxicities of Irgarol and M1 to the cyanobacterium Chroococcus minor and two marine diatom species, Skeletonema costatum and Thalassiosira pseudonana. Our results suggested that Irgarol was consistently more toxic to all of the three species than M1 (96 h EC50 values: C. minor, 7.71 microug L(-1) Irgarol vs. > 200 microg L(-1) M1; S. costatum, 0.29 microg L(-1) Irgarol vs. 11.32 microg L(-1)M1; and T. pseudonana, 0.41 microg L(-1) Irgarol vs. 16.50 microg L(-1)M1). Secondly, we conducted a meta-analysis of currently available data on toxicities of Irgarol and M1 to both freshwater and marine primary producers based on species sensitivity distributions (SSDs). Interestingly, freshwater autotrophs are more sensitive to Irgarol than their marine counterparts. For marine autotrophs, microalgae are generally more sensitive to Irgarol than macroalgae and cyanobacteria. With very limited available data on M1 (i.e. five species), M1 might be less toxic than Irgarol; nonetheless this finding warrants further confirmation with additional data on other autotrophic species.     

Bioremediation of petroleum hydrocarbons in anoxic marine sediments: Consequences on the speciation of heavy metals

We investigated the effects of biostimulation and bioagumentation strategies applied to harbor sediments displaying reducing conditions and high concentrations of petroleum hydrocarbons and heavy metals. We compared the microbial efficiency of hydrocarbon removal from sediments maintained for 60 days in anoxic conditions and inoculated with acetate, sulfate-reducing bacterial strains and acetate and sulfate-reducing bacteria. All treatments determined a significant increase in the microbial growth and significant decreases of hydrocarbon contents and of redox potential values. The addition of sulfate-reducing bacterial strains to the sediment was the most efficient treatment for the hydrocarbon removal. In all experiments, significant changes of the heavy metals’ phase repartition were observed. The results reported here suggest that the biodegradation of petroleum hydrocarbons in anoxic marine sediments may be enhanced by stimulating microbial anaerobic metabolism, but care should be applied to monitor the potential changes in the mobility and bioavailability of heavy metals induced by bio-treatments.     

Occurrence of persistent organic pollutants in marine fish from the Natuna Island,South China Sea

Five marine fish species were collected from the Natuna Island, South China Sea to investigate the occurrence of polybrominated diphenyl ethers (PBDEs), polychlorinated biphenyls (PCBs), dichlorodiphenyltrichloroethane and its metabolites (DDTs). Concentrations of PBDEs, PCBs, and DDTs in marine fish ranged from 2.85 to 7.82, 14.3 to 48.1, and 7.99 to 40.3 ng/g lipid weight, respectively. Higher concentrations of PBDEs, PCBs, and DDTs were observed in Snakefish (Trachinocephalus myops), which might be attributed to their different feeding and living habits. PCBs were the predominant POPs in all marine fish, followed by DDTs and PBDEs. BDE 47 and PCB 153 were the predominant congener of PBDEs and PCBs, respectively. Compositional distribution of DDTs indicated the possible presence of fresh input sources around the Natuna Island. The ratios of o,p′-DDT/p,p′-DDT being less than 1 in fish samples suggested that DDT contributions from dicofol seemed considerably low. New input sources of DDT in South China Sea are worth further research.     

矿山地震监测技术的进展及最新成果

回顾了矿山地震监测的简史,介绍了近期矿震监测技术改造情况．抚顺小孔径矿山地震台网的监测取得了比较完整的观测资料．矿震定位结果表明了矿震与开采进程的相关性．用岩石断裂力学和损伤理论的研究成果对于两类不同矿震的成因给出了最新解释．观测资料证实了矿震与瓦斯溢出的相关性．这些结果表明．在一定条件下．矿震可能成为瓦斯溢出的预警信号．由此证明,实现矿震与瓦斯浓度的联合监测是重要的,也是可行的．矿山地质灾害的综合地球物理监测对于地震成因的研究具有重要的中尺度实验意义,同时对于煤矿安全生产也将带来重要效益．     

The inhibition of marine nitrification by ocean disposal of carbon dioxide

In an attempt to reduce the threat of global warming, it has been proposed that the rise of atmospheric carbon dioxide concentrations be reduced by the ocean disposal of CO2 from the flue gases of fossil fuel-fired power plants. The release of large amounts of CO2 into mid or deep ocean waters will result in large plumes of acidified seawater with pH values ranging from 6 to 8. In an effort to determine whether these CO2-induced pH changes have any effect on marine nitrification processes, surficial (euphotic zone) and deep (aphotic zone) seawater samples were sparged with CO2 for varying time durations to achieve a specified pH reduction, and the rate of microbial ammonia oxidation was measured spectrophotometrically as a function of pH using an inhibitor technique. For both seawater samples taken from either the euphotic or aphotic zone, the nitrification rates dropped drastically with decreasing pH. Relative to nitrification rates in the original seawater at pH 8, nitrification rates were reduced by ca. 50% at pH 7 and more than 90% at pH 6.5. Nitrification was essentially completely inhibited at pH 6. These findings suggest that the disposal of CO2 into mid or deep oceans will most likely result in a drastic reduction of ammonia oxidation rates within the pH plume and the concomitant accumulation of ammonia instead of nitrate. It is unlikely that ammonia will reach the high concentration levels at which marine aquatic organisms are known to be negatively affected. However, if the ammonia-rich seawater from inside the pH plume is upwelled into the euphotic zone, it is likely that changes in phytoplankton abundance and community structure will occur. Finally, the large-scale inhibition of nitrification and the subsequent reduction of nitrite and nitrate concentrations could also result in a decrease of denitrification rates which, in turn, could lead to the buildup of nitrogen and unpredictable eutrophication phenomena. Clearly, more research on the environmental effects of ocean disposal of CO2 is needed to determine whether the potential costs related to marine ecosystem disturbance and disruption can be justified in terms of the perceived benefits that may be achieved by temporarily delaying global warming.     

基于层次分析法的南麂列岛海域人工鱼礁社会效果评价

人工鱼礁建设具有生态效果、经济效果和社会效果。为科学指导人工鱼礁的建设方向,进一步促进海洋牧场建设以及海洋渔业资源和海洋生态环境的可持续发展,文章采用改进的层次分析法,从人工鱼礁与社会的适应性、对社会环境的影响、对社会生活的影响以及对其他行业发展的影响4个方面,选取政策符合性等10个评价指标,通过问卷调查的方式,对南麂列岛海域人工鱼礁的社会效果进行评价,填补该研究领域的空白。研究结果表明:根据各评价指标的权重和效果判定值,南麂列岛海域人工鱼礁产生了较好的社会效果,其中海洋生态环境、项目长远性、改善渔民生活质量和海洋捕捞业等指标发挥作用较大;未来将开展长期和连续的调查研究,提高评价可信度。     

基于逆散射级数法的鬼波压制方法

鬼波问题是影响海上地震资料分辨率和保真度提高的最重要因素之一.详细论述了逆散射级数理论和逆散射级数法鬼波压制原理,说明了逆散射级数方法进行鬼波压制理论的完善性和对鬼波描述的精确性.实现了基于逆散射级数理论的鬼波压制方法,方法以波动方程和Lippmann-Schwinger方程为基础,在频率-波数-波数域内构造与鬼波相关的压制算子,在不需要对地下介质作任何假设条件下实现地震数据驱动鬼波压制,并通过改善消除鬼波的压制算子,提高算法的稳定性.资料处理试验与处理结果分析表明,基于逆散射级数鬼波压制方法能在实现鬼波压制的同时较好保留有效反射波的信息,从而补偿地震资料低频损失和提高地震数据的保真度.数据处理试验还表明,研究方法能对低信噪比的地震资料进行有效的鬼波压制处理.建立了基于逆散射级数鬼波压制处理流程.     

南沙海域第三纪生物礁层序构成和演化

南沙海域第三纪盆地生物礁油气藏勘探具有巨大的潜力。作者运用层序地层学原理精细解剖不同体系域的生物礁内部构成,建立了高精度的生物礁礁层序地层格架,并逐层进行回剥分析,表明第三系充填沉积为四幕伸展裂陷过程,进而揭示盆地生物礁层序的动态发育过程及不同时期南沙海域含油气盆地的发育状态。     

生态文明建设下海洋空间规划体系的构建研究

海洋空间规划是重要的海洋空间管理工具,构建科学高效的海洋空间规划体系是海洋生态文明建设的重要组成部分。文章基于对海洋空间规划及其体系的基本认知,结合国家生态文明建设和海洋空间治理需求,提出海洋空间规划体系构建的时代背景、着力点和基本路径。研究表明,海洋空间规划体系是由各类海洋空间规划组成的,具有一定逻辑组织关系的管理制度集合,是海洋空间发展与资源环境管制的基础性机制集合;其构建应满足时代发展要求和海洋空间治理需求,体现国家海洋生态文明意志和海洋空间治理现代化,以总结多样化实践、建立完善协调机制和统一技术体系为基本路径。     

砂质基底领海基点的保护范围选划及管理研究——以外磕脚领海基点为例

领海基点对于维护国家海洋权益等意义重大。文章基于外磕脚领海基点的保护实践工作,从前期准备、现场调查方法、保护范围选划结果3个方面,开展砂质基点领海基点保护范围选划的案例研究,据此提出砂质基底领海基点保护范围的选划依据和方法。研究表明:砂质基底领海基点的保护范围选划应依据海岛的特殊属性,由保护对象的边界向外延伸至潮汐水道,并充分体现地貌整体性和连续性。针对砂质基底领海基点保护,文章建议应加强工程手段实现基底稳定,维护领海基点安全;加强领海基点外业调查,夯实领海基点地形水文资料基础;加大领海基点巡查力度,持续推进领海基点实时动态监视监测;加强部门沟通协调,完善领海基点信息管理系统;加大宣传教育,树立全民海洋海岛意识等保护管理建议,为领海基点的保护管理工作提供理论和实践探索。