与角岩有关的矿床主要类型及其对深部找矿的意义

作为热接触变质的产物,角岩在石墨、硅灰石、红柱石等变质成因非金属矿床和各种金属矿床以及油气矿藏均可见,但对其调查研究成果并不多。在文献综述的基础上,结合在南岭、冈底斯等重要成矿带地质找矿的实践,通过对与矿产资源有关的角岩广义概念的界定,概述了与角岩有关的各主要类型矿床的地质特征,如石墨、硅灰石、红柱石等变质成因非金属矿床,钨、钼、铁、铜、铀、金、铅锌、锡、银和稀有金属矿床以及油气矿藏;举例阐述了近年来角岩发育矿区深部找矿中的新突破,如江西淘锡坑钨矿,广西大厂铜坑至拉么一带的锡多金属矿床,西藏甲玛铜多金属矿,云南老厂银铅锌矿、羊拉铜矿、雪鸡坪铜矿等矿区;讨论了角岩型矿床成矿预测的准则。结果表明:矿区和矿田大比例尺深部预测时应注意岩石组合、干湿关系、封闭与开放体系、岩石物性和分带性、原岩岩性及其空间配置关系;区域性中、小比例尺成矿评价时应注意角岩的空间分布、岩石学特征与矿产资源的专属性关系等;利用角岩预测隐伏岩体的应用前景广泛,在深部找矿中具有现实意义。建议加强角岩与成矿关系的理论研究,对以往地质填图工作中发现的"角岩化带"可重新评价其与成矿的关系。     

西藏乌鲁穷含铜磁铁矿床的发现及地质特征

继尼雄、弗野、材玛等铁矿床的发现之后,新一轮1：5万区域地质调查又在班公湖-怒江成矿带西段乌鲁穷地区发现了较大规模的含铜磁铁矿矿床。野外路线调查、剖面实测和大比例尺填图表明,乌鲁穷磁铁矿形成于南羌塘南缘中-晚侏罗世中酸性岩体与上三叠统日干配错群二组（T₃R²）碳酸盐岩外接触带中,矿体受后期近南北向高角度正断层改造,成矿作用表现出多期次、多阶段特征。通过对矿体邻近的石英闪长岩、二长花岗岩和控矿断层中同构造碳酸盐脉进行锆石LA-ICP-MS U-Pb同位素测年,获得石英闪长岩、二长花岗岩成岩年龄分别为：（161.3±0.72）Ma、（157.5±1.7）Ma,并获得同构造碳酸盐脉热液锆石年龄为（84.2±1.1）Ma。结合前人研究和1：5万地质调查成果,认为乌鲁穷含铜磁铁矿在中-晚侏罗世（157.5~161.3 Ma）班公湖-怒江洋北向俯冲过程中初步富集成矿,形成矽卡岩型含铜磁铁矿矿床,矿体在晚白垩世（84.2 Ma）陆内伸展过程中再次富集;提出班公湖地区在晚白垩世中期存在一期横跨缝合带的陆内伸展成矿事件,成矿作用与班公湖-怒江洋闭合后地幔软流圈底辟及其相关的地壳线性热隆伸展是一个机理关联的系统。     

新疆萨喀尔得铜矿C-H-O-S同位素特征

新疆萨喀尔得铜矿属中低温热液型,该矿石英和方解石样品中^δ13CPDB值为-17．3‰— -0．7％,δ^18OSMOW为16．2‰-22．4‰ δ18OH2O 水值为6.9‰-12.5‰水值为6．9‰-12．5‰,8D变化于-73．8‰—-52．4‰之间。研究表明,成矿流体主要来源于深部发生循环加热的建造水,并混合变质水和岩浆水;成矿早期流体中的C主要来源于地层水或大气降水,晚期有深部岩浆水的加入。^δ^34S值变化范围为0．2‰-6．1％o,表明流体中的S主要来自岩浆或上地幔。     

Calibration of a chalcogenide glass membrane ion-selective electrode for the determination of free Fe in seawater: I. Measurements in UV photooxidised seawater

Calibration of a chalcogenide glass membrane, Fe(III)ISE [Fe_2.5(Ge₂₈Sb₁₂Se₆₀)_97.5], in buffered saline media has been undertaken in order to assess the suitability of this ISE for seawater analyses. The electrode slopes in saline citrate and salicylate buffers were 26.3 and 28.2 mV/decade, respectively, for Fe³⁺ concentrations ranging from 10⁻¹⁰ M to less than 10⁻²⁵ M Fe³⁺. The calibration lines in the citrate and salicylate buffers were essentially collinear with the response in unbuffered chloride-free standards containing >10⁻⁵ M Fe³⁺, demonstrating that the response of the FeISE is unaffected by chloride ions. A mechanism involving a combination of charge transfer and ion-exchange of Fe(III), at the electrode diffusion layer, can be used to explain the ≈30 mV/decade slope of the FeISE. The response of the FeISE in UV photooxidised seawater containing 8 nM total Fe was measured as the pH was changed from 8.27 to 3.51. The slope of the response was 24.2 mV/decade [Fe³⁺] calculated as a function of pH using Fe(III) hydrolysis constants for seawater. Moreover, the response was essentially collinear with that in citrate buffers and in unbuffered solutions containing >10⁻⁵ M Fe³⁺ and the slope for the combined data was 26.2 mV/decade. This study was restricted to organic-free seawater because the certainty in Fe(III)–ligand stability constants is insufficient to warrant the selection of an ideal calibration buffer system, and there is evidence that powerful chelating ligands (e.g., EDTA along with humic and fulvic acids) may alter the response of the Fe(III)ISE. The Fe dissolution rate of the FeISE in UV photooxidised seawater was found to be 1.6×10⁻² nmol Fe/min, as measured by cathodic stripping voltammetry (CSV). This would contaminate a 100-ml sample by 0.8–1.6 nM Fe over a typical measurement period of 5–10 min obtained using a stability criterion of 0.5 mV/min. Various methods are proposed for reducing the level of contamination in open ocean samples that contain sub-nanomolar concentrations of iron. The FeISE has the potential to detect free Fe³⁺ at concentrations typically found in natural seawater.     

Zircon U–Pb and pyrite Re–Os age constraints on pyrite mineralization in the Yinjiagou deposit,China

We report new zircon U–Pb and pyrite Re–Os geochronological studies of the Yinjiagou poly-metallic deposit, sited along the southern margin of the North China Craton (SMNCC). In this deposit, pyrite, the most important economic mineral, is intergrown/associated with Mo, Cu, Au, Pb, Zn, and Ag. Prior to our new work, the age of chalcopyrite–pyrite mineralization was known only from its spatial relationship with molybdenite mineralization and with intrusions of known ages. The U–Pb and Re–Os isotope systems provide an excellent means of dating the mineralization itself and additionally place constraints on the ore genesis and metal source. Zircons separated from the quartz–chalcopyrite–pyrite veins include both detrital and magmatic groups. The magmatic zircons confine the maximum age of chalcopyrite–pyrite mineralization to 142.0 ± 1.5 Ma. The Re–Os results yield an age of 141.1 ± 1.1 Ma, which represents the age of the chalcopyrite–pyrite mineralization quite well. The common Os contents are notably low (0.5–20.1 ppt) in all samples. In contrast, the Re contents vary considerably (3.0–199.2 ppb), most likely depending on intensive boiling, which resulted in an increase of Re within the pyrite. This study demonstrates that the main chalcopyrite–pyrite mineralization occurred late in the magmatic history and was linked to a deeper intrusion involving dominant mantle-derived materials. This mineralization event might be related to the Early Cretaceous lithospheric destruction and thinning of the SMNCC.     

Community Structure and Dynamics of Phytoplankton in the Western Subarctic Pacific Ocean: A Synthesis

The phytoplankton community in the western subarctic Pacific (WSP) is composed mostly of pico- and nanophytoplankton. Chlorophyll a (Chl a) in the <2 μm size fraction accounted for more than half of the total Chl a in all seasons, with higher contributions of up to 75% of the total Chl a in summer and fall. The exception is the western boundary along the Kamchatka Peninsula and Kuril Islands and the Oyashio region where diatoms make up the majority of total Chl a during the spring bloom. Among the picophytoplankton, picoeukaryotes and Synechococcus are approximately equally abundant, but the former is more important in term of carbon biomass. Despite the lack of a clear seasonal variation in Chl a concentration, primary productivity showed a large seasonal variation, and was lowest in winter and highest in spring. Seasonal succession in the phytoplankton community is also evident with the abundance of diatoms peaking in May, followed by picoeukaryotes and Synechococcus in summer. The growth of phytoplankton (especially >10 μm cell size) in the western subarctic Pacific is often limited by iron bioavailability, and microzooplankton grazing keeps the standing stock of pico- and nano-phytoplankton low. Compared to the other HNLC regions (the eastern equatorial Pacific, the Southern Ocean, and the eastern subarctic Pacific), iron limitation in the Western Subarctic Gyre (WSG) may be less severe probably due to higher iron concentrations. The Oyashio region has similar physical condition, macronutrient supply and phytoplankton species compositions to the WSG, but much higher phytoplankton biomass and primary productivity. The difference between the Oyashio region and the WSG is also believed to be the results of difference in iron bioavailability in both regions. This revised version was published online in July 2006 with corrections to the Cover Date.     

八卦庙金矿床的绿泥石特征及成岩成矿意义

绿泥石是八卦庙大型金矿床的主要热液蚀变矿物，本文系统地研究了绿泥石的产状、矿物学、化学成分等特点。在此基础上应用Walshe的绿泥石六组分热力学模型计算了绿泥石形成的物理化学条件：形成温度247.6～335.1℃，lgfo2值为一27.35～37.99，lgfs2的值是－7．46～－13.02，与根据成矿期石英包裹体所计算的值相近。     

Geochemical characterization of Archaean amphibolites from the eastern part of Anshan–Benxi iron producing area,northeastern China: implication for tectonic setting of BIFs

The Anshan–Benxi iron producing area, which is located at the northeastern margin of the North China Craton, is the main distribution area of Archaean BIFs in China. In their eastern part, including the Gongchangling and Waitoushan deposits, BIFs mainly are hosted in the Archaean middle Anshan Group. Amphibolites are widely distributed in the iron‐bearing rock series, reflecting the tectonic setting of BIFs. Amphibolites not only have MORB‐like compositional characteristics, but also have island arc‐like ones, and they are consistent with back‐arc basin basalts (BABB). In the study area, the protolith of amphibolites belongs to Okinawa‐type BABB; it indicates that tectonic setting of BIFs is the intra‐continental back‐arc basin. In the study area, the formation of sedimentary basins for BIFs had been associated with oceanic plate subduction. Amphibolites from Gongchangling deposit are characterized by relative enrichments in LILE and LREE, and depletions in HFSE. This indicates that they had a relatively large influence of subduction in their formation. Amphibolites from Waitoushan deposit are characterized by relative enrichments in LILE without conspicuous depletions in HFSE, indicating relatively low subduction rates. Copyright © 2015 John Wiley & Sons, Ltd.     

克克齐矿区铜矿床地质、地球物理特征及找矿远景

克克齐矿区铜矿床分别产于石炭系中统本巴图组二岩段及上统阿木山组二岩段的海相火山碎屑沉积岩中，地表以铁帽的形式存在，岩石见褐铁矿化，探槽中可见有孔雀石。该铜矿床的成因类型是海相火山岩型。地下铜矿体的上方有明显的激电异常反映，激电异常应是本区寻找赋存在海相火山碎屑岩地层中铜矿体的找矿有利标志。文章论述了铜矿床所处的区域地质背号、矿区和矿床（体）地质特征、地球物理特征，初步分析了引起矿致异常的条件和因素，对异常进行了评价，并提出了找矿建议。     

内蒙古巴彦哈尔金矿床地质特征及成因初探

内蒙古巴彦哈尔金矿床位于华北陆块北缘艾力庙-锡林浩特中间地块西北缘.矿床赋存于中元古代温都尔庙群的绢云石英片岩和绿泥石片岩中.矿床的形成与区内韧性剪切带及华力西期岩浆活动关系密切.矿区内共圈定出5个矿体,总体走向为北西向,矿体呈似层状或透镜状产出,矿石类型包括石英脉型和糜棱蚀变岩型.金矿化与硅化和黄铁绢英岩化蚀变关系密切.结合矿床的矿体地质、矿物成分、矿物嵌布及围岩蚀变特征以及前人包裹体测温结果,认为矿床类型为浅成低温热液型金矿.