Deep-sea manganese (Mn) nodules are problematic in terms of factors such as their characteristic form and genesis. There are many reports of bacterial species from manganese nodules. However, the genesis of these nodules has not been fully confirmed. Samples, mainly from the Clarion Clipperton Fracture zone in the Pacific Ocean, were examined by mineralogical methods and X-ray CT. Thin sections of these samples showed columnar stromatolite structures with rhythmic bands. Mineralized bacteria were observed by SEM and TEM. Surface morphology could be described as having a fractal-like nature. The fractal characteristics of spherical to dome-like forms were fundamentally composed of at least four ranks. The 4th order form corresponds to the stromatolite dome top shapes. Similar granular domain units and porous characteristics in manganese nodules were clearly observed by X-ray CT sections. Mathematical simulation based on fractal models reproduced similar morphological characteristics to the natural samples. So, we arrived at the concluding hypothesis that manganese nodules are aggregated stromatolite with fractal-like characteristics. Furthermore, we discussed the possibility that the nature of the layer manganese oxide minerals as the major component of the nodule and associated Fe-oxyhydroxide minerals may become an absorber/scavenger of strategic heavy metals and also toxic metals in the environments. 相似文献
The sources and sinks of manganese in underground coal mine workings are poorly understood compared to those of iron. The
geochemical system in the secondary egress drift of Caphouse Colliery near Horbury, UK, is an ideal system for studying these
processes. Five locations along the drift and four secondary inflows to the drift were sampled 24 times through the year commencing
May 2005. During the sampling period, the pH in the main channel varied from 6.73 to 7.93 and increased along the flow path.
The secondary inflows to the drift from the strata were of higher alkalinity (mean = 385 mg/L as CaCO3) than the main flow (mean = 330 mg/L as CaCO3); the affects of mixing between the less alkaline main channel and the more alkaline secondary inflows and of carbon dioxide
exsolution are evident in the form of carbonate and hydroxide precipitates. SEM and XRD analysis of precipitates collected
from the drift confirm the presence of calcium and manganese carbonates and ferric hydroxide. PHREEQC speciation and solubility
modelling confirms supersaturation of the water in the main channel with respect to ferric oxy-hydroxides; iron, manganese,
magnesium and calcium carbonates; and manganese oxides.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
Datangpo-type sedimentary manganese deposits, which are located in northeastern Guizhou province and its adjacent areas, are Mn carbonate-type deposits hosted in black carbonaceous shale that represent a series of medium to large deposits containing a huge tonnage of reserves. PAAS-normalized rare earth element distribution patterns of manganese ores record “hat-shaped” REY (REE + Y) plots characterized by pronounced middle rare earth element enrichment, evident positive Ce anomalies, weak to strong positive Eu anomalies and negligible negative Y anomalies. These REY geochemical characteristics are different from those of country rocks and record the processes and features of sedimentation and diagenesis. Manganese was precipitated as Mn-oxyhydroxide particles in oxidized water columns with the sorption of a certain amount of rare earth elements, subsequently transforming from Mn-oxyhydroxides to rhodochrosite and redistributing REY in reducing alkaline pore-water during early diagenesis. A number of similarities can be observed through a comparison of Datangpo-type manganese ores and modern marine ferromanganese oxyhydroxide precipitates based on their rare earth elements. The precipitation of Datangpo-type manganese ores is similar to that of hydrogenetic crusts and nodules based on their positive Ce anomalies and relatively higher total REY concentrations. However, several differences also exist. Compared to hydrogenetic crusts and nodules, Datangpo-type manganese ores record smaller positive Ce anomalies, lower total REY concentrations, unobvious fractionation between Y and Ho, and weak to strong positive Eu anomalies. These were caused by quicker sedimentary rates in the oxic water columns of the shallower basin, after which pore water became strongly reducing and alkaline due to the degradation of organic matter in the early diagenetic stage. In addition, compared to typical deposits in the world, Datangpo-type manganese ores are similar to hydrogenetic deposits and different than hydrothermal deposits. All of these characteristics of manganese ores indicate that Datangpo-type manganese ores, the principal metallogenic factors of which include oxidation conditions during deposition and reducing conditions during early diagenetic stages, represent hydrogenetic deposits. 相似文献
I~D~IONThe numerous research results on the deep-sea manganese nodules show that the most valuable metal elements such as Cu, Ni are mainly concentrated in the manganese minerals, which only take about 15% Of the weight in the total manganese nodules, therefore, many marine scien.tists pay more attention in their research on the manganese minerals rather than the other mineralsin the deep-sea maganeses nodules.There are more than tens of different kinds of manganese mineral phases in the nod… 相似文献
Desert varnish of pristine sandstone and petroglyph surfaces from Takabart Kabort (Naturalistic Bubaline Art School) and Alamas (Tanzina Art School) can be well classified by their (SiO2+Al2O3):MnO2, Al2O3:SiO2, and P2O5:CaO ratios. Specific ratios are due to the occurrence of clay minerals like illite, kaolinite, smectite, and feldspar, quartz, carbonates like calcite and dolomite, manganese oxyhydroxides, and apatite. Their occurrence corresponds to the local origin and composition of the primary aeolian material.
In general, the analyzed desert varnish shows lamination patterns characterized by alternating MnO2-rich and -poor layers (25 wt% MnO2) at rather constant iron oxyhydroxide content (6 wt% Fe2O3). Varnish on non-engraved surfaces exhibits three MnO2-rich layers, whereas varnish-coated petroglyphs reveal minor lamination patterns corresponding to the dating of petroglyphs by rock art. The older Naturalistic Bubaline Art School petroglyphs (about 6–4 ka BP) and the younger Tazina Art School petroglyphs (about 3.8–3 ka BP) contain only two and one MnO2-rich layer, respectively. It is assumed that the occurrence of such microlaminations is caused by climate changes in North Africa. Three humid periods are discerned from the Terminal Pleistocene to Holocene in the literature. Such periods are suitable to induce manganese accumulation by biotic and abiotic processes. Accordingly, the distinct lamination patterns gained from this study verify the dating of petroglyphs by rock art. From another point of view, classification of the above petroglyphs may be provided by analyses of microlaminations independently on cultural historical aspects. 相似文献