甘孜—理塘结合带锰结核的发现及其地质意义

在甘孜—理塘结合带内理塘县中木拉乡附近发现锰结核。通过地质填图和综合研究,该锰结核产于结合带内瓦能蛇绿混杂岩组中的黑色粉砂质板岩中。其沉积层序为玄武岩→硅质岩→含锰结核粉砂质板岩。锰结核主量元素具有高Mn、低Fe、Si、Ca的特点,其中Mn含量为42.19%,高出大洋锰结核平均值1.83倍,Mn/Fe值较高,达8.1。锰结核中除Cr高于大洋锰结核平均值2～7倍外,多数微量元素低于大洋锰结核平均值。稀土元素具有较明显的Ce正异常,稀土总量、轻重稀土分异程度、Eu异常特征与混杂岩中的砂岩、硅质岩近似,而与玄武岩差别较大。该锰结核产出于大陆边缘构造环境,火山活动微弱,代表甘孜—理塘洋扩张到最大程度时的沉积。其时甘孜—理塘洋规模仍是有限的。     

西昆仑麻扎构造混杂岩带中－下侏罗统叶尔羌群源区构造背景分析

本文在收集和总结前人研究成果的基础上,通过对西昆仑麻扎地区中-下侏罗统叶尔羌群碎屑组分和砂岩地球化学特征分析,讨论了叶尔羌群沉积源区大地构造背景.在莎里塔什组沉积时期,物源区的构造背景主要为大陆岛弧、大洋岛弧的性质;杨叶组沉积时期,源区的大地构造背景为大陆岛弧,兼有活动大陆边缘性质;塔尔尕组沉积时期,源区构造背景复杂:既显示活动大陆边缘和岛弧(大洋岛弧、大陆岛弧)的性质,同时还显示出被动陆缘环境,其可能与晚三叠世造山开始时克拉通地块边缘的卷入有关.     

Rapid Determination of Trace and Ultra Trace Level Elements in Diverse Silicate Rocks in Pressed Powder Pellet Targets by LA‐ICP‐MS using a Matrix‐Independent Protocol

A simple, single sample preparation involving pressed rock powder pellets was utilised to determine the trace and ultra trace abundances of petrogenetically important elements including high field‐strength elements and REEs by laser ablation‐ICP‐MS. One of the elements predetermined by XRF spectrometry served as an internal standard. The influence of sample preparation parameters (grain size, pellet compactness and amount of binding media) on analytical performance was also investigated, including sample homogeneity issues at the laser sampling scale. Line scanning with a high repetition frequency (20 Hz) and large beam diameter (200 μm) ensured ablation from a larger sample surface area, eliminating issues related to sample heterogeneity. A median grain size of about 10 μm for silicate rock powders was found to be sufficiently representative at this scale of laser sampling. Granitic rocks or samples containing resistant minerals such as zircon needed extra grinding to achieve grain sizes down to < 5 μm for better precision for elements that are concentrated in these phases. Using ¹³⁷Ba as an internal standard, reasonable accuracies within 15–20% for most of the high mass trace elements were achieved; in the case of low mass elements, it may deviate up to 40%. Precision of measurements rarely exceeded 15% RSD.