长乐-南澳构造带燕山期(J-K)TTG岩石组合及其地质意义

长乐-南澳构造带火成岩类多年来备受国内外地学界关注和瞩目,但对其构造环境的认识却存在较大分歧.本文通过分析构造带燕山期(J-K)火成岩类的时空分布、岩石学特征及其TTG岩石组合等,讨论厘定构造带的构造性质与岩浆源区.据构造带花岗岩类岩石结构构造特征、锆石SHRIMP U-Pb与LA-ICP-MS U-Pb同位素定年,测年结果集中分布于200~191Ma、155~97Ma与84~69Ma三个区间,暗示构造带燕山期(J-K)岩浆活动可以划分为三个阶段:(1)早侏罗世(J₁),以片麻岩类与糜棱岩类为主;(2)晚侏罗世-早白垩世(J₃-K₁),片麻状花岗岩类占优势;(3)晚白垩世(K₂),出现大量的晶洞花岗岩类与脉岩类.采用O'Connor An-Ab-Or标准矿物分类方案识别TTG岩石组合获知,早侏罗世(J₁)与晚侏罗世-早白垩世(J₃-K₁)时,构造带存在TTG岩石组合;晚白垩世(K₂)时,构造带TTG岩石组合消失,发育典型的双峰式火成岩.TTG岩石组合以钙性(C)和中钾钙碱性(MKCA)为主,显示奥长花岗岩演化趋势(Tdj),具大陆边缘弧花岗岩(CAG)的特征,由此可推断长乐-南澳构造带燕山期(J-K)构造性质为主动大陆边缘弧.构造带发育两类成因机制的TTG岩石组合,分别来自不同的岩浆源区:具镁安山质(MA)性质的TTG岩浆来源于玄武质洋壳的脱水融熔,具正常安山质(A)性质的TTG岩浆来源于陆壳底部玄武质岩石的局部熔融.     

云南澜沧勐佛铅多金属矿成矿特征

勐佛铅多金属矿的成因类型为破碎带热液充填交代型。沿断裂分布方铅矿化、黄铜矿化、黄铁矿化、斑铜矿化、方铅矿化及相应的次生矿化蚀变。     

Trace Elements in Olivines from the Giant Jinchuan Ni-Cu-(PGE) Deposit,NW China,and Its Geological Implication

The giant Jinchuan magmatic sulfide deposit in China is the third largest mining deposits in the world. Although many research have been done, there still exist some debates in the genesis of deposit. This study using the LA-IC-MS to obtain the trace elements concentrations of the olivine in order to discuss the mechanism of influence the element variability and illustrate the process of magmatism and ore-forming. The analytical results show that Ni, Co correlate negatively with Fo in the olivine, Mn/Fe is positively correlate with Fo, while Mn/Zn and Zn/Fe show no obvious correlation with Fo. The primitive mantle olivine-normalized trace element patterns of the Jinchuan olivine show that Jinchuan Ⅰ, Ⅱ intrusions have the same trace elements characteristics, which display negative Cr, V, Ni, Co and Ti anomalies and enrichment of Zr, Y, Ti, Sc and Ca. The multi-element patterns of the Jinchuan olivine imply same parental magma in the intrusion Ⅰ and Ⅱ. The spinel which cocrystallization with the olivine make it display negative Cr, V and Ti anomalies. The contents of Ni and Co in olivine are influenced by the process of sulfide segregation and the reaction between sulfide and olivine. The lower content of Cr and V in olivine of the intrusion Ⅱ compared with the intrusion Ⅰ imply that the parental magma of the intrusion Ⅱ was more evolved. Higher Mn/Zn (>13) ratios and lower Zn/Fe (<11) ratios indicate that the magma of Jinchuan intrusion likely originate from partial melting of peridotite mantle possibly, instead of pyroxene mantle sources.     

Time scales and length scales in magma ?ow pathways and the origin ofmagmatic Ni-Cu-PGE ore deposits

Ore forming processes involve the redistribution of heat, mass and momentum by a wide range of processes operating at different time and length scales. The fastest process at any given length scale tends to be the dominant control. Applying this principle to the array of physical processes that operate within magma flow pathways leads to some key insights into the origins of magmatic Ni-Cu-PGE sulfide ore deposits. A high proportion of mineralised systems, including those in the super-giant Noril'sk-Talnakh camp, are formed in small conduit intrusions where assimilation of country rock has played a major role. Evidence of this process is reflected in the common association of sulfides with varitextured contaminated host rocks containing xenoliths in varying stages of assimilation. Direct incorporation of S-bearing country rock xenoliths is likely to be the dominant mechanism for generating sulfide liquids in this setting. However, the processes of melting or dissolving these xenoliths is relatively slow compared with magma flow rates and, depending on xenolith lithology and the composition of the carrier magma, slow compared with settling and accumulation rates. Chemical equilibration between sulfide droplets and silicate magma is slower still, as is the process of dissolving sulfide liquid into initially undersaturated silicate magmas. Much of the transport and deposition of sulfide in the carrier magmas may occur while sulfide is still incorporated in the xenoliths, accounting for the common association of magmatic sulfide-matrix ore breccias and contaminated "taxitic" host rocks. Effective upgrading of so-formed sulfide liquids would require repetitive recycling by processes such as reentrainment, back flow or gravity flow operating over the lifetime of the magma transport system as a whole. In contrast to mafic-hosted systems, komatiite-hosted ores only rarely show an association with externally-derived xenoliths, an observation which is partially due to the predominant formation of ores in lava flows rather than deep-seated intrusions, but also to the much shorter timescales of key component systems in hotter, less viscous magmas. Nonetheless, multiple cycles of deposition and entrainment are necessary to account for the metal contents of komatiite-hosted sulfides. More generally, the time and length scale approach introduced here may be of value in understanding other igneous processes as well as non-magmatic mineral systems.     

北苏鲁仰口地区变辉长岩中锆石U-Pb定年、微量元素和Hf同位素特征及其地质意义

北苏鲁仰口地区出露超高压的变辉长岩.锆石阴极发光图像和其内部矿物包体激光拉曼测试的联合研究结果表明,变辉长岩锆石具有弱发光效应的岩浆韵律环带的核和被改造的强发光效应的边.岩浆韵律环带的核部保存大量而复杂的矿物包体,包括普通辉石(Cpx)+斜方辉石(Opx)+斜长石(P1)+石英(Qtz)+黑云母(Bt)+钛铁矿(Ilm)+磷灰石(Ap);边部保存的矿物包体则相对较少,包括普通辉石(Cpx)+斜方辉石(Opx)+斜长石(Pl)+磷灰石(Ap).尽管岩浆韵律环带核部的稀土元素总合量比被改造的锆石边部明显偏高,但二者稀土元素配分模式具有明显的相似性,主要表现为轻稀土相对亏损,而重稀土明显富集,相应的(La/Yb)N=0.00015～0.00039,并具有明显的负Eu异常(Eu/Eu*=0.20～0.26)、相对明显的正Ce异常(Ce/Ce*=71.5～147.4)和较高的Th/U比值(1.97～2.69).上述特征表明,仰口地区变辉长岩中的锆石均为继承性的岩浆锆石,而没有新生的变质锆石.LA-(MC)-ICP-MS锆石原位U-Pb定年和Lu-Hf同位素分析结果表明,两件锆石样品Y1和Y2的年龄数据所构成的不一致线显示了十分接近的上交点和下交点年龄.其上交点年龄分别为785±15Ma(2σ)和784±12Ma(2σ),应代表原岩的形成时代,表明变辉长岩的原岩与Rodinia超大陆裂解的岩浆事件存在密切的成因关系;而下交点年龄分别为226±24Ma(2σ)和228±26Ma(2σ),与苏鲁其它类型超高压岩石中含柯石英锆石微区记录的变质年龄十分吻合,应代表变辉长岩的超高压变质时代.岩浆结晶锆石的核部具有明显偏高的176Lu/177Hf(0.00044～0.00291)和176Yh/177Hf(0.0165～0.1168)比值,而176Hf/177Hf比值变化于0.281956～0.282048之间,相应的εHf(t)=-8.5～-14.0,tDM2=2.03～2.32Ga,表明仰口地区变辉长岩的原岩起源于古元古代时期的富集地幔或发生部分熔融的下地壳残留体.被改造的岩浆结晶锆石的边部则具有明显偏低的176Lu/177Hf(0.00029～0.00060)和176Yh/177Hf(0.0112～0.0200)比值,而176Hf/177Hf(t)比值变化于0.281953～0.282002之间,相应的εHf(t)=-10.2～-11.9,tDM2=2.12～2.21Ga.与岩浆结晶锆石核部相比,被改造的岩浆锆石边部的176Lu/177Hf、176Yb/177Hf、176Hf/177Hf(t)比值和εHf(t)和tDM2值的变化范围更小,表明中-新三叠纪的超高压变质作用使岩浆结晶锆石边部的Lu-Hf同位素体系发生调整,更趋向于均一化.     

Consequences of crystal shape and fabric on anisotropic permeability in magmatic mush

Crystals that form an interconnected porous network can become preferentially oriented both prior to and during compaction of magmatic mush. This introduces anisotropy in the melt pore-space that can reduce permeability in the direction of compaction and in turn decrease melt flux and compaction rate. Using a number of grain-scale numerical models, the consequences of end-member magmatic fabrics on the directional dependence of permeability are tested over a range in melt fraction from 22 to 77%. As the crystal aspect ratio (i.e. ratio of long to short axis length) increases from 2 to 10, isotropic permeability decreases by a factor of 2 and 5 for randomly oriented prolate and oblate-shaped crystals, respectively, at a melt fraction of 22%. With a flattening fabric, permeability is reduced in the compaction direction no more than approximately a factor of 2 relative to the isotropic permeability at the same melt fraction and crystal shape for both oblate and triaxial prisms. However, permeability is enhanced in directions orthogonal to the compaction direction. For example, permeability is enhanced up to a factor of 11 relative to the isotropic permeability at a melt fraction of 22% for oblate prisms with a ratio of the long to short axis length of 10. Anisotropy in permeability increases as the melt fraction decreases and the crystal aspect ratio increases. Ratios of the principal permeabilities are sufficiently large based on the realistic crystal shapes tested here to warrant including anisotropic permeability into macroscale melt segregation models including those for compaction.     

Compositional variations of several Early Permian magmatic sulfide deposits in the Kalatongke district,southern Altai,western China: With genetic and exploration implications

A Permian magmatic Ni-Cu sulfide deposit cluster occurs in the Kalatongke district in the Southern Chinese Altai Orogenic Belt, western China. These deposits are associated with the mafic units of the Y1, Y2, Y3, Y9 and G21 mafic-intermediate complexes. In this paper we report the first zircon U-Pb ages for the Y3 and G21 intrusions, which are 283.3 ± 1.3 Ma and 281.1 ± 1.5 Ma, respectively. Our new age data confirm that the sulfide-bearing mafic units of the Y1, Y2 (connected with Y1 at depth), Y3, Y9 and G21 intrusions all formed in Early Permian between ∼281 and ∼287 Ma. New and existing petrological-geochemical data show some important regular variations between these deposits. The host lithologies change from olivine-bearing rocks for the Y1-Y2-Y9 deposits to olivine-free rocks such as norite for the Y3 deposit and leucogabbro for the G21 deposit. The olivine Fo contents of the Y1 deposit are up to 82 mol%, which are slightly higher than those of the Y2 deposit (up to 81 mol%) and the Y9 deposit (up to 79 mol%). The average plagioclase An contents of the olivine-bearing Y1-Y2-Y9 deposits are higher than those of the olivine-free Y3-G21 deposits. Among the three deposits (Y1, Y2 and Y3) that occur closely along the same structural lineament, the Ni/Cu ratios of bulk sulfides decrease from the olivine-bearing deposits (Y1 and Y2) to the olivine-free deposit (Y3). The PGE tenors of these deposits (Y1, Y2 and Y3) and the nearby coeval deposits (Y9 and G21) are extremely low, indicating that their parental magmas are severely depleted in PGEs. The variations of PGE tenors within a single deposit as well as among the different deposits are mainly due to variable R factors. The host rocks of these deposits are all characterized by elevated initial ⁸⁷Sr/⁸⁶Sr ratios from 0.7045 to 0.7047, positive εNd values from 4.95 to 6.86, positive εHf values of zircon from 9 to 16, and elevated δ¹⁸O values of zircon from 6.15 to 6.7‰. The isotope data indicate that the parental magmas for these deposits experienced up to ∼15 wt% crustal contamination. The δ³⁴S values of the sulfide minerals from these deposits are from −3.1‰ to 0.4‰, with a peak at −2.2‰, indicating the involvement of crustal sulfur. The isotope data and mineral chemistry together indicate that both olivine fractional crystallization and addition of crustal sulfur played a role in triggering sulfide saturation in the parental magmas for these deposits. Based on higher Ni/Cu ratios of sulfide mineralization in the olivine-bearing intrusions (Y1, Y2, Y9) than in the coeval olivine-free intrusions (Y3, G21), we recommend that Ni exploration in the region focus on the olivine-bearing intrusions that were emplaced in the Early Permian.     

钦杭成矿带东段燕山期中酸性岩浆活动时空演化与成矿规律

钦杭成矿带东段处于华夏地块与扬子地块的交接部位,其特殊的构造背景造就了其独特的岩浆事件与成矿作用。本文详细总结了燕山期中酸性岩浆时空演化与成矿规律,认为钦杭成矿带东段燕山期岩浆活动是连续的,可分为"两期四阶段":早期早阶段(180~160Ma)主要形成I型花岗岩,早期晚阶段(160~145Ma)形成I型、S型花岗岩,晚期早阶段(145~125Ma)以形成S型花岗岩为主(136Ma之后开始形成A型花岗岩),晚期晚阶段(125~100Ma)主要形成A型花岗岩。以东乡-德兴I型花岗岩带为岩浆活动中心,总体经历了从西往东,从I型→S型→A型的演化过程。按成矿专属性,将I型花岗岩分为两种类型:I_1型花岗岩以形成铜(金)铅锌铁多金属矿床为特色,I_2型花岗岩主要形成钨钼矿;将S型花岗岩分为三类:S_1型花岗岩主要形成钨锡钼矿床,高分异的S_2型花岗岩形成铌钽矿,S_3型花岗岩主要形成铅锌银铀矿床;A型花岗岩则具备I型、S型两种花岗岩的成矿特征。与岩浆作用一致,成矿作用也是连续的,可分为相应的"两期四阶段"。成岩成矿的时空演化过程主要受太平洋板块俯冲过程中动力条件变化的控制,导致不同部位的基底地层发生熔融,发生不同程度的壳幔相互作用。     

Magmatic systems of large continental igneous provinces

Large igneous provinces (LIPs) formed by mantle superplume events have irreversibly changed their composition in the geological evolution of the Earth from high-Mg melts (during Archean and early Paleoproterozoic) to Phanerozoic-type geochemically enriched Fe-Ti basalts and picrites at 2.3 Ga. We propose that this upheaval could be related to the change in the source and nature of the mantle superplumes of different generations. The first generation plumes were derived from the depleted mantle, whereas the second generation (thermochemical) originated from the core-mantle boundary (CMB). This study mainly focuses on the second (Phanerozoic) type of LIPs, as exemplified by the mid-Paleoproterozoic Jatulian–Ludicovian LIP in the Fennoscandian Shield, the Permian–Triassic Siberian LIP, and the late Cenozoic flood basalts of Syria. The latter LIP contains mantle xenoliths represented by green and black series. These xenoliths are fragments of cooled upper margins of the mantle plume heads, above zones of adiabatic melting, and provide information about composition of the plume material and processes in the plume head. Based on the previous studies on the composition of the mantle xenoliths in within-plate basalts around the world, it is inferred that the heads of the mantle (thermochemical) plumes are made up of moderately depleted spinel peridotites (mainly lherzolites) and geochemically-enriched intergranular fluid/melt. Further, it is presumed that the plume heads intrude the mafic lower crust and reach up to the bottom of the upper crust at depths ～20 km. The generation of two major types of mantle-derived magmas (alkali and tholeiitic basalts) was previously attributed to the processes related to different PT-parameters in the adiabatic melting zone whereas this study relates to the fluid regime in the plume heads. It is also suggested that a newly-formed melt can occur on different sides of a critical plane of silica undersaturation and can acquire either alkalic or tholeiitic composition depending on the concentration and composition of the fluids. The presence of melt-pockets in the peridotite matrix indicates fluid migration to the rocks of cooled upper margin of the plume head from the lower portion. This process causes secondary melting in this zone and the generation of melts of the black series and differentiated trachytic magmas.