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61.
62.
The distribution of platinum group elements (PGEs) in massive sulfides and hematite–magnetite±pyrite assemblages from the
recently discovered basalt-hosted Turtle Pits hydrothermal field and in massive sulfides from the ultramafic-hosted Logatchev
vent field both on the Mid-Atlantic Ridge was studied and compared to that from selected ancient volcanic-hosted massive sulfide
(VHMS) deposits. Cu-rich samples from black smoker chimneys of both vent fields are enriched in Pd and Rh (Pd up to 227 ppb
and Rh up to 149 ppb) when compared to hematite–magnetite-rich samples from Turtle Pits (Pd up to 10 ppb, Rh up to 1.9 ppb).
A significant positive correlation was established between Cu and Rh in sulfide samples from Turtle Pits. PGE chondrite-normalized
patterns (with a positive Rh anomaly and Pd and Au enrichment), Pd/Pt and Pd/Au ratios close to global MORB, and high values
of Pd/Ir and Pt/Ir ratios indicate mafic source rock and seawater involvement in the hydrothermal system at Turtle Pits. Similarly
shaped PGE chondrite-normalized patterns and high values of Pd/Pt and Pd/Ir ratios in Cu-rich sulfides at Logatchev likely
reflect a similar mechanism of PGE enrichment but with involvement of ultramafic source rocks. 相似文献
63.
64.
白云鄂博碳酸岩墙的稀土和微量元素地球化学及对其成因的启示 总被引:11,自引:1,他引:11
根据矿物组成白云鄂博矿区的碳酸岩岩可墙可分为白云石型、白云石-方解石共存型和方解石型三种类型。REE和微量元素地球化学表明,这三类碳酸岩岩墙为碳酸岩浆演化不同阶段的产物,白云石型和白云石-方解石共存型对应于早期岩浆阶段,其(La/Nd)n、(La/Yb)n比值随稀土总量的增加而增大,方解石型则对应于碳酸岩浆演化的晚期热液阶段,其稀土总量明显富集,但其(La/Nd)n、(La/Y)n和(La/Yb)n比值随稀土总量的增加却有减小的趋势,热液阶段也是白云鄂博稀土矿化的主要阶段。 相似文献
65.
硫化物矿物溶解度与溶液pH值的关系 总被引:2,自引:0,他引:2
硫化物作为自然界常见的一大类矿物 ,由于溶解度很小 ,硫化物对水pH值的影响以及水对它的溶解度影响往往被人们所忽视。通过计算常见硫化物矿物的自由能ΔG0f、溶度积Ksp和溶解度S、绘制logS—pH曲线 ,得出硫化物矿物在不同 pH值条件下的溶解规律 ,水溶液的pH值受硫化物矿物的控制 ;反过来 ,水溶液的pH值也影响着矿物溶解度的大小。此外 ,对硫化物矿物饱和溶液的缓冲范围、缓冲容量和硫化物与溶液pH值相互作用的机理进行了探讨 相似文献
66.
Rodolfo A. TAMAYO Jr Graciano P. YUMUL Jr René C. MAURY Mireille POLVÉ Joseph COTTEN Marcel BOHN 《Resource Geology》2001,51(2):145-164
Abstract: The Antique ophiolite, located in Panay island (west‐central Philippines), corresponds to several tectonic slices within the suture zone between the Philippine Mobile Belt (PMB) and the North Palawan Block (NPB). It includes dismembered fragments of a basaltic sequence, dominantly pillow‐lavas with minor sheet flows, rare exposures of sheeted dikes, isotropic gabbros, subordinate layered mafic and ultramafic rock sequences and serpentinites. Most of the ophiolite units commonly occur as clasts and blocks within the serpentinites, which intrude the whole ophiolitic body, as well as, the basal conglomerate of the overlying Middle Miocene sedimentary formation. The volcanic rock sequence is characterized by chemical compositions ranging from transitional (T)‐MORB, normal (N)‐MORB and to chemistry intermediate between those of MORB and island arc basalt (IAB). The residual upper mantle sequence is harzburgitic and generally more depleted than the upper mantle underlying modern mid‐oceanic ridges. Calculations using whole‐rock and mineral compositions show that they can represent the residue of a fertile mantle source, which have undergone degrees of partial melting ranging from 9‐22.5 %. Some of the mantle samples display chondrite‐nor‐malized REE and extended multi‐element patterns suggesting enrichments in LREE, Rb, Sr and Zr, which are comparable to those found in fore‐arc peridotites from the Izu‐Bonin‐Mariana (IBM) arc system. The Antique ultramafic rocks also record relatively oxidizing mantle conditions (Δlog fO2 (FMQ)=0.9‐3.5). As a whole, the ophiolite probably represents an agglomeration of oceanic ridge and fore‐arc crust fragments, which were juxtaposed during the Miocene collision of the PMB and the NPB. The intrusion of the serpentinites might be either coeval or subsequent to the accretion of the oceanic crust onto the fore‐arc. Volcanogenic massive sulfide (VMS) deposits occur either in or near the contact between the pillow basalts and the overlying sediments or interbedded with the sediments. The morphology of the deposits, type of metals, ore texture and the nature of the host rocks suggest that the formation of the VMS bodies was similar to the accumulation of metals around and in the subsurface of hydrothermal vents observed in modern mid‐oceanic ridge and back‐arc basin rift settings. The podiform chromitites occur as pods and subordinate layers within totally serpentinized dunite in the residual upper mantle sequence. No large coherent chromitite deposit was found since the host dunitic rocks often occur as blocks within the serpentinites. It is difficult to evaluate the original geodynamic setting of the mineralized bodies since the chemistry of the host rocks were considerably modified by alteration during their tectonic emplacement. A preliminary conclusion for Antique is that the VMS is apparently associated with a primitive tholeiitic intermediate MORB‐IAB volcanic suite, the chemistry of which is close to the calculated composition of the liquid that coexisted with the podiform chromitites. 相似文献
67.
Abstract: Two adjacent volcanogenic massive sulfide (VMS) deposits, the Main Malusok and the Malusok Southeast, are delineated within Barangay Tabayo, Siocon, Zamboanga del Norte, Mindanao, Philippines. These deposits comprise massive to semi-massive sulfide lenses representing the down-dip equivalent of oxidized gossans. The massive sulfides have a primary mineral assemblage of pyrite-chalcopyrite-sphalerite with significant amounts of supergene copper in the form of chal-cocite. Owing to structural and metamorphic overprinting combined with intense alteration, primary textures are generally obliterated. Rock types are classified according to dominant mineral assemblages whereas the main lithologic units comprising the Malusok volcanic package are divided based on the position of each unit relative to the mineralized zone. The main lithologic units are designated as the hanging wall, the host, and the footwall sequences. In correlating the stratigraphy of the Main Malusok zone with that of the Malusok Southeast zone, a chlorite/epidote-rich interval located at the base of the hanging wall sequence serves as a distinct stratigraphic marker from which all lithologies are referred to. Comparisons between the stratigraphy of the two areas show that massive to semi-massive sulfide lenses are confined within a single stratigraphic interval representing the favorable horizon for the entire Malusok area. However, differences exist relative to style of mineralization and configuration of the altered interval between the Main Malusok and the Malusok Southeast VMS deposits. Based on characteristics exhibited by each individual deposit, it is inferred that the Main Malusok VMS deposit overlies a feeder zone whereas the Malusok Southeast sulfide lenses represent satellite deposits and transported blocks. 相似文献
68.
安徽沿江地区中生代岩浆岩的基本特点 总被引:23,自引:6,他引:23
安徽沿江地区位于长江中下游岩浆带中段,中生代岩浆活动强烈,类型复杂,特点突出。它具有夹心饼干式分带现象。中间为富碱的高钾钙碱性岩系和橄榄安粗岩系;两侧为钙碱性岩系。中间的岩浆岩具有高钾富碱、高Sr,低Mg、Cr、Ni,εNd变化大但Isr变化小且较低以及岩浆演化的多样性为特点。 相似文献
69.
我国一些铜镍硫化物矿床主要金属矿物的特征 总被引:7,自引:0,他引:7
镍、铜共生的铜镍硫化物矿床是镍矿也是铜矿的重要矿床类型。磁黄铁矿,镍黄铁矿、黄铜矿是这类矿床的主要金属矿物。它们的某些矿物学特征,特别是微量元素Co/Ni比值,与其他铜矿类型明显不同,这三种矿物组成不同于任何其他铜矿类型的典型矿物共生组合, 形成特殊的海绵损铁状、球滴状构造。 相似文献
70.
在瑞典,硫化物矿尾矿污染水的淋滤造成巨大的环境污染问题。本文概述一项利用天然土覆盖尾矿、最大限度地减少淋滤水的调查报告。研究表明,天然土渗水性是如此之高,以致于起不到明显的隔水效果。天然土盖层只能减少高降雨量期或迅速化雪期的渗水量,而且只对淋滤水峰值有作用。但是,作为一种蓄水体,位于尾矿顶部的密封盖层具有重要意义,它可以增加蒸腾损失。 相似文献