An experimental study on felsic rock–artificial seawater interaction: implications for hydrothermal alteration and sulfate formation in the Kuroko mining area of Japan

Experimental studies on the interactions between artificial seawater (ASW) and fresh rhyolite, perlite and weakly altered dacitic tuff containing a small amount of smectite suggest changing cation transfer during smectite-forming processes. Initially, dissolution of K from the rocks accompanies incorporation of Mg and Ca from ASW during both earlier (devitrification stage) and later smectite formation, whereas Ca incorporated with early smectite formation redissolves with progressive reaction. Barium mobility increases toward the later smectite-forming reactions. Therefore, the large amounts of barite, anhydrite and gypsum in Kuroko ore deposits are considered to have precipitated from hydrothermal solutions derived from the interaction with previously altered felsic rocks during late smectite formation, rather than by the reaction with fresh felsic rocks.Editorial handling: D. Lentz     

金龙——丘岭金矿床成矿流体的储运规律及区域找金方向

金龙山——丘岭金矿区含金矿源为层上泥盆统南羊山组和下石炭统袁家沟组。组成含金矿源层岩石为高频互层的细碎屑岩-碳酸盐岩，其中细砂岩、粉砂岩、碳酸盐岩含成矿流体物性较好．页岩、板岩含成矿流体物性较差，构成屏蔽层。金鸡岭Ⅰ级复式向斜控制着金、砷、锑等异常范围；松枣Ⅱ级复式背斜控制着金的矿化带；金龙山-丘岭金矿Ⅲ级背斜控制着金的矿（化）体；镇安——板岩镇断裂的次级断裂是金矿化体的容矿有利位置。在成矿过程中，构造变形与成矿流体的形成、运移及储集密切相关。其规律是：①原生构造导致成矿流体的初次聚集。②第一期构造变形导致成矿流体的聚集。③第二期构造变形导致成矿流体运移及金矿床形成。此期变形是金的主要成矿期。④第三期构造变形使成矿流体进一步聚集和金矿体的富集。⑤第四期构造变形是石英方解石脉的形成时期。总结出矿床形成模式。据此提出了在4种不同的构造部位找金的方向。     

西藏自治区乃东县劣布铜矿综合地质特征

文章介绍区域地质背景、矿区地物化特征，对成矿时代、流体包裹体特征进行初步研究，并指出找矿远景，希望对矿区的矿产勘查具有借鉴和指导意义。     

广西南丹地区有色金属尾砂型人工矿床地质特征及其资源化

广西南丹地区尾矿分布于大厂、车河、芒场等矿区。尾砂来自以锡石为主的多金属矿床，尾砂中除Sn，Pb，Zn，Ag，Sb的质量分数达到工业指标外，Au亦达到综合利用指标。通过试验证明，对尾矿中的细微粒锡石可采用风力分级选矿、磁选和化学选矿等方法回收；尾砂中的非金属资源可作为填充材料、水泥原料利用，使尾砂型人工矿床充分的资源化。     

辽宁省鞍本地区铁尾矿资源现状及其开发利用

辽宁省的鞍山、本溪两市为我国重要的钢铁基地，各矿山长期生产遗留的铁尾矿问题越来越引起人们的重视，如污染环境、诱发地质灾害等，如何解决已成为地质、环保、水工界的关注。     

Effect of suction on the mechanical behaviour of iron ore rock

The effect of suction on the behaviour of iron ore has been studied from both physical and mechanical points of view. The porosity and the suction phenomena have been analysed using different experimental techniques. Uniaxial compressive tests on partially saturated samples have shown that the suction is responsible for strength and cohesion improvement. Considering the theory of partially saturated porous soils of Coussy and Dangla (Mécanique des sols non saturés (2002 edn). Hermès Science: 2002; 390), we have proposed a constitutive law for partially saturated iron ore. The real increase in the apparent cohesion due to the capillary attraction forces is overestimated if the yield function is written in terms of effective stresses. The effect of the capillary cohesion has been modelled with a function in the expression of the apparent cohesion of the yield function. The effect of suction on the mechanical behaviour has been represented in the effective stresses space and in the total stresses space like the Alonso model (Géotechnique 1990; 40 :405–430). Copyright © 2005 John Wiley & Sons, Ltd.     

Diagenetic paths in the margin of a Triassic Basin: NW zone of the Iberian Chain, Spain

Buntsandstein deposits generated in a slowly subsiding basin on the western margin of the Iberian Chain are represented by a stratigraphic succession of fluvial deposits less than 100 m thick (conglomerates, sandstones, and shales). Diagenetic processes in sandstones can be grouped as eodiagenetic, mesodiagenetic, and telodiagenetic. Eodiagenesis can be associated with Muschelkalk, Keuper, and probably early Jurassic times. Mesodiagenesis is probably related to Jurassic times. Diagenetic chemical reactions suggest a maximum burial less than 1.5 km and low temperatures (<120°C). Patterns of porosity reduction by compaction and cementation suggest four diagenetic stages: (1) Loss of primary porosity by early mechanical compaction; (2) early cementation (K-feldspar and dolomite); (3) dissolution of cements; and (4) framework collapse by re-compaction. These stages are manifested by the presence of two types of sandstone. Type I sandstones present high intergranular volume (mean, 30%). Type II sandstones are characterized by high compactional porosity loss and exhibit low values of intergranular volume (mean, 16.9%). Type II sandstones are associated with the dissolution of cement and later re-compaction of type I sandstones. An intermediate telodiagenetic phase is deduced and related to the sharp unconformity between Lower Cretaceous sediments and the underlying sediments. This suggests that a mechanically unstable framework collapsed during the Cretaceous, generating type II sandstones. The analyzed diagenetic paths have a wide applicability on similar marginal areas of rift basins.     

Progradational and backstepping shoreface deposits in the Ladinian to Early Norian Snadd Formation of the Barents Sea

Shoreface sandstone deposits within the Early Carnian part of the Snadd Formation of the Norwegian Barents Sea can be traced for hundreds of kilometres in the depositional strike direction and for tens of kilometres in the depositional‐dip direction. This study uses three‐dimensional seismic attribute mapping and two‐dimensional regional seismic profiles to visualize the seismic facies of these shoreface deposits and to map their internal stratigraphic architecture at a regional scale. The shoreface deposits are generally elongate but show variable width from north‐east to south‐west, which corresponds to a sediment source in the northern part of the basin and a southward decrease in longshore sediment transport. The Snadd Formation presents an example of how large‐scale progradational shoreface deposits develop. The linear nature of its shoreface deposits contrasts with more irregular, cuspate wave‐dominated deltaic shorelines that contain river outlets, and instead implies longshore drift as the main sediment source. In map view, discrete sets of linear features bounded by truncation surfaces scale directly to beach ridge sets in modern counterparts. The shoreface deposits studied here are characteristic in terms of scale and basin‐wide continuity, and offer insight into the contrast between shallow marine deposition under stable Triassic Greenhouse and fluctuating Holocene Icehouse climates. Findings presented herein are also important for hydrocarbon exploration in the Barents Sea, because they describe a hitherto poorly understood reservoir play in the Triassic interval, wherein the most prominent reservoir plays have so far been considered to be found in channelized deposits in net‐progradational delta‐plain strata that form the topsets to shelf‐edge clinoforms. The documented presence of widespread wave‐dominated shoreface deposits also has implications for how the relative importance of different sedimentary processes is considered within the basin during this period.     

Granitoid emplacement by multiple sheeting during Variscan dextral transpression: The Saint-Laurent – La Jonquera pluton (Eastern Pyrenees)

The structural study of the Saint-Laurent – La Jonquera pluton (Eastern Pyrenees), a Variscan composite laccolithic intrusion emplaced in metasedimentary and gneissic rocks of the Roc de Frausa dome, by means of the anisotropy of magnetic susceptibility (AMS) technique has allowed the determination of the nature and orientation of its magmatic fabrics. The magmatic foliation has a predominant NE–SW strike and the mean lineation is also NE–SW trending with a shallow plunge. A strain gradient is measured so that the tonalites to granodiorites that form the basal parts of the pluton, and are intruded into amphibolite-facies metamorphic rocks, recorded the highest anisotropies, whereas the monzogranites and leucogranites, emplaced into upper crustal, low-grade metamorphic rocks, are weakly deformed. These results point to the synkinematic sequential emplacement of multiple granitoid sheets, from less to more differentiated magmatic stages, during the Late Carboniferous D₂ event characterized by an E–W-trending dextral transpression. The magmatic foliation appears locally disturbed by the effects of two tectonic events. The first of them (D₃) produced mylonitization of granitoids along NW–SE retrograding shear zones and open folds in the host Ediacaran metasediments of the Roc de Frausa massif, likely during late Variscan times. Interference between D₂ and D₃ structures was responsible for the dome geometry of the whole Roc de Frausa massif. The second and last perturbation consisted of local southward tilting of the granitoids coupled to the Mesozoic–Cenozoic cover during the Alpine.     

泡沫塑料吸附分离富集-电感耦合等离子体质谱法测定稀土矿石中的镓

采用电感耦合等离子体质谱法(ICP-MS)测定稀土矿石中的镓,高含量的稀土元素会造成严重的质谱干扰。本文采用聚氨酯泡沫塑料在6 mol/L盐酸介质中吸附样品溶液中的镓后,以0.5 mol/L氯化铵水浴加热解脱30 min,镓的吸附-解脱效率超过99%,稀土元素等干扰物质基本不进入解脱液中,即在富集镓的同时实现了镓与基体元素的高效分离,降低了质谱干扰。本方法检出限低(0.022μg/g),经土壤及水系沉积物标准物质验证,镓的测定值与标准值吻合(绝对偏差为0.38%~4.70%),实际稀土矿石样品的加标回收率为94.1%~100.6%,精密度(RSD)低于4%(n=12),可应用于分析一般地质样品以及稀土矿石中的镓。