Plagioclase in the Skaergaard intrusion. Part 1: Core and rim compositions in the layered series

The anorthite content of plagioclase grains (X_An) in 12 rocks from the layered series of the Skaergaard intrusion has been studied by electron microprobe (typically ∼30 core and ∼70 rim analyses per thin section). Mean core compositions vary continuously from An₆₆ at the base of the layered series (LZa) to An_32–30 at the top. On the other hand, crystal rims are of approximately constant composition (An_{50 ± 1}) from the LZa to the lower Middle Zone (MZ). Above the MZ, core and rim compositions generally overlap. Profiles across individual plagioclase grains from the lower zone show that most crystals have an external zone buffered at X_An ∼50 ± 1. The simplest explanation for these features is that during postcumulus crystallization in the lower zone, interstitial liquids passed through a density maximum. This interpretation is consistent with proposed liquid lines of descent that predict silica enrichment of the liquid associated with the appearance of cumulus magnetite.     

Tectonic mechanisms associated with P–T paths of regional metamorphism: alternatives to single-cycle thrusting and heating

Metamorphic pressure (P)–temperature (T) paths are commonly used as tools to interpret the tectonic history of orogenic belts, those deformed belts of rocks that record past activity along active plate margins. Many studies and reviews relating P–T path development to tectonics have focused on thrusting–thermal relaxation cycles, with special emphasis on collisional processes. Other studies have assumed that P–T paths resulted from a single tectono-metamorphic event that accounted for the entire burial–exhumation history of the rocks. In many cases, such assumptions may prove invalid.This paper speculates on the relationship of tectonic processes other than thrusting–heating to P–T path development. The processes discussed herein include subduction initiation, triple-junction interactions, initiation and shut off of arc volcanism, subcontinental delamination, and hot spot migration. All of these processes may leave a signature in the metamorphic rock record. Examples are presented from a number of localities, most of which are from the Pacific Rim. Although thrusting–heating cycles have influenced metamorphic evolution in many orogenic belts, the potential impact of other types of tectonic mechanisms should not be overlooked.     

Ga/Mg ratio as a new geochemical tool to differentiate magmatic from metamorphic blue sapphires

Using ICP-MS–LA analyses, we demonstrate that the use of the Ga/Mg ratio, in conjunction with the Fe concentration, is an efficient tool in discriminating between “metamorphic” and “magmatic” blue sapphires. Magmatic blue sapphires found in alkali basalts (e.g. southeastern Asia, China, Africa) are commonly medium-rich to rich in Fe (with average contents between 2000 and 11000 ppm), high in Ga (> 140 ppm), and low in Mg (generally < 20 ppm) with high Ga/Mg ratios (> 10). Conversely, metamorphic blue sapphires found in basalts (e.g. Pailin pastel) and in metamorphic terrains (e.g. Mogok, Sri Lanka, Ilakaka) are characterized by low average iron contents (< 3000 ppm), low Ga contents (< 75 ppm), and high Mg values (> 60 ppm) with low average Ga/Mg ratios (< 10). Basaltic magmatic sapphires have Fe, Ga and Mg contents similar to those obtained for primary magmatic sapphires found in the Garba Tula syenite. This suggests that these both sets of sapphires have a possible common “syenitic” origin, as previously proposed from other criteria. In addition, plumasite-related sapphires and metamorphic sapphires also exhibit similar composition in trace elements. Based on results from the present study, we suggest that fluid circulations during a metamorphic stage produced metasomatic exchanges between mafic and acidic rocks (plumasite model), thus explaining the high Mg contents and converging Ga/Mg ratios observed in metamorphic sapphires.     

湘南宝山地区燕山期成矿花岗岩岩浆作用研究

本文对湘南宝山花岗闪长斑岩进行了系统的锆石和磷灰石U-Pb定年、岩石地球化学以及锆石Hf同位素研究,并探讨了宝山花岗闪长斑岩的岩石成因和构造意义。锆石和磷灰石的LA-ICP-MS U-Pb定年显示,宝山花岗闪长斑岩的成岩年龄为160Ma。综合元素和同位素地球化学证据,宝山花岗闪长斑岩的成因可能为新生地壳与古老地壳的混合熔融,同时宝山花岗闪长斑岩中发现的890±20Ma的继承锆石,验证了新元古代新生地壳的参与。磷灰石的主微量元素研究显示花岗闪长斑岩具有较高的氧逸度和Cl含量,Sr/Th比值具有较大变化,而La/Sm比值变化不大等特征,表明形成花岗闪长斑岩岩浆的母岩受到俯冲板片脱水形成的流体交代作用影响。在上述过程中,富含Cl和H₂O的流体从板片中释放出来,引发地幔楔熔融,并对矿床中成矿金属元素进行提取。由于古太平洋板块俯冲引发的伸展-减薄运动,在地幔上涌过程中,新元古代新生地壳发生部分熔融,这些高温岩浆底侵老地壳源区,诱发老地壳部分熔融,进而发生了强烈的壳-壳混合作用,产生花岗闪长质岩浆。

     

Magmatic stoping as an important emplacement mechanism of Variscan plutons: evidence from roof pendants in the Central Bohemian Plutonic Complex (Bohemian Massif)

The presence of numerous roof pendants, stoped blocks and discordant intrusive contacts suggests that magmatic stoping was a widespread, large-scale process during the final construction of the Central Bohemian Plutonic Complex, Bohemian Massif. The measured total length of the discordant contacts that cut off the regional cleavage and were presumably formed by stoping corresponds to about half of all contacts with the upper-crustal host rocks. In addition, at least some of the straight, cleavage-parallel intrusive contacts may also have recorded complex intrusive histories ending with piecemeal stoping of thin cleavage-bounded host rock blocks into the magma chamber. Based on the above, we argue that the fast strain rates required for emplacement of large plutons of the Central Bohemian Plutonic Complex into brittle upper crustal host rocks over relatively short-time span could not have been accommodated entirely by slow ductile flow or slip along faults. Instead, the emplacement was largely accommodated by much faster thermal cracking and extensive stoping independent of regional tectonic deformation. Finally, we emphasize that magmatic stoping may significantly modify the preserved structural patterns around plutons, may operate as an important mechanism of final construction of upper-crustal plutons and thus may contribute to vertical recycling and downward transport of crustal material within the magma plumbing systems in the crust.     

Magmatic systems of large continental igneous provinces

Large igneous provinces (LIPs) formed by mantle superplume events have irreversibly changed their composition in the geological evolution of the Earth from high-Mg melts (during Archean and early Paleoproterozoic) to Phanerozoic-type geochemically enriched Fe-Ti basalts and picrites at 2.3 Ga. We propose that this upheaval could be related to the change in the source and nature of the mantle superplumes of different generations. The first generation plumes were derived from the depleted mantle, whereas the second generation (thermochemical) originated from the core-mantle boundary (CMB). This study mainly focuses on the second (Phanerozoic) type of LIPs, as exemplified by the mid-Paleoproterozoic Jatulian–Ludicovian LIP in the Fennoscandian Shield, the Permian–Triassic Siberian LIP, and the late Cenozoic flood basalts of Syria. The latter LIP contains mantle xenoliths represented by green and black series. These xenoliths are fragments of cooled upper margins of the mantle plume heads, above zones of adiabatic melting, and provide information about composition of the plume material and processes in the plume head. Based on the previous studies on the composition of the mantle xenoliths in within-plate basalts around the world, it is inferred that the heads of the mantle (thermochemical) plumes are made up of moderately depleted spinel peridotites (mainly lherzolites) and geochemically-enriched intergranular fluid/melt. Further, it is presumed that the plume heads intrude the mafic lower crust and reach up to the bottom of the upper crust at depths ～20 km. The generation of two major types of mantle-derived magmas (alkali and tholeiitic basalts) was previously attributed to the processes related to different PT-parameters in the adiabatic melting zone whereas this study relates to the fluid regime in the plume heads. It is also suggested that a newly-formed melt can occur on different sides of a critical plane of silica undersaturation and can acquire either alkalic or tholeiitic composition depending on the concentration and composition of the fluids. The presence of melt-pockets in the peridotite matrix indicates fluid migration to the rocks of cooled upper margin of the plume head from the lower portion. This process causes secondary melting in this zone and the generation of melts of the black series and differentiated trachytic magmas.     

Compositional variations of several Early Permian magmatic sulfide deposits in the Kalatongke district,southern Altai,western China: With genetic and exploration implications

A Permian magmatic Ni-Cu sulfide deposit cluster occurs in the Kalatongke district in the Southern Chinese Altai Orogenic Belt, western China. These deposits are associated with the mafic units of the Y1, Y2, Y3, Y9 and G21 mafic-intermediate complexes. In this paper we report the first zircon U-Pb ages for the Y3 and G21 intrusions, which are 283.3 ± 1.3 Ma and 281.1 ± 1.5 Ma, respectively. Our new age data confirm that the sulfide-bearing mafic units of the Y1, Y2 (connected with Y1 at depth), Y3, Y9 and G21 intrusions all formed in Early Permian between ∼281 and ∼287 Ma. New and existing petrological-geochemical data show some important regular variations between these deposits. The host lithologies change from olivine-bearing rocks for the Y1-Y2-Y9 deposits to olivine-free rocks such as norite for the Y3 deposit and leucogabbro for the G21 deposit. The olivine Fo contents of the Y1 deposit are up to 82 mol%, which are slightly higher than those of the Y2 deposit (up to 81 mol%) and the Y9 deposit (up to 79 mol%). The average plagioclase An contents of the olivine-bearing Y1-Y2-Y9 deposits are higher than those of the olivine-free Y3-G21 deposits. Among the three deposits (Y1, Y2 and Y3) that occur closely along the same structural lineament, the Ni/Cu ratios of bulk sulfides decrease from the olivine-bearing deposits (Y1 and Y2) to the olivine-free deposit (Y3). The PGE tenors of these deposits (Y1, Y2 and Y3) and the nearby coeval deposits (Y9 and G21) are extremely low, indicating that their parental magmas are severely depleted in PGEs. The variations of PGE tenors within a single deposit as well as among the different deposits are mainly due to variable R factors. The host rocks of these deposits are all characterized by elevated initial ⁸⁷Sr/⁸⁶Sr ratios from 0.7045 to 0.7047, positive εNd values from 4.95 to 6.86, positive εHf values of zircon from 9 to 16, and elevated δ¹⁸O values of zircon from 6.15 to 6.7‰. The isotope data indicate that the parental magmas for these deposits experienced up to ∼15 wt% crustal contamination. The δ³⁴S values of the sulfide minerals from these deposits are from −3.1‰ to 0.4‰, with a peak at −2.2‰, indicating the involvement of crustal sulfur. The isotope data and mineral chemistry together indicate that both olivine fractional crystallization and addition of crustal sulfur played a role in triggering sulfide saturation in the parental magmas for these deposits. Based on higher Ni/Cu ratios of sulfide mineralization in the olivine-bearing intrusions (Y1, Y2, Y9) than in the coeval olivine-free intrusions (Y3, G21), we recommend that Ni exploration in the region focus on the olivine-bearing intrusions that were emplaced in the Early Permian.     

渤海湾盆地南堡凹陷断裂控藏特征研究

南堡凹陷为渤海湾盆地的一个新生代富生烃凹陷,内部断层十分发育,大量的油气藏都围绕断裂分布。根据断裂平面及剖面组合特征,断裂平面组合样式可分为4种：平行状、交织状、梳状和帚状;剖面组合分为3种：复“y”形组合、花状组合及阶梯式组合。根据断裂、砂体及油气藏的分布特征,发现二级和三级生长断层凹面储集厚度较大、且砂体孔渗性较好,是油气运移的主要方向。反向旋转断层组合的断层下盘和同向旋转断层组合的断层上盘是油气聚集的有利部位。但由于断层带的分带性,上诱导裂缝带相对下诱导裂缝带渗透性好。上诱导裂缝带利于油气运移,下诱导裂缝带利于封堵油气,油气的最有利聚集部位为反向旋转断层组合的下盘。     

云开地区燕山期岩浆活动与金银矿化关系

通过对广西云开地区岩浆活动与金银矿化关系的研究表明,金银矿主要是燕山期岩浆作用形成的;矿化岩体与金银矿化在空间位置上存在“东向性”和“定距性”规律;岩浆岩岩石化学成分、岩浆分异程度、成因类型的不同,导致了金银成矿的显著差异;燕山期岩浆活动对金银成矿,既提供了成矿热液,也提供了主要的物质来源。     

基于CFP的岩溶管道流数值模拟研究——以桂林寨底地下河子系统为例

为了描述岩溶多重含水介质存在非达西流问题,研究管道流CFP模型在岩溶区数值模拟中的应用。在分析管道流CFP基本原理的基础上,通过建立概念模型算例(5个管道,上下临界雷诺数分别为2 000和4 000),探讨不同管道水文地质参数对出口流量及水流状态的影响,并对参数敏感性进行分析,最后将CFPM1模型应用于广西寨底岩溶地下河系统,探讨在实际应用中的管道流模型适用性。概念模型结果表明,参数敏感度从大到小依次为:管道直径、水力梯度、管道渗透系数、弯曲度及粗糙度,流量与雷诺数随管道参数增大而增大,水流状态从层流变为紊流。寨底岩溶管道流模型中3个观测井及地下河出口实测流量表明CFPM1能较好地模拟出岩溶地下水水位变化趋势。得出结论:CFPM1管道流模型允许岩溶管道与基岩含水层进行水流交换,能够较好地刻画岩溶区管道介质非达西流特征,但管道参数获取较为困难,且不能刻画岩溶管道形态变化。该方法具有一定通用性,可为实际应用提供指导。