安徽铜陵中生代侵入岩地质地球化学特征再认识及成因讨论

安徽铜陵地区是我国最著名的铜多金属矿产地,岩浆岩出露广泛,岩浆作用与成矿关系密切.作者广泛收集了前人对铜陵地区中生代岩浆岩的研究资料和成果,并在此基础上进行了仔细的岩相学观察和深入的岩石学、岩石化学和微量元素及同位素地球化学研究,系统总结了该区中生代侵入岩的地质地球化学特征,并探讨了其成因机制.研究认为:①铜陵地区中酸性侵入岩形成于晚侏罗世-早白垩世(135 ～ 147Ma),岩浆活动持续时间大约为10～15Ma;岩体沿近东西向深断裂呈带状分布,浅成侵入产出,受多期不同方向和性质的断裂控制.②依据Q-A-P图解确定区内侵入岩主要为辉石闪长岩、石英(二长)闪长岩和花岗闪长岩3类中酸性闪长质岩石,均属亚碱性高钾钙碱性系列.③3类侵入岩具有相似的微量元素、稀土元素和Pb-Sr-Nd-O同位素地球化学特征,反映原始岩浆起源于富集岩石圈地幔,受到壳源物质的混染.④3类侵入岩可能是地壳深部带状岩浆房不同岩浆层中的岩浆与构造运动诱发的深断裂相沟通并随机地上升、脉动式侵位形成的;深部岩浆房中的带状岩浆层可能是由于温度梯度引起扩散对流作用进而发生一定程度的熔离分异作用所致;岩浆演化过程中存在镁铁矿物及磷灰石和锆石等矿物的结晶分异作用.⑤铜陵地区中生代岩浆活动的大地构造背景是大陆板块内部,岩浆作用与晚侏罗纪古太平洋板块的俯冲作用密切相关,但同时受区域前中生代基底构造的制约;侵入岩原始岩浆起源于挤压向拉张转换的动力学背景下的岩石圈地幔加厚之后的减压熔融并底侵下地壳岩石.     

阿尔山火山区地壳上地幔电性结构初探

在阿尔山活火山区一条北北西向测线上进行了7个大地电磁测深点的观测。2-D解释结果表明,研究区内新、老两条火山带可能存在通往深部的岩浆通道。其中,新发现的活火山带地下在10~12km还保持着较高的热状态,很可能富含流体,在30~50km处可能是地幔向上的供热通道;而老火山带30km以上可能存在一个正在冷却的岩浆通道,两条火山条带的深部可能是同源的。     

徐淮地区早白垩世adakitic岩石的年代学和Pb同位素组成:对岩浆源区与华北克拉通东部构造深化的制约

本文报道了徐淮地区5个早白垩世adakitic岩体全岩的Pb同位素组成和其中3个岩体的锆石LA-ICP-MS U-Pb定年结果,并讨论了岩浆源区的性质和华北克拉通东部中生代早期的构造演化.结果表明,班井、丰山和蔡山岩体形成于早白垩世,其206Pb/238U加权平均年龄分别为127±1Ma、129±2Ma和131±1Ma.利国、班井、夹沟、丰山和蔡山岩体的全岩(206Pb/024Pb)t、(207Ph/204Pb)t和(208Pb/204Pb)t初始比值分别变化于17.957～18.620、15.508～15.655和38.129～38.710之间.综合早白垩世adakitic岩石高的放射成因Pb同位素组成以及继承锆石年代学和其中榴辉岩类捕虏体锆石U-Pb年代学和地球化学的研究成果,可以认为华北克拉通东部徐淮地区早白垩世adakitic岩石的岩浆源区以断离的扬子克拉通俯冲板片(基底物质)为主,并有拆沉的华北克拉通基底物质的参与.这与扬子克拉通沿北西方向俯冲于华北克拉通之下的构造模式相吻合.     

The exsolution of magmatic hydrosaline chloride liquids

Hydrosaline liquid represents the most Cl-enriched volatile phase that occurs in magmas, and the exsolution of this phase has important consequences for processes of hydrothermal mineralization and for volcanic emission of Cl to the atmosphere. To understand the exsolution of hydrosaline liquids in felsic to mafic magmas, the volatile abundances and (Cl/H₂O) ratios of more than 1000 silicate melt inclusions (MI) have been compared with predicted and experimentally determined solubilities of Cl and H₂O and associated (Cl/H₂O) ratios of silicate melts that were saturated in hydrosaline chloride liquid with or without aqueous vapor in hydrothermal experiments. This approach identifies the minimum volatile contents and the values of (Cl/H₂O) at which a hydrosaline chloride liquid exsolves from any CO₂- or SO₂-poor silicate melt. Chlorine solubility is a strong function of melt composition, so it follows that Cl solubility in magmas varies with melt evolution. Computations show that the (Cl/H₂O) ratio of residual melt in evolving silicate magmas either remains constant or increases to a small extent with fractional crystallization. Consequently, the initial (Cl/H₂O) in melt that is established early during partial melting has important consequences for the exsolution of vapor, vapor plus hydrosaline liquid, or hydrosaline liquid later during the final stages of melt ascent, emplacement, and crystallization or eruption. It is demonstrated that the melt (Cl/H₂O) controls the type of volatile phase that exsolves, whereas the volatile abundances in melt control the relative timing of volatile phase exsolution (i.e., the time of earliest volatile exsolution relative to the rate of magma ascent and crystallization history).

Comparing melt inclusion compositions with experimentally determined (Cl/H₂O) ratios and corresponding volatile solubilities of hydrosaline liquid-saturated silicate melts suggests that some fractions of the eruptive, calc-alkaline dacitic magmas of the Bonnin and Izu arcs should have saturated in and exsolved hydrosaline liquid at pressures of 2000 bars. Application of these same melt inclusion data to the predicted volatile solubilities of Cu-, Au-, and Mo-mineralized, calc-alkaline porphyritic magmas suggests that the chemical evolution of dioritic magmas to more-evolved quartz monzonite compositions involves a dramatic reduction in Cl solubility that increases the probability of hydrosaline liquid exsolution. The prediction that quartz monzonite magmas should exsolve a hydrosaline chloride liquid, that is potentially mineralizing, is consistent with the general observation of metal-enriched, hypersaline fluid inclusions in the more felsic plutons of numerous porphyry copper systems. Moreover, comparing the volatile contents of melt inclusions from the potassic, alkaline magmas of Mt. Somma-Vesuvius with the predicted (Cl/H₂O) ratios of hydrosaline liquid-saturated melts having compositions similar to those of the volatile-rich, alkaline magmas associated with the orthomagmatic gold–tellurium deposits of Cripple Creek, Colorado, suggests that hydrosaline chloride liquid should have exsolved at Cripple Creek as the magmas evolved to phonolite compositions. This prediction is consistent with the well-documented role of Cl-enriched, mineralizing hydrothermal fluids at this major gold-mining district.     

西准噶尔夏尔莆岩体岩浆混合岩石化学证据

夏尔莆岩体是西准噶尔地区较典型岩浆混合花岗岩.岩体由寄主岩石(中酸性侵入岩)、微粒镁铁质包体和中基性岩墙群3部分组成.寄主岩石(中酸性侵入岩)与微细粒镁铁质包体具相似岩石化学特征,有明显元素双扩散现象.在图解中,寄主岩石具良好线型岩浆混合演化特征,微细粒镁铁质包体也位于演化趋势上,显示两者具共同成因联系,中基性岩墙群具独立演化趋势,属不同岩浆端元.岩石化学显示的岩浆混合信息与岩相学表现的岩浆混合特征完全吻合,支持岩浆混合成因认识,为解决该岩体成因分歧提供重要依据.     

金平阿德博铜镍矿区王家寨矿段矿床成因探讨

矿床与华力西期超基性一基性一中性岩浆杂岩关系密切,成矿专属性明显。先期矿浆在杂岩体中初步熔离富集,后期矿浆在压力作用下沿断裂贯入,经期后热液改造再富集成矿。     

Geochemical and Sr–Nd–Pb isotopic compositions of the Eocene Dölek and Sariçiçek Plutons, Eastern Turkey: Implications for magma interaction in the genesis of high-K calc-alkaline granitoids in a post-collision extensional setting

The major and trace elements and Sr–Nd–Pb isotopes of the host rocks and the mafic microgranular enclaves (MME) gathered from the Dölek and Sariçiçek plutons, Eastern Turkey, were studied to understand the underlying petrogenesis and geodynamic setting. The plutons were emplaced at  43 Ma at shallow depths ( 5 to 9 km) as estimated from Al-in hornblende geobarometry. The host rocks consist of a variety of rock types ranging from diorite to granite (SiO₂ = 56.98–72.67 wt.%; Mg# = 36.8–50.0) populated by MMEs of gabbroic diorite to monzodiorite in composition (SiO₂ = 53.21–60.94 wt.%; Mg# = 44.4–53.5). All the rocks show a high-K calc-alkaline differentiation trend. Chondrite-normalized REE patterns are moderately fractionated and relatively flat [(La/Yb)_N = 5.11 to 8.51]. They display small negative Eu anomalies (Eu/Eu = 0.62 to 0.88), with enrichment of LILE and depletion of HFSE. Initial Nd–Sr isotopic compositions for the host rocks are ε_Nd(43 Ma) = − 0.6 to 0.8 and mostly I_Sr = 0.70482–0.70548. The Nd model ages (T_DM) vary from 0.84 to 0.99 Ga. The Pb isotopic ratios are (²⁰⁶Pb/²⁰⁴Pb) = 18.60–18.65, (²⁰⁷Pb/²⁰⁴Pb) = 15.61–15.66 and (²⁰⁸Pb/²⁰⁴Pb) = 38.69–38.85. Compared with the host rocks, the MMEs are relatively homogeneous in isotopic composition, with I_Sr ranging from 0.70485 to 0.70517, ε_Nd(43 Ma) − 0.1 to 0.8 and with Pb isotopic ratios of (²⁰⁶Pb/²⁰⁴Pb) = 18.58–18.64, (²⁰⁷Pb/²⁰⁴Pb) = 15.60–15.66 and (²⁰⁸Pb/²⁰⁴Pb) = 38.64–38.77. The MMEs have T_DM ranging from 0.86 to 1.36 Ga. The geochemical and isotopic similarities between the MMEs and their host rocks indicate that the enclaves are of mixed origin and are most probably formed by the interaction between the lower crust- and mantle-derived magmas. All the geochemical data, in conjunction with the geodynamic evidence, suggest that a basic magma derived from an enriched subcontinental lithospheric mantle, probably triggered by the upwelling of the asthenophere, and interacted with a crustal melt that originated from the dehydration melting of the mafic lower crust at deep crustal levels. Modeling based on the Sr–Nd isotope data indicates that  77–83% of the subcontinental lithospheric mantle involved in the genesis. Consequently, the interaction process played an important role in the genesis of the hybrid granitoid bodies, which subsequently underwent a fractional crystallization process along with minor amounts of crustal assimilation, en route to the upper crustal levels generating a wide variety of rock types ranging from diorite to granite in an extensional regime.     

冈底斯中段早侏罗世辉长岩-花岗岩杂岩体成因及其对新特提斯构造演化的启示:以日喀则东嘎岩体为例

以冈底斯中段日喀则东嘎出露的早侏罗世辉长岩-花岗岩杂岩体为对象,进行了锆石U-Pb年龄和Hf同位素,以及全岩元素地球化学组成的系统测定,据此探讨了岩石的成因及其对新特提斯构造演化的启示。该杂岩体中辉长岩主要由角闪石和钙质斜长石组成,缺乏辉石;花岗岩主要为英云闪长岩、花岗闪长岩等构成的TTG岩石组合;花岗岩中普遍发育呈塑变形态的镁铁质包体。锆石LA-ICP-MS U-Pb定年结果显示,英云闪长岩和镁铁质包体的成岩年龄十分接近,且与辉长岩的年龄基本一致,均为177~180Ma。化学组成上,辉长岩低硅、富铝、贫碱,富轻稀土和大离子亲石元素,贫高场强元素,相似于高铝玄武岩。英云闪长岩贫碱、准铝、富钠,属钙碱性I型花岗岩。镁铁质包体具有与寄主岩相似的矿物组成和微量元素分布模式,二者均具有显著亏损的锆石Hf同位素组成,εHf(t)值分别为+11.4~+15.0和+14.4~+18.6。综合分析表明,早侏罗世冈底斯南缘应处于新特提斯洋板片俯冲的构造背景,其中辉长质侵入体为遭受俯冲板片析出流体交代作用的亏损地幔部分熔融的产物,花岗质岩石起源于初生地壳的部分熔融,镁铁质包体为辉长质岩浆与花岗质岩浆二者经混合作用的产物。结合对区内其它辉长质侵入体及相关镁铁质包体资料的全面分析,表明在新特提斯洋板片的整个俯冲过程中(205~40Ma),冈底斯南缘应存在多次的基性岩浆底侵及其诱发的壳幔岩浆混合作用。     

利用ANSYS WORKBENCH模拟火山岩浆活动热扩散过程

火山喷发必然伴随着高温岩浆侵入体把热量从岩石圈深部携带到地壳浅层的过程,因而火山区往往也是地热资源富集区。火山岩浆侵入体热扩散过程的数值模拟不仅是火山区构造热演化研究的重要手段,而且也是火山区地热资源评估的重要方法。本文利用在工程热物理领域应用甚广、但在地热地球物理领域鲜有报道的有限元软件ANSYS WORKBENCH对火山活动岩浆冷却过程及其对围岩的热扰动过程进行了数值模拟。首先本文建立一系列简单的柱状模型,模拟了不同规模、不同顶板埋深的侵入体的热扩散过程,引入冷却指数α=(T_(侵入)-T)/(T_(侵入)-T_(稳态))×100%及干扰温差ΔT=T-T稳态分别来定量分析岩浆侵入体冷却过程及围岩受侵入体热扩散扰动程度。结果表明,半径为0.5km的柱状侵入体的冷却时间约为50ka左右,对围岩热扰动持续时间不到0.5Ma,最大横向热扰动范围约为3km。而半径1km的柱状侵入体的冷却时间约为200ka左右,对围岩温度场影响可持续1.4Ma,热扰动范围可至7km。顶板埋深越大,侵入体对围岩热扰动的持续时间越短。在上述模拟实验的基础上,本文结合最新的相关研究成果,模拟计算了上地壳岩浆房和上中地壳岩浆房两种情景下长白山天池火山千年大喷发对于温度场的可能影响。结果表明,无论其岩浆房位于上地壳或中地壳上部,千年大喷发对于围岩的热扰动目前还局限于500m左右的范围内,这可能是区内尚无大规模地热显示的原因。     

溧阳戴埠火山岩开放体系岩浆活动探讨

戴埠下火山岩系层序—岩相—成分演化之间关系研究表明，火山产物是从十个喷发中心经深部岩浆脉动式补充、快速分异、间歇式喷发所形成。第一和第二旋回之间具沉积间断，而且喷发中心迁移与新生岩浆补充相对应。在两个旋回内部，中性和酸性喷发产物都具宽的或较宽的成分范围和快速分异特点。中性溢流相之后，从中酸性火山屑碎流相至酸性溢流相或侵出相的喷发强度降低，是岩浆房萃取深度降低的结果。分离结晶和同化作用是岩浆演化的主要原因。