滇南新元古代的岩浆作用：来自瑶山群深变质岩SHRIMP锆石 U-Pb年代学证据

滇南瑶山—哀牢山地区出露一套呈NW—SE向狭长条带状展布的深变质岩系——下元古界瑶山群和哀牢山群,并认为存在前寒武纪的结晶基底。本文选取瑶山群眼球状花岗质糜棱岩和金平阿得博的片麻状花岗岩作为研究对象,进行SHRIMP锆石U-Pb定年。结合阴极发光图像,获得岩浆锆石的结晶年龄为828±6.2Ma(N=11,MSWD=1.8)和748～801Ma。同时,作者在墨江-元江剖面的哀牢山群黑云母花岗闪长质片麻岩中获得SHRIMP锆石核部U-Pb年龄为769～893Ma。研究揭示滇南的瑶山和哀牢山地区存在新元古代岩浆作用。瑶山群中古老残余锆石核部的984Ma年龄和哀牢山群中古老残余锆石核部年龄1104～1353Ma及2655Ma,表明该区存在中元古代或太古代的结晶基底,研究区很可能位于南华裂谷与康滇裂谷的交汇部位,新元古代的岩浆活动可能与Rodinia超大陆聚合——裂解过程有关。这为构筑Rodinia超大陆聚散过程和揭示华南大地构造演化史提供年代学方面证据。     

Mesozoic collision-related magmatism and crust–mantle interaction along the Anhui segment of the Yangtze River Valley,east-central China

The middle segment of the Yangtze River Deep Fault Belt, located in the foreland of the Dabie orogen, contains widely exposed volcanic–intrusive complexes that formed during two episodes of magmatism (post-collisional and post-orogenic), reflecting crust–mantle interactions during the Late Jurassic (J₃) to Early Cretaceous (K₁). This article summarizes research on the Mesozoic igneous suites and xenolith suites in the area along the Yangtze River. ‘Post-collisional magmatism’ occurred during lithospheric extension at ～145–130 Ma. Its beginning and end are marked by gabbroic xenoliths and pyroxene cumulates within intrusions at Tongling, and by alkali-rich magmatic rocks. The association includes peraluminous silicic rocks and metaluminous mafic–felsic igneous suites, ranging from medium-K to high-K calc-alkaline to shoshonitic compositions. Taking the Tongling region as an example, quartz monzodiorite yields a sensitive high resolution ion microprobe (SHRIMP) zircon U–Pb age of 139.5 ± 2.9 Ma, and granodiorite yields an age of 135.5 ± 4.4 Ma. These intrusive rocks contain 52.79–66.46 wt.% SiO₂, 13.12–17.73 wt.% Al₂O₃, 1.37–4.62 wt.% MgO, 3.86–6.84 wt.% FeO^T, and 4.71–7.87 wt.% total alkalis (Na₂O?+?K₂O). ACNK values range from 0.62 to 1.20, and ANK values from 1.45 to 3.48. ‘Post-orogenic magmatism’ occurred during lithospheric delamination at ～130–120 Ma. The start of magmatism was marked by the formation of gabbro containing spinel lherzolite xenoliths in the Nanjing–Wuhu Basin (NWB), and its end was marked by the generation of feldspathoid phenocryst-bearing phonolite in the NWB and the Lujiang–Zongyang Basin (LZB), respectively. The association that formed during this episode ranges from alkaline to peralkaline. Taking the Niangniangshan Formation in the NWB as an example, the Nosite phonolite yields a whole-rock monomineral Rb–Sr isochron age of 120 ± 9 Ma, and contains 49.92–60.09 wt.% SiO₂, 17.67–20.65 wt.% Al₂O₃, 0.08–2.45 wt.% MgO, 1.32–6.62 wt.% FeO^T, and 9.24–13.92 wt.% total alkalis (Na₂O?+?K₂O). ACNK values range from 0.72 to 1.24, and ANK values from 1.03 to 1.35.

The two magmatisms correspond to two episodes of crust–mantle interaction. The first involved intensive interaction between middle–lower crust and underplated basaltic magma derived from the upper mantle lithosphere, whereas the second involved minor interaction between the middle–lower crust and basaltic magma derived from the lower lithospheric mantle.     

Geochronological evidence and tectonic significance of Carboniferous magmatism in the southwest Trabzon area,eastern Pontides,Turkey

The northern and southern zones of the eastern Pontides (northeast Turkey) contain numerous plutons of varying ages and compositions. Geochemical and isotopic results on two Hercynian granitoid bodies located in the northern zone of the eastern Pontides allow a proper reconstruction of their origin for the first time. The intrusive rocks comprise four distinct bodies, two of which we investigated in detail. Based on LA–ICP–MS U–Pb zircon dating, the Derinoba and Kayadibi granites have similar ²⁰⁶Pb/²³⁸U versus ²⁰⁷Pb/²³⁵U Concordia ages of 311.1 ± 2.0 and 317.2 ± 3.5 million years for the former and 303.8 ± 1.5 million years for the latter. Aluminium saturation index values of both granites are between 0.95 and 1.35, indicating dominant peraluminous melt compositions. Both intrusions have high SiO₂ (74–77 wt.%) contents and show high-K calc-alkaline and I- to S-type characteristics. Primitive mantle-normalized element diagrams display enrichment in K, Rb, Th, and U, and depletion in Ba, Nb, Ta, Sr, P, and Ti. Chondrite-normalized rare earth element patterns are characterized by concave-upward shapes and pronounced negative Eu anomalies with La_cn/Yb_cn?=?4.6–9.7 and Eu_cn/Eu*?=?0.11–0.59 (Derinoba), and La_cn/Yb_cn?=?2.7–5.5 and Eu_cn/Eu*?=?0.31–0.37 (Kayadibi). These features imply crystal-melt fractionation of plagioclase and K-feldspar without significant involvement of garnet. The Derinoba samples have initial ?Nd values between –6.1 and –7.1 with Nd model ages and T _DM between 1.56 and 2.15 thousand million years. The Kayadibi samples show higher initial ?Nd_(I) values, –4.5 to –6.2, with Nd model ages between 1.50 and 1.72 thousand million years. This study demonstrates that the Sr isotope ratios generally display negative correlation with Nd isotopes; Sr isotope ratios were lowered in some samples by hydrothermal interaction or alteration. Isotopic and petrological data suggest that both granites were produced by the partial melting of early Palaeozoic lower crustal rocks, with minor contribution from the mantle. Collectively, these rocks represent a late stage of Hercynian magmatism in the eastern Pontides.     

Eocene mafic volcanism in northern Anatolia: its causes and mantle sources in the absence of active subduction

Eocene mafic volcanic rocks occurring in an E–W-trending, curvilinear belt along and north of the Izmir–Ankara–Erzincan suture zone (IAESZ) in northern Anatolia, Turkey, represent a discrete episode of magmatism following a series of early Cenozoic collisions between Eurasia and the Gondwana-derived microcontinents. Based on our new geochronological, geochemical, and isotope data from the Kartepe volcanic units in northwest Anatolia and the extant data in the literature, we evaluate the petrogenetic evolution, mantle melt sources, and possible causes of this Eocene volcanism. The Kartepe volcanic rocks and spatially associated dikes range from basalt and basaltic andesite to trachybasalt and basaltic trachyandesite in composition, and display calc-alkaline and transitional calc-alkaline to tholeiitic geochemical affinities. They are slightly to moderately enriched in large ion lithophile (LILE) and light rare earth elements (LREE) with respect to high-field strength elements (HFSE) and show negative Nb, Ta, and Ti anomalies reminiscent of subduction-influenced magmatic rocks. The analysed rocks have ⁸⁷Sr/⁸⁶Sr_(i) values between 0.70570 and 0.70399, positive ?_Nd values between 2.7 and 6.6, and Pb isotope ratios of ²⁰⁶Pb/²⁰⁴Pb_(i) = 18.6–18.7, ²⁰⁷Pb/²⁰⁴Pb_(i) = 15.6–15.7, and ²⁰⁸Pb/²⁰⁴Pb_(i) = 38.7–39.1. The ⁴⁰Ar/³⁹Ar cooling ages of 52.7 ± 0.5 and 41.7 ± 0.3 Ma obtained from basaltic andesite and basalt samples indicate middle to late Eocene timing of this volcanic episode in northwest Anatolia. Calculated two-stage Nd depleted mantle model (T_DM) ages of the Eocene mafic lavas range from 0.6 to 0.3 Ga, falling between the T_DM ages of the K-enriched subcontinental lithospheric mantle of the Sakarya Continent (1.0–0.9 Ga) to the north, and the young depleted mantle beneath central Western Anatolia (0.4–0.25 Ga) to the south. These geochemical and isotopic features collectively point to the interaction of melts derived from a sublithospheric, MORB-like mantle and a subduction-metasomatized, subcontinental lithospheric mantle during the evolution of the Eocene mafic volcanism. We infer triggering of partial melting by asthenospheric upwelling beneath the suture zone in the absence of active subduction in the Northern Neotethys. The geochemical signature of the volcanic rocks changed from subduction- and collision-related to intra-plate affinities through time, indicating an increased asthenospheric melt input in the later stages of Eocene volcanism, accompanied by extensional deformation and rifting.     

Petrology of two contrasting Mexican volcanoes,the Chiapanecan (El Chichón) and Central American (Tacaná) volcanic belts: the result of rift- versus subduction-related volcanism

The alkaline El Chichón and calc-alkaline Tacaná volcanoes, located in southern Mexico, form parts of the Chiapanecan Volcanic Belt and Central American Volcanic Arc, respectively. El Chichón has emitted potassium-, sulphur-, and phosphorus-rich trachyandesites and trachybasalts (as mafic enclaves), whereas Tacaná has erupted basalts to dacites with moderate potassium contents, and minor high-Ti magmas (1.5–1.8 wt.% TiO₂). The magmatic evolution in the two volcanoes has involved similar fractionating assemblages: Fe-Ti oxides, olivine, plagioclase, pyroxenes, amphibole, and apatite. K₂O/P₂O₅ ratios and isotopic signatures indicate that magmas from both El Chichón and Tacaná have undergone significant crustal contamination. The volcanism at both Tacaná and El Chichón was previously related to northeastward subduction of the Cocos Plate, representing the main arc and the backarc, respectively. Although such an origin is in accord with Tacaná occurring 100 km above the Cocos Benioff Zone, it is inconsistent with: (a) the absence of a calc-alkaline belt between El Chichón and the Middle America Trench; and (b) truncation of the subducted Cocos Plate by the southwesterly dipping Yucatan slab near the Middle America Trench (i.e. the Cocos Plate does not presently underlie El Chichón). On the other hand, El Chichón and the Chiapanecan Volcanic Belt are located on the sinistral Veracruz fault zone that forms the northern boundary of the Southern Mexico block, which has been migrating relatively to the east since ca. 5 Ma. In this context, the anomalous high potassium, sulphur, and phosphorus levels in the El Chichón magmas are explicable in terms of rifting in a pull-apart system with the weak subduction fingerprint inherited from the Yucatan slab.     

Arc magmatism in eastern Kumaun Himalaya,India: A study based on geochemistry of granitoid rocks

Petrochemical studies of granitoid rocks from the eastern part of Kumaun region suggest that the leading edge of India represents an active arc during Late Paleoproterozoic times. It has been observed that melt generation for granodiorite rocks from the eastern Almora Nappe and Chhiplakot klippe along with the Askot klippe was caused through a subduction‐related process involving hydrous partial melting of a Paleoproterozoic amphibole‐ and/or garnet‐bearing mafic source with the involvement of sediments from the subduction zone. The medium‐ to high‐K basic rocks, common in subduction‐related magmatic arcs, can also explain the generation of the high‐K granodiorites of the Chhiplakot klippe. The augen gneisses from the eastern Almora nappe and Chhiplakot klippe along with the Askot klippe further show geochemical similarity with the associated granodiorites, suggesting there is a genetic linkage with one another.     

Geological, geochemical characteristics and isotope systematics of the Longqiao iron deposit in the Lu-Zong volcano-sedimentary basin, Middle-Lower Yangtze (Changjiang) River Valley, Eastern China

The Middle-Lower Yangtze (Changjiang) River Valley metallogenic belt is located on the northern margin of the Yangtze Craton of eastern China. Most polymetallic deposits in the Changjiang metallogenic belt are clustered in seven districts where magmatism of Mesozoic age (Yanshanian tectono-thermal event) is particularly extensive. From west to east these districts are: E-dong, Jiu-Rui, Anqing-Guichi, Lu-Zong, Tong-Ling, Ning-Wu and Ning-Zhen. World-class iron ore deposits occur in the Lu-Zong and Ning-Wu ore clusters, which are mainly located in continental fault-bound volcanic-sedimentary basins. One of these deposits is the Longqiao iron deposit, discovered in the northern part of the Lu-Zong Basin in 1985. This deposit consists of a single stratabound and stratiform orebody, hosted in sedimentary carbonate rocks of the Triassic Dongma'anshan Formation. A syenite pluton (Longqiao intrusion) is situated below the deposit. The iron ore is massive and disseminated and the ore minerals are mainly magnetite and minor pyrite. Wall rock alteration mostly consists of skarn minerals, such as diopside, garnet, potassic feldspar, quartz, chlorite, phlogopite and anhydrite. Thin sedimentary siderite beds of Triassic age occur as relict laminated ore at the top and the margin of the magnetite orebody. These sideritic laminae are part of Triassic evaporite-bearing carbonate deposits (Dongma'anshan Formation).Sulfur isotopic compositions show that the sulfur in the deposit was derived from a mixture of magmatic hydrothermal fluids and carbonate–evaporite host rocks. Similarly, the C and O isotopic compositions of limestones from the Dongma'anshan Formation indicate that these rocks interacted with magmatic hydrothermal fluids. The O isotopic compositions of the syenitic rocks and minerals from the deposit show that the hydrothermal magnetite and skarn minerals were formed from magmatic fluids. The Pb isotopic compositions of sulfides are similar to those of the Longqiao syenite. Phlogopite coexisting with magnetite in the magnetite ores yielded a plateau age of 130.5 ± 1.1 Ma (2σ), whereas the LA-ICP MS age of the syenite intrusion is 131.1 ± 1.5 Ma, which is slightly older than the age of phlogopite.The Longqiao syenite intrusion may have crystallized from a parental alkaline magma, generated by partial melting of lithospheric mantle, during extensional tectonics. The ore fluids were probably first derived from magma at depth, later emplaced in the sedimentary rocks of the Dongma'anshan Formation, where it interacted with siderite and evaporite-bearing carbonate strata, resulting in the formation of magnetite and skarn minerals. The Longqiao iron deposit is a skarn-type stratabound and stratiform mineral system, genetically and temporally related to the Longqiao syenite intrusion. The Longqiao syenite is part of the widespread Mesozoic intracontinental magmatism (Yanshanian event) in eastern China, which has been linked to lithospheric delamination and asthenospheric upwelling.     

Permian Tectonic Evolution in Southwestern Khanka Massif: Evidence from Zircon U‐Pb Chronology,Hf isotope and Geochemistry of Gabbro and Diorite

Laser ablation-inductively coupled plasma mass spectrometry (LA-ICP-MS) zircon U-Pb dating and geochemical data for the Permian gabbros and diorites in the Hunchun area are presented to constrain the regional tectonic evolution in the study area. Zircons from gabbro and diorite are euhedral-subhedral in shape and display fine-scale oscillatory zoning as well as high Th/U ratios (0.26–1.22), implying their magmatic origin. The dating results indicate that the gabbro and diorite formed in the Early Permian (282±2 Ma) and in the Late Permian (255±3 Ma), respectively. In addition, the captured zircons with the weighted mean age of 279±4 Ma are also found in the diorite, consistent with the formation age of the gabbro within uncertainty. The gabbros belong chemically to low-K tholeiitic series, and are characterized by low rare earth element (REE) abundances, flat REE pattern, weak positive Eu anomalies (δEu), and depletion in high field strength elements (HFSEs, Nb, Ta, and Ti), similar to the high-aluminum basalts from island arc setting. Initial Hf isotopic ratios of zircons from the gabbro range from +7.63 to +14.6, suggesting that its primary magma could be mainly derived from partial melting of a depleted lithospheric mantle. The diorites belong to middle K calc-alkaline series. Compared with the gabbros, the diorites have higher REE abundance, weak negative Eu anomalies, and more depletion in HFSEs (Nb, Ta, and Ti), similar chemically to the volcanic rocks from an active continental margin setting. Initial Hf isotopic ratios and Hf two-stage model ages of zircons from the diorite range from +11.22 to +14.17 and from 424 to 692 Ma, respectively, suggesting that its primary magma could be mainly derived from partial melting of the Early Paleozoic and/or Neoproterozoic accretted lower crust. Taken together, it is suggested that geochemical variations from the Early Permian gabbros to the Late Permian diorites reveal that the subduction of the Paleo-Asian oceanic plate beneath the Khanka Massif and collision between the arc and continent (Khanka Massif) happened in the late stage of the Late Paleozoic.     

大别山鲁家寨花岗岩地球化学、锆石年代学和Hf同位素特征:扬子克拉通北东缘新元古代岩浆活动证据

对大别山造山带的鲁家寨花岗岩进行了锆石U-Pb年代学、锆石Hf同位素和岩石地球化学研究.锆石LA-ICP-MS U-Pb定年结果表明鲁家寨花岗岩形成于新元古代((816±17)Ma).鲁家寨花岗岩总体具有高硅(SiO2 69.13%～75.47%)、准铝-弱过铝(A/CNK=0.98～1.01)的化学组成特征.稀土元素...     

我国火山地热流体地球化学研究新进展

本文综述了最近几年来中国研究者在地热流体地球化学研究领域取得的主要进展。在国际上关于地球内部流体及其作用研究取得重要进展的大背景下,我国学者在地热流体地球化学研究上也取得了一些重要成果,主要表现在火山地热区和非火山地热区两大方面,在火山学、地热学、环境学、大地构造学、地震学等五个学科领域都取得了一些重要进展。