Characterization of the subsurface architecture and identification of potential groundwater paths in a clay-rich floodplain using multi-electrode resistivity imaging

The interaction between surface water and groundwater in clay-rich fluvial environments can be complex and is generally poorly understood. Airborne electromagnetic surveys are often used for characterizing regional groundwater systems, but they are constrained by the resolution of the method. A resistivity imaging survey has been carried out in the Macquarie Marshes (New South Wales, Australia) in combination with water chemical sampling. The results have enabled the identification of buried palaeochannels and the location of potential recharge points. The data have been compared with previously published airborne electromagnetic data in the same area. Deeper less conductive features suggest that there is a potential connection between the Great Artesian Basin and groundwater contained within the shallow sand aquifer. Even though the chemistry of the groundwater samples does not indicate interaction with the Great Artesian Basin, the observed discontinuity in the saprolite implies potential for this to happen in other locations.     

山东黄县弧形断裂带断层泥铁元素化学种分布特征及其地震地质意义

本文利用德国Wissel公司生产的新型穆斯堡尔谱仪(Bench-MB500)对山东龙口常庄子村北黄县弧形断裂断层剖面上的多种断层泥样品进行了穆斯堡尔谱测试分析,讨论了该断层剖面上铁元素地球化学分布特征及其地震地质意义。结果显示,该断裂中央部分比较年轻的断层泥相对富集para-Fe~(2+),而两侧较老的断层泥基本由para-Fe~(3+)组成;剖面断层泥样品中铁元素的地球化学特征与断层的活动演化历史密切相关,显示了断裂带内存在复杂的水岩相互作用。     

Indosinian Tectonic Setting of the Southern Yidun Arc： Constraints from SHRIMP Zircon Chronology and Geochemistry of Dioritic Porphyries and Granites

A mass of granitoid and dioritic intrusions are distributed in the southern Yidun Arc, among which the representative Indosinian intrusions include the Dongco and Maxionggou granitoid intrusions in Daocheng County and hypabyssal intrusions intruding into arc volcanic rocks near the Xiangcheng town. The Dongco and Maxionggou granitoid intrusions consist mainly of porphyraceous monzogranites, megacryst monzogranites and aplite granites. The Xiangcheng hypabyssal intrusions are composed dominantly of dioritic porphyries. SHRIMP zircon ages of 224±3 Ma and 222±3 Ma have been obtained for the Dongco granitoid intrusion and the Xiangcheng dioritic porphyries, respectively. The Xiongcheng dioritic porphyries show a cak-alkaline geochemical feature, and are characterized by higher Sr/Y ratios, depletive Nb, Ta, P and Ti, enriched LILEs, and lower εNd (t) (= -3.27), suggesting that they might be derived from mantle source magmas that were obviously contaminated by continent crustal materials. However, the Dongco and Maxionggou granitoids belong to high-potassium calc alkaline series with a per-metaluminous feature, and are characterized by higher CaO/(∑FeO+MgO) and Al2O3/(∑FeO+ MgO) ratios, lower (La/Yb)n and Sr/Y ratios, depletive Nb, Ta, Sr, P and Ti, enriched LILEs, and very low εNd (t) (= -8.10), indicating that the granitoids might be derived from partial melting of continental crust materials mainly of graywacke. Petrogenesis of Dongco and Maxionggou granitoids implies that there was an oceanic crust between the Zongza continental block (ZCB) and western margin of the Yangtze Craton (WMYZC). And the oceanic crust slab subducted westward during the Indosinian Epoch, producing an Andes-type continent marginal arc and a back arc basin at the WMSCC. Then the oceanic basin closed and a sinistrally lateral collision occurred at ca. 224 Ma-222 Ma between the ZCB and the WMYZC, causing partial melting of sediments in the back-arc basin to generate granitoid magmas of the Dongco and Maxionggou intrusions.     

Constructing the latest Neoproterozoic to Early Paleozoic multiple crust-mantle interactions in western Bainaimiao arc terrane,southeastern Central Asian Orogenic Belt

Identifying the crust-mantle interactions in association with the evolution of the Precambrian microcontinents provides critical constraints on the accretionary evolution in the Central Asian Orogenic Belt(CAOB).The Bainaimiao arc terrane(BAT) is one of the most important Precambrian microcontinents in southeastern CAOB,however,few studies have paid attention to the types and the evolving processes of the crust-mantle interactions that occurred before its final accretion onto the northern North China Craton.This study presents an integrated study of geochronology,zircon Hf isotope and whole-rock geochemistry on the latest Neoproterozoic diabases and the Early Paleozoic arc intrusions in the western BAT.The latest Neoproterozoic(ca.546 Ma) diabases display low SiO_2(46.52-49.24 wt.%) with high MgO(8.23-14.41 wt.%),Cr(66-542 ppm) and Ni(50-129 ppm),consisting with mantle origin.Their highly negative zircon ε_(Hf)(t)(-12.0 to-24.7) and high Fe/Mn ratios(62.1-81.7)further indicate a significantly enriched mantle source.Considering that the BAT maybe initially separated from the Tarim Craton with a thickened crustal root,we propose that these diabases were generated through partial melting of an enriched lithospheric mantle source that had been hybridized by lower-crustal eclogites during foundering of the BAT lower crust.The Early Paleozoic(ca.475-417 Ma) arc intrusions in western BAT can be divided into Periods Ⅰ and Ⅱ at approximately 450 Ma.The Period Ⅰ(450 Ma) intrusions contain abundant mafic minerals like hornblende and pyroxene,and show positive zircon ε_(Hf)(t)(+1.5 to+10.9).They are predominantly medium-K calc-alkaline with broad correlations of SiO2 versus various major and trace elements,which correlate well with the experimental melts produced by the fractional crystallization of primitive hydrous arc magmas at 7 kbar.We assume they were formed through mid-crustal differentiation of the mantle wedge-derived hydrous basaltic melts.By contrast,the Period Ⅱ(≤450 Ma) intrusions are characterized by variable zircon e_(Hf)(t)(-15.0 to+11.5) with irregular variations in most major and trace elements,which are more akin to the arc magmas generated in an open system.The general occurrence of elder inherited zircons,along with the relatively high Mg#(45) of some samples,call upon a derivation from the reworking of the previously subduction-modified BAT lower crust with the input of mantle-derived mafic components.In combination with the Early Paleozoic tectonic melanges flanking western BAT,we infer that the compositional transition from Period Ⅰ to Ⅱ can be attributed to the tectonic transition from south-dipping subduction of Solonker ocean to north-dipping subduction of South Bainaimiao ocean in southeastern CAOB.The above results shed light not only on the latest Neoproterozoic to Early Paleozoic multiple crust-mantle interactions in western BAT,but also on the associated crustal construction processes before the final arc-continent accretion.     

Early to mid-Paleozoic magmatic and sedimentary records in the Bainaimiao Arc: An advancing subduction-induced terrane accretion along the northern margin of the North China Craton

The early to mid-Paleozoic subduction-induced terrane accretion along the northern margin of the North China Craton is not well understood. To address this issue, we investigate the magmatic and sedimentary records, including both new and previously published geochemical, Sr–Nd isotopic, and zircon U–Pb–Hf isotopic data from the Bainaimiao Arc. The collected gabbro–diorites and granitoids have been dated to 431–453 Ma. The gabbro–diorites have high Mg/(Mg + Fe) molar ratios (44.41–73.39); depleted Nb, Ta and Ti; and negative ε_Nd(t) values (-9.43–-6.80). They were derived from a mantle wedge metasomatized by subduction-derived fluids with crustal contamination. The granitoids are characterized by high silica, low to high K, low Fe and Mg contents, strong fractionation of rare earth elements, and positive ε_Hf(t) values (+1.42–+8.19). They were derived from crustal melts with juvenile additions. The clastic rocks from the Baoerhantu Group and Xibiehe Formation are dominated by early Paleozoic zircons, whereas those from the Bainaimiao Group are dominated by early Paleozoic and Precambrian zircons. Detrital zircon geochronology and field geology confirm their deposition in early to mid-Paleozoic. The U–Pb ages and petrographic and geochemical analyses indicate that the clastic rocks were deposited in arc-related basins with felsic sources from the Bainaimiao Arc. The xenocrystic and detrital zircons in the magmatic and clastic rocks, respectively, imply a Precambrian basement for the Bainaimiao Arc. The early Paleozoic magmatic rocks of the Bainaimiao Arc show secular changes with decreasing age: increasing K₂O contents and Sr/Y ratios and decreasing Fe₂O₃^T + MgO contents and ε_Hf(t) and ε_Nd(t) values. This is likely in response to advancing subduction and related crustal thickening. Accordingly, the following tectono-paleogeographic model was proposed for the Bainaimiao Arc: (a) ∼500–455 Ma initial subduction and juvenile arc development, (b) ∼455–415 Ma continuous subduction with mature arc development, and (c) ∼415–400 Ma accretion to the North China Craton.     

Strike-slip systems as the main tectonic features in the Plio-Quaternary kinematics of the Calabrian Arc

The oblique and diachronous collision of the Apennine-Maghrebian Chain with the Apulian (in the north-east) and Pelagian (in the south) continental forelands, has determined the characteristic arcuate structure of this orogen. The effects of Plio-Pleistocene deformation of the Calabrian Arc have been analysed on the basis of available reflection seismic profiles and using local time-structural maps reconstructed along the main structures. During this period, internal sectors of the Tertiary chain migrated forward on the oceanic Ionian foreland, and were cut by important strike-slip systems. These last have an orientation approximately coincident with that of the migration of the front, allowing differential movement of the different sectors of the arc, towards the weakly buoyant Ionian oceanic domain. The dataset suggests a clear connection between the development of the strike-slip systems cutting the chain and the direction of tectonic transport, towards the East during Late Messinian/Early Pliocene time, to the ESE during Late Pliocene/Early Pleistocene time, finally to the SSE during the Middle/Late Pleistocene to Present, showing a clockwise rotation in well defined stages during the kinematic evolution of the chain. The origin of the Strait of Messina during the different phases is also interpreted in the context of the analysed regional tectonic setting.     

Origin of high field strength element enrichment in volcanic arcs: Geochemical evidence from the Sulu Arc, southern Philippines

Lavas from the Sulu Arc, southern Philippines, exhibit an enrichment in high field strength elements (HFSE) that represents a departure from the typical volcanic arc geochemical signature. It has been postulated that this relative enrichment arises from metasomatism of mantle wedge peridotites by melts derived from the subducting oceanic lithosphere, through formation of amphibole which subsequently breaks down and enriches the mantle source of parental arc magmas in HFSE. Divergent chemical and isotopic characteristics between Sulu Arc HFSE-enriched lavas and the Sulu Sea crust being subducted—the presumed source of slab-derived melts—render it unlikely, however, that HFSE enrichment arises from the influence of such melts. New geochemical data suggest that the varying degrees of HFSE enrichment in Sulu Arc lavas are instead the result of variable amounts of mixing between enriched and depleted mantle end-components—the sources of South China Sea intraplate lavas and Sulu seafloor basalts, respectively—within a compositionally heterogeneous mantle wedge.     

A rapid method to map the crustal and lithospheric thickness using elevation, geoid anomaly and thermal analysis. Application to the Gibraltar Arc System, Atlas Mountains and adjacent zones

We present a method based on the combination of elevation and geoid anomaly data together with thermal field to map crustal and lithospheric thickness. The main assumptions are local isostasy and a four-layered model composed of crust, lithospheric mantle, sea water and the asthenosphere. We consider a linear density gradient for the crust and a temperature dependent density for the lithospheric mantle. We perform sensitivity tests to evaluate the effect of the variation of the model parameters and the influence of RMS error of elevation and geoid anomaly databases. The application of this method to the Gibraltar Arc System, Atlas Mountains and adjacent zones reveals the presence of a lithospheric thinning zone, SW–NE oriented. This zone affects the High and Middle Atlas and extends from the Canary Islands to the eastern Alboran Basin and is probably linked with a similarly trending zone of thick lithosphere constituting the western Betics, eastern Rif, Rharb Basin, and Gulf of Cadiz. A number of different, even mutually opposite, geodynamic models have been proposed to explain the origin and evolution of the study area. Our results suggest that a plausible slab-retreating model should incorporate tear and asymmetric roll-back of the subducting slab to fit the present-day observed lithosphere geometry. In this context, the lithospheric thinning would be caused by lateral asthenospheric flow. An alternative mechanism responsible for lithospheric thinning is the presence of a hot magmatic reservoir derived from a deep ancient plume centred in the Canary Island, and extending as far as Central Europe.     

Volatile (S,Cl and F) and fluid mobile trace element compositions in melt inclusions: implications for variable fluid sources across the Kamchatka arc

Volatile element, major and trace element compositions were measured in glass inclusions in olivine from samples across the Kamchatka arc. Glasses were analyzed in reheated melt inclusions by electron microprobe for major elements, S and Cl, trace elements and F were determined by SIMS. Volatile element–trace element ratios correlated with fluid-mobile elements (B, Li) suggesting successive changes and three distinct fluid compositions with increasing slab depth. The Eastern Volcanic arc Front (EVF) was dominated by fluid highly enriched in B, Cl and chalcophile elements and also LILE (U, Th, Ba, Pb), F, S and LREE (La, Ce). This arc-front fluid contributed less to magmas from the central volcanic zone and was not involved in back arc magmatism. The Central Kamchatka Depression (CKD) was dominated by a second fluid enriched in S and U, showing the highest S/K₂O and U/Th ratios. Additionally this fluid was unusually enriched in ⁸⁷Sr and ¹⁸O. In the back arc Sredinny Ridge (SR) a third fluid was observed, highly enriched in F, Li, and Be as well as LILE and LREE. We argue from the decoupling of B and Li that dehydration of different water-rich minerals at different depths explains the presence of different fluids across the Kamchatka arc. In the arc front, fluids were derived from amphibole and serpentine dehydration and probably were water-rich, low in silica and high in B, LILE, sulfur and chlorine. Large amounts of water produced high degrees of melting below the EVF and CKD. Fluids below the CKD were released at a depth between 100 and 200 km due to dehydration of lawsonite and phengite and probably were poorer in water and richer in silica. Fluids released at high pressure conditions below the back arc (SR) probably were much denser and dissolved significant amounts of silicate minerals, and potentially carried high amounts of LILE and HFSE. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

云南中甸地区两个斑岩铜矿容矿斑岩的地球化学特征——以雪鸡坪和普朗斑岩铜矿床为例

位于义敦岛弧南端的中甸岛弧已成为我国又一重要的斑岩铜矿产地,其中雪鸡坪中型斑岩铜矿床产于西斑岩带,普朗超大型斑岩铜矿床产于东斑岩带。详细对比研究了这两个斑岩铜矿床矿床地质,含矿斑岩的岩石化学、地球化学以及年代学等特征,认为:①两者的元素组成非常相似,如稀土配分形式均为轻稀土元素富集型,亏损重稀土元素和Y,富集Sr、K、Rb、Ba、Th等大离子亲石元素,亏损Nb、Ta、Zr、Hf、Ti等高场强元素,显示了埃达克岩的地球化学特征,表明它们可能是俯冲的甘孜—理塘洋壳部分熔融的产物,并受到地壳物质的混染;②中甸岛弧的结构及时空演化保持了义敦岛弧的共性,发育完整的沟-弧-盆体系,其中东斑岩带属于外弧,而西斑岩带属于内弧,中斑岩带及零星分布的属都蛇绿混杂岩产于弧间盆地。