Geochemistry and zircon U-Pb geochronology of Aligoodarz granitoid complex, Sanandaj-Sirjan Zone, Iran

The Aligoodarz granitoid complex (AGC) is located in the Sanandaj-Sirjan Zone (SSZ), western Iran and consists of quartz-diorites, granodiorites and subordinate granites. Whole rock major and trace element data mostly define linear trends on Harker diagrams suggesting a cogenetic origin of the different rock types. (⁸⁷Sr/⁸⁶Sr)_i and εNd_t ratios are in the ranges 0.7074-0.7110 and −3.56 to −5.50, respectively. The trace elements and Sr-Nd isotopic composition suggest that the granitoids from the AGC are similar to crustal derived I-type granitoids of continental arcs. The whole rock suite was produced by assimilation and fractional crystallization starting from a melt with intermediate composition likely possessing a mantle component. In situ zircon U-Pb data on the granites with LA-ICP-MS yield a crystallization age of ∼165 Ma. Inherited grains spanning in age from ∼180 Ma up to 2027 Ma were also found and confirm that assimilation of country rock has occurred.Chemical and chronological data on the AGC were compared with those available for other granitoid complexes of the central SSZ (e.g., Dehno, Boroujerd and Alvand). The comparison reveals that in spite of the different origins that have been proposed, all these granitoid complexes are likely genetically related. They share many chemical features and are derived from crustal melts with minor differences. Alvand granites have the most peculiar compositions most likely related to the presence of abundant pelitic component. All these intrusions are coeval and reveal the presence of an extensive magmatic activity in the central sector of the SSZ during middle Jurassic.     

氟化物固体缓冲剂-交流电弧直读发射光谱法测定化探样品中易挥发与难挥发微量元素

应用电弧直读发射光谱法测定化探样品,样品无需消解,采用固体进样的方式可以同时测定多个元素。但目前化探分析中常采用的固体缓冲剂(如焦硫酸钾、氟化钠)的电弧温度较低,只能分析银、硼、锡、铅、钼、铜等易挥发元素,而不能分析铬、锰、钛等沸点较高的难挥发性元素。本文通过碱金属控制较低的电弧温度,并利用难挥发元素能在高温条件下与氟离子发生化学反应降低其激发温度,配制了一种以氟化铝、聚三氟氯乙烯等氟化效率较高的化合物为主要成分的固体缓冲剂,通过优化分析线对的选择、曝光时间、电极形状等分析条件,实现了一次制样可同时分析地球化学样品中14种易挥发和难挥发元素。方法检出限为0.016~46.93μg/g,相对标准偏差为4.1%~12.3%,通过国家标准物质验证了准确度,测定值与标准值相符,各项参数都能满足地球化学普查规范要求。本方法分析效率高,在化探分析中具有一定的实用性。     

Formation of arcs and backarc basins inferred from the tectonic evolution of Southeast Asia since the Late Cretaceous

Results of the geological and geophysical surveys in the Daito ridges and basin in the northern West Philippine Basin suggest that the Daito Ridge was an arc facing toward the south from the Late Cretaceous to the Early Tertiary. The Late Cretaceous and Tertiary history of Southeast Asia is evaluated based on these data in the Daito ridges and basins and reconstructed based on overall plate kinematics that have operated in this area. During the Late Cretaceous, the Daito Ridge and the East Philippine Islands were positioned along the boundary between the Indian and Pacific Plates. The western half of the Philippines setting on the Indian Plate approached from the south and collided with the East Philippine–Daito Arc either during the latest Paleocene or the earliest Eocene. It is inferred that the bulk of the Philippine archipelago rotated clockwise and Borneo spun counterclockwise during the Tertiary.From the reconstruction, the formation of backarc basins and their spreading direction are assessed. As a result, some primary causes and significant characteristics are suggested for the opening of backarc basins in Southeast Asia. First, opening of some backarc basins commenced with or was triggered by collisions. Second, backarc basins opened approximately parallel to oceanic plate motion. Third, the formation of some backarc basins was triggered by the approach of a hot spreading center. Fourth, the spreading mode or direction of backarc basins was greatly affected by the configuration of the surrounding continent and was also rearranged to spread approximately parallel to oceanic plate motion.The formation of backarc basins and their spreading direction can be reasonably explained by plate kinematics. However, the generative force responsible for their formation is possibly within the subduction system, particularly to form horizontal tensional force in backarc side.     

俯冲带硫的地球化学行为及硫循环SCIEI北大核心CSCD

俯冲带是全球最大的物质循环系统,控制着硫(S)在地球内部圈层及表层的循环,影响着大气圈、水圈、生物圈、岩石圈的稳定性以及地球的宜居性。厘清S在俯冲带中的地球化学行为和循环特征对理解地球各储库的氧化还原状态、岩浆作用与演化、成矿物质聚集、以及地球大气成分等具有重要意义。本文首先总结了进入俯冲带之前的大洋岩石圈的S结构模型,对S在大洋板片中的分布状态和地球化学特征进行了系统归纳。随后,系统阐述了俯冲带高压-超高压变质岩记录的板片变质及脱水过程中硫的地球化学行为。岩石学研究表明俯冲板片中的S多以硫化物相存在,硫酸盐矿物在弧前深度就已被释放或分解。相较于熔体,俯冲带流体中S的溶解度更高,是运移硫的更有效方式。DEW模型计算结果显示,流体中S含量总体较低,但在俯冲板片~90km处其含量有一个峰值(浓度0.5%~1.0%)。岩相学证据、地球化学测试结果、磷灰石S近边吸收结构(S-XANES)特征以及模拟结果都显示俯冲深部流体中S多以HS^(-)及H_(2)S形式存在,不含大量的SO_(4)^(2-)及硫酸盐;中f_(S_(2))流体有利于S迁移出俯冲板片,从而促进俯冲带大规模S循环,而高f_(S_(2))流体在流-岩交换过程沿流体通道发生S的锁固作用而不利于俯冲带S循环。质量平衡计算显示全球俯冲带S输入通量为4.65×10^(13)g/yr,弧下深度板片S输出通量为2.91×10^(12)g/yr,板片-岛弧S循环效率仅6.3%。俯冲板片在弧下深度可能存在一个短暂高效的S释放窗口,释放流体的δ^(34)S值为-2.1±3.0‰。基于高压-超高压变质岩中硫化物的研究,初步厘清了俯冲板片中S的地球化学行为,首次从板片角度全面、定量地限定了俯冲带的脱硫通量、效率、种型和同位素特征,提出俯冲带循环的S不是岛弧岩浆的氧化剂,与岛弧环境的正δ^(34)S值也无直接因果联系,对解析俯冲带S循环和理解地球长期的S循环具有重要意义。最后,本文还展望了俯冲带S循环的未来发展方向,应在俯冲带流体氧化还原性质(硫酸盐的命运)、俯冲沉积物对S循环的制约、俯冲带环境下多硫同位素的分馏效应、S循环与其它挥发分(如C等)循环之间的耦合关系、地球历史上深部S循环等方向做出探索,更深入地理解俯冲带及全球S循环过程。     

水平分辨率对DEM流域特征提取的影响

选取石质山地与黄土丘陵过渡区宛川河流域作为研究区,利用1∶5万、水平分辨率10~100 m栅格DEM提取流域特征参数进行分析。结果表明:DEM水平分辨率对数字河网的提取精度有影响,提取的流域面积差别很小,河流长度、河道总长、河道坡度以及河网密度有偏差,流域平均坡度变化明显,长度和坡度特征参数的变化导致流域汇流时间及滞时不一致。     

华北克拉通新太古代板块俯冲作用:来自山西云中山地区变质高镁火成岩组合的证据

在华北克拉通中部的山西云中山地区,新太古代花岗闪长质片麻岩中存在一些超镁铁质岩-镁铁质岩块及由斜长角闪岩、角闪变粒岩、石英岩和石榴夕线黑云片岩等岩石类型构成的变质表壳岩残片,其中的超镁铁质-镁铁质岩、斜长角闪岩和角闪变粒岩构成一套高镁火成岩组合。超镁铁质岩已变质为橄榄绿泥阳起片岩等岩石类型,呈变余斑状结构,橄榄石斑晶仍有保存;岩石SiO_2含量为39.22%～44.99%,Al_2O_3为8.82%～13.47%,Mg O为19.24%～22.13%,Na_2O+K_2O=0.71%～1.11%,CaO为5.75%～8.42%;Al_2O_3/TiO_2=14.8～17.4,CaO/Al_2O_3=0.60～0.84;化学成分上与科马提岩有一定的相似性。与之紧密伴生的斜长角闪岩也具有高镁特征,Mg O含量为11.28%～15.09%,铝、硅和碱质均偏低,具正铕异常,显示堆晶辉长岩的特征。非高镁斜长角闪岩有相对高的铝、硅和碱质,其原岩应为钙碱性玄武岩。角闪变粒岩样品的SiO_2含量为54.21%～55.71%,Al_2O_3为14.24%～15.49%,Mg O为6.26%～8.28%,Fe OT/Mg O=1.11～1.58,高钠低钾,Na_2O+K_2O=3.7%～4.78%,Na_2O/K_2O=5.15%～13.13,Mg#=53.0～61.5,属于高镁安山岩。由超镁铁质质岩-斜长角闪岩-角闪变粒岩构成的变质高镁火山岩组合具有钙碱性系列趋势。超镁铁质岩稀土元素含量总量较低,具有轻稀土富集和重稀土亏损的稀土型式;斜长角闪岩与超镁铁质岩比较,除富集大离子亲石元素和Cr、Ni明显较低外,具有相似的微量元素图谱形态。三种岩石类型在微量元素蛛网图上均显示出Ta、Nb、Ti负异常和Pb正异常。野外产状和岩石地球化学特征表明超镁铁质岩和高镁斜长角闪岩属于阿拉斯加型杂岩体,角闪变粒岩属于赞岐岩质高镁安山岩。在Zr/Nb-Nb/Th和Nb/Y-Zr/Y构造环境判别图解上显示出与俯冲相关的演化趋势,在Hf-Th-Ta、Nb/La-(La/Sm)N和Th/Yb-Nb/Yb图解上也落在岛弧钙碱性岩石区域。以上特征表明高镁火成岩组合形成于与板块俯冲相关的岛弧构造背景。野外地质关系和锆石U-Pb年龄限定高镁火成岩组合形成时代在～2.5Ga。云中山地区阿拉斯加型镁铁质-超镁铁质杂岩与赞岐岩质高镁安山岩共生,表明该地区存在新太古代的板块俯冲作用,为太古宙存在板块构造机制提供了新证据。     

安达曼弧与缅甸、云南强震相关性研究

研究区包括安达曼弧、缅甸平原和云南地区三个部分。对安达曼弧7级以上地震与缅甸、云南7级和6.8级地震的群体与个体的相关特征进行了研究,发现安达曼弧、缅甸平原M≥7.0地震与云南M≥6.8地震在群体上有一定相关性,但并非一一相关。云南有4个地震活跃期,但安达曼弧与缅甸平原却只有3个,缺失第3活跃期。研究区强震活动从板缘向板内逐渐减弱,三个地区最大震级分别为8.7级、7.8级和7.7级。安达曼弧与缅甸、云南7级地震的个体相关概率分别为33%和27%,平均30%左右,缅甸与云南的个体相关概率为43%。最后对云南的地震趋势进行了预测。     

Myojin Rift, Izu–Bonin Arc as the Modern Analog of Hokuroku Basin, Northeast Japan: Geotectonic Significance of the New Hydrothermal Deposit in the Back-Arc Rift

A huge hydrothermal field, named the "Hakurei Sulfide Deposit" (HSD) was discovered in the North Myojin Rift (NMR), Izu–Bonin Back-Arc Rift (BAR) during the 2003 survey cruise of R/V Hakurei-maru No.2 . This paper investigates the geotectonic features and the tectonic setting of ore deposits between the NMR and the Hokuroku Basin, which is representative of kuroko fields in Japan. The topographic features of the NMR and the Hokuroku Basin are similar. Both have a clear ring structure surrounded by faults and the east–west width is almost the same. Many kuroko deposits were formed on the extrusion centers of the five pre-mineral acidic volcanic complexes, located in a loop inside the Hokuroku Basin. In the case of the NMR, seven submarine volcanoes are also located in a loop, and the HSD formed inside the summit caldera of Bayonnaise Knoll, which is one of the seven volcanoes. These topographic similarities highlight that the NMR is a modern analog of the Hokuroku Basin. Identifying such similarities is extremely useful when prospecting kuroko deposits on land equivalents as well as on the other segments of the Izu–Bonin BAR. The probability of finding kuroko deposits on land is expected to increase when the following are identified: (i) location of back-arc rift and the volcanic front; (ii) direction of the arc–trench system and intra-rift faults (and/or fracture zone); (iii) position of submarine volcanoes surrounding a back-arc rift; and (iv) intersections of a caldera fault and intra-rift fault (and/or fracture zone) inside the summit caldera of submarine volcanoes. Within these aforementioned points a ring structure, acidic volcanic complexes that circle the circuit and submarine calderas along the volcanic front, are an important indication of submarine hydrothermal deposits.     

从CAD到ArcGIS格式数据转换的精度改进

针对直接利用空间数据操作引擎将CAD注记数据转换成ArcGIS数据与原CAD图文字注记数据存在一定差异的问题,提出了一种新的转换注记方法。利用Arc Map提取CAD原图注记层数据,较好的减少了FME转换的注记的差异,为地形图的转换提供了可行的方案。以某市的地形图为数据源进行实例论证,实验结果显示所提的方法不仅能够更好地保持数据的精度和完整性,还有利于数据的入库。研究结果对从事地理信息系统开发的技术人员具有一定的参考价值。