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991.
Liu Hongbing Kong Xiangru Xiaobing Ma Wang Qianshen Yan Yongli Yan Yafen Yang Zhiqiang 《中国科学D辑(英文版)》2001,44(1):64-76
Chemical reactions of plagioclase, biotite and their single minerals, as well as a mineral mixture of (plagioclase+biotite+quartz),
with KCl and (KCl+KHCO3) solutions were carried out at 150–400°C and 50–80 MPa. Experiments show that alkaline fluid promotes plagioclase’s changing
into potash feldspar, while acid fluid helps plagioclase, potash feldspar and biotite alteration form chlorite and sericite.
After chemical reaction the acidity-alkalinity of solutions often changes reversely. It was observed that gold dissolved from
the tube wall and recrystallized on the surfaces of biotite and pyrite. Therefore the transportation and enrichment of gold
are related to the elementary effect of the fluid-mineral interfaces. Fe3+-Fe2+, as an oxidition-reduction agent, and volatile components Cl- and CO2 play important roles in the reaction process 相似文献
992.
Mário A. Gonçalves 《Mathematical Geology》2001,33(1):41-61
The use of multifractals in the applied sciences has proven useful in the characterization and modeling of complex phenomena. Multifractal theory has also been recently applied to the study and characterization of geochemical distributions, and its relation to spatial statistics clearly stated. The present paper proposes a two-dimensional multifractal model based on a trinomial multiplicative cascade as a proxy to some geochemical distribution. The equations for the generalized dimensions, mass exponent, coarse Lipschitz–Hölder exponent, and multifractal spectrum are derived. This model was tested with an example data set used for geochemical exploration of gold deposits in Northwest Portugal. The element used was arsenic because a large number of sample assays were below detection limit for gold. Arsenic, however, has a positive correlation with gold, and the two generations of arsenopyrite identified in the gold quartz veins are consistent with different mineralizing events, which gave rise to different gold grades. Performing the multifractal analysis has shown problems arising in the subdivision of the area with boxes of constant side length and in the uncertainty the edge effects produce in the experimental estimation of the mass exponent. However, it was possible to closely fit a multifractal spectrum to the data with enrichment factors in the range 2.4–2.6 and constant K1 = 1.3. Such parameters may give some information on the magnitude of the concentration efficiency and heterogeneity of the distribution of arsenic in the mineralized structures. In a simple test with estimated points using ordinary lognormal kriging, the fitted multifractal model showed the magnitude of smoothing in estimated data. Therefore, it is concluded that multifractal models may be useful in the stochastic simulation of geochemical distributions. 相似文献
993.
Tiexin Gu Zhong Zhang Chunshu Wang Weidong Yan 《Geostandards and Geoanalytical Research》2001,25(1):153-158
Two types of gold deposit with both good homogeneity and a high-grade of gold were selected to prepare four gold ore reference materials (GAu-19,GAu-20,GAu-21 and GAu-22) by the Institute of Geophysical and Geochemical Exploration (IGGE),China.Seven laboratories participated in the certification programme. Volumetric methods for GAu19-21 and atomic absorption spectrometry for GAu-22 were used for the homogeneity testing,the coefficient of variation being found to be less than 3%.After sample digestion and preconcentration,the samples were analysed by flame atomic absorption spectrometry (AAS),colorimetry,neutron activation analysis (NAA)and volumetric analysis. The certified values for the gold concentration in GAu19-22 are 18.3 μg g -1, 32.3 μg g -1, 53.0 μg g -1 and 5.72 μg g -1,respectively. 相似文献
994.
The Upper Permian Sedimentary Facies and Its Role in the Dajing Cu-Sn Deposit, Linxi County, Inner Mongolia, China 总被引:3,自引:1,他引:3
Gongjiong QIN Yosuke KAWACHI Liqing ZHAO Yongzheng WANG Qiang OU 《Resource Geology》2001,51(4):293-305
Abstract: Exhaustive investigations were launched for confirming the upper Permian host rocks of the Dajing Cu-Sn Deposit, probing into the possibility that Dajing is a Sedex type deposit during cosedimentation, complementing the deficiency of previous researches and going further into substantiating the role of the upper Permian strata in the control of ore distribution. After more than two years work, we reclassified the sedimentary facies in the Dajing area and its periphery as shallow fresh water lake and delta. Indicative sedimentary structures, such as ripple marks, rain marks, and mud cracks combined with contemporary fossils, were revealed. Having measured the flow directions, performed chemical comparison, and analyzed various sediments from sourceland in the Dajing area by XRF, we consequently redivided the strata into four sedimentary members, among which P2 l1 and P2 l2 were concluded as significant ore-hosted strata. The upper Permian basin was a lateral rift basin. The water and sediments in the basin are much deeper and thicker in the north than those in the south.
The indicators of special sedimentary facies, such as gravity flow, brine pool and synchronogenic stratiform structure of the ore cannot be found in the Dajing area. There was no growth fault, assemblage of sulfide and sulfate, and no zonation as well.
On the basis of study in this area, taking into account the paleosedimentary environment as capriciously flowing shallow lake, which approximated the state of oxidation, we figured that the paleogeography made it prohibitively difficult to form stratiform sulfide deposits which are prone to form in deoxidized environment. It can be ruled out the possibility that the Dajing deposit is a syngenetic deposit during sedimentation. 相似文献
The indicators of special sedimentary facies, such as gravity flow, brine pool and synchronogenic stratiform structure of the ore cannot be found in the Dajing area. There was no growth fault, assemblage of sulfide and sulfate, and no zonation as well.
On the basis of study in this area, taking into account the paleosedimentary environment as capriciously flowing shallow lake, which approximated the state of oxidation, we figured that the paleogeography made it prohibitively difficult to form stratiform sulfide deposits which are prone to form in deoxidized environment. It can be ruled out the possibility that the Dajing deposit is a syngenetic deposit during sedimentation. 相似文献
995.
Abstract: The skarns and genesis were studied of the Huanggang Fe‐Sn deposit and the nearby Sumugou Zn‐Pb deposit in Inner Mongolia, China. In the Huanggang mine, Nos. 1 to 4 Fe ore bodies are arranged along a calcareous horizon from proximal to distal in this order to a granite intrusion named Luotuochangliang, while Sn ore body is situated near another granite intrusion named 204. According to the distance from the granitic intrusions, mineral assemblages in skarns are systematically changed. Garnet is the most predominant skarn mineral throughout the deposit. Hastingsitic amphiboles, however, predominate in the proximal skarns. Fluorite is common in the proximal skarns, while instead calcite is common in the distal skarns. Chlorite is characteristically present only in No. 3 ore body, and chlorite geothermometry gives near 300C for the mineralization of later stage. When garnet crystal shows zonal structure, isotropic andraditic garnet occupies the core, and is surrounded with anisotropic less‐andraditic garnet. The presence of white skarn along the boundary between main skarns and host sedimentary rocks confirms relatively reducing environment prevailing as a whole in the studied area. However, the compositional relation between coexisting garnet and clinopyroxene demonstrates that relatively oxidizing condition was achieved for garnet skarn and magnetite ore in the distal, Nos. 2 to 4 Fe ore bodies and Sumugou deposit, compared to that for garnet skarn in the proximal, No. 1 and Sn ore bodies. Preliminary study on the tin content of garnets in the studied area revealed a certain degree of contribution brought from granitic intrusives since the early stage of skarn formation, irrespective of proximal or distal. Oxygen isotope study on garnet, magnetite, quartz and skarn calcite, as well as hydrogen isotope study on hastingsitic amphibole, demonstrates mainly meteoric water origin for the skarn– and ore‐forming solutions. The occurrence of Sn, W, Mo and F minerals indicates that those elements were mainly supplied to the deposit later than the formation of skarns and iron ores, overlapping to them. These constraints allow to delineate the formation model of the deposit as follows (Fig. 10): At the time of late Jurassic to early Cretaceous, felsic activity occurred in this region as a part of Yanshanian magmatism, and formed granitic intrusions as well as thick volcanic piles on the surface. The circulation of meteoric water was provoked by the heat brought by the intrusions. By this circulation, much amount of iron was extracted from andesites of the Dashizhai Formation, and precipitated as skarns and magnetite ores along calcareous horizons near the bottom of the Huanggangliang Formation. Subsequently, volatile‐rich fluids with Sn, W and Mo were expelled from the solidifying granitic magmas, and precipitated these metals in the pre‐existing skarns and ores. 相似文献
996.
Abstract: The Dajing Cu–Sn–Ag–Pb–Zn ore deposit, Inner Mongolia of China, is a fissure‐filling hydrothermal ore deposit that occurs within the Upper Permian Linxi group. No magmatic pluton and volcanic rocks outcrop on the surface of the deposit. Most of ore veins show clear‐cut boundary with country rocks. Wallrock alterations that include silicification, carbonation, chlori–tization, and sericitization are generally weak and occur in the close vicinity of ore veins. Mineralization is divided into three stages: (1) cassiterite–arsenopyrite–quartz stage, (2) sulfide stage, and (3) Pb–Zn–Ag–carbonate stage. These mineralization stages have distinct ranges of homogenization temperatures, 290–350C for Stage 1, 260–320C for Stage 2, and 150–250C for Stage 3. However, salinities for Stages 1, 2, and 3 overlap and range between 2.2 and 10.4 wt % NaCl equivalent. The dD values relative to V‐SMOW of inclusion water from quartz are lower than –88% and centered at –100 to –130%. The δ34S values relative to CDT of sulfide ore minerals and δ13C values relative to PDB of carbonate gangue minerals, vary from –0.3 to +2.6%, and from –7.0 to –2.9%, respectively. Integrated isotopic data point to two major contributions to the mineralizing fluid that include a dominant meteoric‐derived water and the other from hypogene magma for sulfur and carbon species. Analyses of inclusion gas and liquid compositions are performed. The H2O and CO2 are the two most abundant gaseous components, whereas SO42‐ and Cl‐, and Na+, Ca2+, and K+ are the major anions and cations, respectively. A linear trend is shown on the gaseous H2O versus CO2 plot. Phase separation is excluded as cause for the trend on the basis of isotope data and fluid inclusion microthermometry. In addition, a weak wallrock alteration does not support fluid‐rock interaction as an efficient mechanism. Hence, the linear H2O–CO2 trend is interpreted in terms of absorption or dilution of CO2–dominant magmatic vapor by meteoric‐derived water. Cooling effects resulting from dilution may have caused precipitation of ore minerals. Major and trace element compositions of regional granites show a high‐K calc–alkaline characteristics and an arc–affinity. Lead isotopic compositions of galena samples from the Dajing deposit exhibit elevated U/Pb and Th/Pb ratios. These characteristics indicate a common source of supra subduction zone mantle wedge for regional granites and metals from the Dajing deposit. 相似文献
997.
Rodolfo A. TAMAYO Jr Graciano P. YUMUL Jr René C. MAURY Mireille POLVÉ Joseph COTTEN Marcel BOHN 《Resource Geology》2001,51(2):145-164
Abstract: The Antique ophiolite, located in Panay island (west‐central Philippines), corresponds to several tectonic slices within the suture zone between the Philippine Mobile Belt (PMB) and the North Palawan Block (NPB). It includes dismembered fragments of a basaltic sequence, dominantly pillow‐lavas with minor sheet flows, rare exposures of sheeted dikes, isotropic gabbros, subordinate layered mafic and ultramafic rock sequences and serpentinites. Most of the ophiolite units commonly occur as clasts and blocks within the serpentinites, which intrude the whole ophiolitic body, as well as, the basal conglomerate of the overlying Middle Miocene sedimentary formation. The volcanic rock sequence is characterized by chemical compositions ranging from transitional (T)‐MORB, normal (N)‐MORB and to chemistry intermediate between those of MORB and island arc basalt (IAB). The residual upper mantle sequence is harzburgitic and generally more depleted than the upper mantle underlying modern mid‐oceanic ridges. Calculations using whole‐rock and mineral compositions show that they can represent the residue of a fertile mantle source, which have undergone degrees of partial melting ranging from 9‐22.5 %. Some of the mantle samples display chondrite‐nor‐malized REE and extended multi‐element patterns suggesting enrichments in LREE, Rb, Sr and Zr, which are comparable to those found in fore‐arc peridotites from the Izu‐Bonin‐Mariana (IBM) arc system. The Antique ultramafic rocks also record relatively oxidizing mantle conditions (Δlog fO2 (FMQ)=0.9‐3.5). As a whole, the ophiolite probably represents an agglomeration of oceanic ridge and fore‐arc crust fragments, which were juxtaposed during the Miocene collision of the PMB and the NPB. The intrusion of the serpentinites might be either coeval or subsequent to the accretion of the oceanic crust onto the fore‐arc. Volcanogenic massive sulfide (VMS) deposits occur either in or near the contact between the pillow basalts and the overlying sediments or interbedded with the sediments. The morphology of the deposits, type of metals, ore texture and the nature of the host rocks suggest that the formation of the VMS bodies was similar to the accumulation of metals around and in the subsurface of hydrothermal vents observed in modern mid‐oceanic ridge and back‐arc basin rift settings. The podiform chromitites occur as pods and subordinate layers within totally serpentinized dunite in the residual upper mantle sequence. No large coherent chromitite deposit was found since the host dunitic rocks often occur as blocks within the serpentinites. It is difficult to evaluate the original geodynamic setting of the mineralized bodies since the chemistry of the host rocks were considerably modified by alteration during their tectonic emplacement. A preliminary conclusion for Antique is that the VMS is apparently associated with a primitive tholeiitic intermediate MORB‐IAB volcanic suite, the chemistry of which is close to the calculated composition of the liquid that coexisted with the podiform chromitites. 相似文献
998.
Victor B. MAGLAMBAYAN Daizo ISHIYAMA Toshio MIZUTA Osamu MATSUBAYA Yohei ISHIKAWA 《Resource Geology》2001,51(2):107-116
Abstract: The disseminated Au‐Ag telluride Bulawan deposit, Negros island, Philippines, is hosted by dacite porphyry breccia pipes which formed in a Middle Miocene dacite porphyry stock. Electrum and Au‐Ag tellurides occur mostly as grains intergrown with or filling voids between sphalerite, pyrite, chalcopyrite, galena and tennantite. Calcite, quartz and rare dolomite are the principal gangue minerals. Four types of alteration were recognized in the deposit, namely; propylitic, K‐feldspar‐sericitic, sericitic and carbonate alteration. Carbonate alteration is correlatable to the gold deposition stage and occurs mostly along fault zones. The δ18O and δ13C compositions of calcite and dolomite in propylite zone and ore‐stage dacite porphyry breccia were determined. The δ18O values of calcite in propylitized andesite range from +12.2 to +14.7%, and their δ13C values range from ‐6.1 to ‐1.0%. The δ18O values of calcite and dolomite in sericite‐ and carbonate‐altered, mineralized dacite porphyry breccia and dacite porphyry rocks range from +15.1 to +23.1%, and the δ13C values of calcite and dolomite range from ‐3.9 to +0.9%. The δ18O and δ13C values of the hydrothermal fluids were estimated from inferred temperatures of formation on the basis of fluid inclusion microthermometry. The δ18O values of hydrothermal fluid for the propylitic alteration were calculated to be +8.5 ‐ +9.5%, assuming 375°C. On the other hand, the δ18O values of ore solutions for base metal and Au mineralization were computed to be +13.6 ‐ +14.6%, assuming 270°C. The hydrothermal fluids that formed the Bulawan deposit are dilute and 18O‐enriched fluids which reacted with 18O‐ and 13C‐rich wallrocks such as limestone. 相似文献
999.
Based on the knowing geochemical characteristics of wall rock in the Mobin gold deposit and composition of fluid inclusion in ore,water-rock experiments were carried out,important achievements are acquired as following: Gold is mainly derived from the ore-bearing wall rock,i,e.,a series of epimetamorphic clastic gritstone,sandy slate,and tuffaceous slate in the Wuqiang Banxi Formation,Wuqiangxi Group.In thermal system with middle-low temperature chlorine gold may be derived form stable complex ions,so it is quite important in gold metallogenic process.Sulphur and chlorine perform as the major negative ions throughout the gold activation and migration movement.The concentration of sulphur and chlorine ions,pH value and temperature are of deciding significance for gold activation,migration and precipitation. 相似文献
1000.