A Compilation of Silicon,Rare Earth Element and Twenty‐One other Trace Element Concentrations in the Natural River Water Reference Material SLRS‐5 (NRC‐CNRC)

The natural river water certified reference material SLRS‐5 (NRC‐CNRC) was routinely analysed in this study for major and trace elements by ten French laboratories. Most of the measurements were made using ICP‐MS. Because no certified values are assigned by NRC‐CNRC for silicon and 35 trace element concentrations (rare earth elements, Ag, B, Bi, Cs, Ga, Ge, Li, Nb, P, Rb, Rh, Re, S, Sc, Sn, Th, Ti, Tl, W, Y and Zr), or for isotopic ratios, we provide a compilation of the concentrations and related uncertainties obtained by the participating laboratories. Strontium isotopic ratios are also given.     

柴达木盆地东部36～18kaB.P.期间的孢粉记录及其气候环境

对柴达木盆地察尔汗古贝壳堤剖面的沉积物进行孢粉分析,结果显示这个地区植被与气候在晚更新世中晚期经历以下几个阶段的变化:36.2～31.2kaB.P.(未校正14C年代,下同)期间,以禾本科、藜科、蒿属、莎草科为主,发育草原-草甸植被,气候温和湿润,盘星藻出现较多,反映淡水湖泊,水深在10m左右;31.2～27.6kaB.P.期间,松属、云杉属、桦属等为主的木本植物的含量增加,周围山地森林发育,表明气候温暖,降水量增多。但由于蒸发量大,有效湿度下降,荒漠成分柽柳属等增加,盘星藻在30kaB.P.以后消失,反映湖泊盐度增大;27.6～23.3kaB.P.期间,植被中荒漠成分显著增加,周围山地森林萎缩,气候趋向相对寒冷干旱,湖面积缩小;23.3～18.0kaB.P.,孢粉浓度很低,蒺藜科、藜科等荒漠成分明显增加,植被稀疏,已趋向荒漠化草原,反映气候寒冷干旱。从整个剖面来看,主要的陆生植物孢粉类型为禾本科、柽柳属、蒺藜科、麻黄属、松属、云杉属、柏科、胡桃属和桦属等,藜科和蒿属含量很少,这与柴达木盆地东部地区的表土分析结果完全不同,也与其他草原以及荒漠草原的表土花粉结果相异。这说明晚更新世中晚期柴达木盆地东部地区的植被和现在无法进行比较,气候环境与现在显著不同。     

A Common Reference Material for Cadmium Isotope Studies – NIST SRM 3108

Research into natural mass‐dependent stable isotope fractionation of cadmium has rapidly expanded in the past few years. Methodologies are diverse with MC‐ICP‐MS favoured by all but one laboratory, which uses thermal ionisation mass spectrometry (TIMS). To quantify the isotope fractionation and correct for instrumental mass bias, double‐spike techniques, sample‐calibrator bracketing or element doping has been used. However, easy comparison between data sets has been hampered by the multitude of in‐house Cd solutions used as zero‐delta reference in different laboratories. The lack of a suitable isotopic reference material for Cd is detrimental for progress in the long term. We have conducted a comprehensive round‐robin assay of NIST SRM 3108 and the Cd isotope offsets to commonly used in‐house reference materials. Here, we advocate NIST SRM 3108 both as an isotope standard and the isotopic reference point for Cd and encourage its use as ‘zero‐delta’ in future studies. The purity of NIST SRM 3108 was evaluated regarding isobaric and polyatomic molecular interferences, and the levels of Zn, Pd and Sn found were not significant. The isotope ratio ¹¹⁴Cd/¹¹⁰Cd for NIST SRM 3108 lies within ～ 10 ppm Da^?1 of best estimates for the Bulk Silicate Earth and is validated for all measurement technologies currently in use.     

Heat capacity and phase equilibria of wadeite-type K2Si4O9

The low-temperature heat capacity (C _p) of Si-wadeite (K₂Si₄O₉) synthesized with a piston cylinder device was measured over the range of 5–303 K using the heat capacity option of a physical properties measurement system. The entropy of Si-wadeite at standard temperature and pressure calculated from the measured heat capacity data is 253.8 ± 0.6 J mol⁻¹ K⁻¹, which is considerably larger than some of the previous estimated values. The calculated phase transition boundaries in the system K₂O–Al₂O₃–SiO₂ are generally consistent with previous experimental results. Together with our calculated phase boundaries, seven multi-anvil experiments at 1,400 K and 6.0–7.7 GPa suggest that no equilibrium stability field of kalsilite + coesite intervenes between the stability field of sanidine and that of coesite + kyanite + Si-wadeite, in contrast to previous predictions. First-order approximations were undertaken to calculate the phase diagram in the system K₂Si₄O₉ at lower pressure and temperature. Large discrepancies were shown between the calculated diagram compared with previously published versions, suggesting that further experimental or/and calorimetric work is needed to better constrain the low-pressure phase relations of the K₂Si₄O₉ polymorphs. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

High‐Precision Measurement of 187Os/188Os Isotope Ratios of Nanogram to Picogram Amounts of Os in Geological Samples by N‐TIMS using Faraday Cups Equipped with 1013 Ω Amplifiers

N(¹⁸⁷Os)/N(¹⁸⁸Os) ratios of six geological reference materials were measured using static Faraday cups (FCs) with 10¹³ Ω amplifiers by N‐TIMS. Our results show that the repeatability precision was 2–3‰ (2 RSD, n = 3), when taking ~ 1 g of BHVO‐2 with 76 pg g^?1 of Os mass fraction and ~ 2 g of BCR‐2 with 21 pg g^?1 of Os mass fraction for each sample, whether measured by FCs or by secondary electron multiplier. The repeatability precision measured by FCs was 1–0.2‰ (2 RSD, n = 3) when taking ~ 1 g of BIR‐2 with 350 pg g^?1 of Os mass fraction, ~ 1 g of WGB‐1 with 493 pg g^?1 of Os mass fraction or ~ 0.5 g of WPR‐1 with 13.3 ng g^?1 of Os mass fraction for each sample, which is much better than those measured by secondary electron multiplier. Instead, when taking ~ 2 g of AGV‐2 with 4 pg g^?1 Os mass fraction, the repeatability precision measured by secondary electron multiplier is 3–4‰ (RSD, n = 3), which is better than those measured by FCs. Of the six reference materials analysed, WPR‐1 and BIR‐1a are the most homogeneous with regard to Os isotopic composition (2 RSD of 0.08% and 0.23%, respectively) when test portion masses are 0.5–1 g.     

A Review of the IAG GeoPT™ and Certification Programmes,their Protocols,and the Differences between the Original and Potential Modifications to the Certification Protocol

The IAG conducts two programmes, the GeoPT ^? proficiency test and a certification programme that are closely interconnected. Both support the quality control/quality assurance activities of geochemical laboratories. Each derives an estimate of ‘true value’ for a number of samples, but arrives at that estimate, and its uncertainty, differently. This review discusses the history of the two programmes and compares the ‘true values’ and their uncertainties obtained through each. It then considers ‘fitness‐for‐purpose’ issues related to both GeoPT ^? and certification uncertainties. Issues related to potential modification of the IAG protocol for certification are also considered.     

Determination of Ga,Ge, Mo,Ag, Cd,In, Sn,Sb, W,Tl and Bi in USGS Whole‐Rock Reference Materials by Standard Addition ICP‐MS

A procedure for determining a wide range of chalcophile and siderophile elements in typical crustal rocks using standard addition and ICP‐SFMS (inductively coupled plasma sector field mass spectrometry) is presented. New results for Ga, Ge, Mo, Ag, Cd, In, Sn, Sb, W, Tl and Bi abundances in USGS whole‐rock reference materials AGV‐2, BHVO‐1, BIR‐1, G‐2, GSP‐1 and W‐2 are reported using this analytical procedure. Intermediate precision of means based on multiple dissolved aliquots of each USGS reference material was 10% RSD or better for Ga, Ge, In and Sn in all, and similarly good for Ag, Cd, Sb, Tl and Bi in most reference materials. Poorer intermediate precision of Mo and W measurements in several reference materials is probably due to higher analytical blanks on these elements and powder heterogeneity due to a sulfide‐related nugget effect in the specific case of Mo in GSP‐1. Results for all elements fell within the range of available published data with the exception of Ag, which yielded systematically higher concentrations than found in the literature for five of the six reference materials, likely reflecting interference from unresolved polyatomic species.     

设计院管理信息化建设的体会

通过管理信息平台和图纸打印收集归档利用系统的综合信息化管理,改变了原先不能及时有效得到各专业的实际生产状况和信息不能及时共享的问题,实现了项目管理的每个环节都有可供查询的信息,项目管理人员可随时利用管理信息平台对相关信息和数据进行分析,并形成分析报表,辅助决策。同时通过图纸打印收集归档利用系统对电子图纸进行辅助管理,使设计人员高效快速地对于既往图纸查询、利用。浙江工业大学建筑规划设计研完院的管理信息系统与协同设计工具（图纸打印收集归档利用系统）通过近两年的综合运行,有效降低了设计成本和管理成本,提高了设计人员的生产效率和项目管理人员的管理水平,这种全新的综合应用方式和技术思路有广泛的实用价值和借鉴作用。     

辽宁省沈抚新区区域地壳稳定性评价

在广泛收集资料和野外调查工作的基础上,经综合分析控制和影响区域地壳稳定性的主要因素和内外动力地质的耦合作用,基于ArcGIS平台采用多因素加权叠加分析方法开展了沈抚新区区域地壳稳定性评价研究.评价因素主要选取活动断裂、 地震活动性和深部地球物理以及工程岩组、 地形地貌与地表地质灾害等共12个影响因子,并依据评价因素的关...     

用层次分析法确定气象服务评价指标权重

在气象服务评价体系中,以气象服务总体评价为目标层,分层次确立一级和二级评价指标,利用2010年全国公众气象服务满意度调查中评价指标数据,应用层次分析法 (AHP) 中的9分位标度法和0.618标度法来构建判断矩阵,分析了各级评价指标的权重系数确定方法。分析发现,当评价指标少于5个时,可采用9分位标度法构建判断矩阵,以确定各评价指标的权重值;而当评价指标达到5个时,需采用0.618标度法来构建判断矩阵,计算出相应的权向量即为权重系数。将上述方法应用于2011年公众气象服务满意度调查数据中,前后两年主要评价指标对比显示,气象服务信息内容的权重在增加,而气象知识宣传普及的权重有所减小,即公众对于气象服务信息内容更为重视,同时气象部门对于公众的气象知识宣传普及工作也取得了成效。