Equation of state of MgGeO3 perovskite to 65 GPa: comparison with the post-perovskite phase

The equation of state of MgGeO₃ perovskite was determined between 25 and 66 GPa using synchrotron X-ray diffraction with the laser-heated diamond anvil cell. The data were fit to a third-order Birch–Murnaghan equation of state and yielded a zero-pressure volume (V ₀) of 182.2 ± 0.3 Å³ and bulk modulus (K ₀) of 229 ± 3 GPa, with the pressure derivative (K′₀ = (?K ₀/?P) _T ) fixed at 3.7. Differential stresses were evaluated using lattice strain theory and found to be typically less than about 1.5 GPa. Theoretical calculations were also carried out using density functional theory from 0 to 205 GPa. The equation of state parameters from theory (V ₀ = 180.2 Å³, K ₀ = 221.3 GPa, and K′₀ = 3.90) are in agreement with experiment, although theoretically calculated volumes are systematically lower than experiment. The properties of the perovskite phase were compared to MgGeO₃ post-perovskite phase near the observed phase transition pressure (～65 GPa). Across the transition, the density increased by 2.0(0.7)%. This is in excellent agreement with the theoretically determined density change of 1.9%; however both values are larger than those for the (Mg,Fe)SiO₃ phase transition. The bulk sound velocity change across the transition is small and is likely to be negative [?0.5(1.6)% from experiment and ?1.2% from theory]. These results are similar to previous findings for the (Mg,Fe)SiO₃ system. A linearized Birch–Murnaghan equation of state fit to each axis yielded zero-pressure compressibilities of 0.0022, 0.0009, and 0.0016 GPa^?1 for the a, b, and c axis, respectively. Magnesium germanate appears to be a good analog system for studying the properties of the perovskite and post-perovskite phases in silicates.     

Preliminary evaluation of hydrochemistry of the Kalambaina Formation, Sokoto Basin, Nigeria

Hydrochemical investigations in the Kalambaina Formation have been initiated to determine potability and suitability of the shallow groundwater for domestic and agricultural uses. This limestone formation is an extensive aquifer supplying water to livestock and domestic wells in its outcrop areas. The aquifer is recharged by rainfall and discharges mainly into the Sokoto–Rima River system and lakes at Kware, Gwadabawa and Kalmalo in Nigeria. Because recharge to the aquifer is mainly from rainfall, the quality of the groundwater is controlled essentially by chemical processes in the vadose zone and locally by human activities. Water samples were taken at 11 sites comprising boreholes, dug wells and a spring and were chemically analysed for their major ion components. Hydrochemical results show water of fairly good quality. It is, however, hard and generally of moderate dissolved solids content. Concentration of the total dissolved solids is between 130 and 2,340 mg/l. Concentrations of ions vary widely but a high concentration of K⁺ is found in places. NO₃⁻ is on the higher side of the World Health Organization (WHO) permissible limits, indicating pollution in such areas. Groundwater chemistry is predominantly of two facies, namely the calcium–magnesium–bicarbonate and calcium–magnesium–sulphate–chloride facies. These facies probably evolved primarily as a result of dissolution of calcium and magnesium carbonates as well as some human/land-use activities.     

Palaeomagnetism of the teschenitic rocks (Lower Cretaceous) in the Outer Western Carpathians of Poland: constraints for tectonic rotations in the Silesian unit

Results of palaeomagnetic investigations of the Lower Cretaceous teschenitic rocks in the Silesian unit of the Outer Western Carpathians in Poland bring evidence for pre-folding magnetization of these rocks. The mixed-polarity component reveals inclinations, between 56° and 69°, which might be either of Cretaceous or Tertiary age. Apparently positive results of fold and contact tests in some localities and presence of pyrhotite in the contact aureole suggest that magnetization is primary, although a Neogene or earlier remagnetization cannot be totally excluded since inclination-only test between localities gives 'syn-folding' results. Higher palaeoinclinations (66°–69°) correlate with a younger variety of teschenitic rocks dated for 122–120 Ma, while lower inclinations (56°–60°) with an older variety (138–133 Ma). This would support relatively high palaeolatitudes for the southern margin of the Eurasian plate in the late part of the Early Cretaceous and relatively quick northward drift of the plate in this epoch, together with the Silesian basin at its southern margin. Declinations are similar to the Cretaceous–Tertiary palaeodeclinations of stable Europe in the eastern part of the studied area but rotated ca. 14°–70° counter-clockwise in the western part. This indicates, together with older results from Czech and Slovakian sectors of the Silesian unit, a change in the rotation pattern from counter-clockwise to clockwise at the meridian of 19°E. The rotations took place before the final collision of the Outer Carpathians nappe stack with the European foreland.     

Berriasian (Lower Cretaceous) brachiopods from the Crimea

Four successive assemblages of Berriasian brachiopods distinguished for the first time in the Crimea are correlated with concurrent subdivisions of the ammonoid scale. Berriasian brachiopods are represented by 44 species of 27 genera and 14 families, which are most complete in terms of taxonomic composition as compared to other concurrent brachiopod faunas known elsewhere. The assemblages are dominated by local species. As is proved, the Berriasian brachiopods studied are appropriate for age determination, subdivision and correlation of their host deposits. Their geographic distribution that has been analyzed elucidates connections of the Berriasian sea basins within the Mediterranean paleozoogeographic region.     

Geodynamic significance of granitoid magmatism in the southeast Anatolian orogen: geochemical and geochronogical evidence from Göksun–Afşin (Kahramanmaraş, Turkey) region

In southeast Anatolia, there are number of tectonomagmatic units in the Kahramanmaraş–Malatya–Elazığ region that are important in understanding the geological evolution of the southeast Anatolian orogenic belt during the Late Cretaceous. These are (a) metamorphic massifs, (b) ophiolites, (c) ophiolite-related metamorphics and (d) granitoids. The granitoids (i.e. Göksun–Afşin in Kahramanmaraş, Doğanşehir in Malatya and Baskil in Elazığ) intrude all the former units in a NE–SW trending direction. The granitoid in Göksun–Afşin (Kahramanmaraş) region is mainly composed of granodioritic and granitic in composition. The granodiorite contains a number of amphibole-bearing mafic microgranular enclaves of different sizes, whereas the granite is intruded by numerous aplitic dikes. The granitoid rocks have typical calcalkaline geochemical features. The REE- and Ocean ridge granite-normalized multi-element patterns and tectonomagmatic discrimination diagrams, as well as biotite geochemistry suggest that the granitoids were formed in a volcanic arc setting. The K–Ar geochronology of the granitoid rocks yielded ages ranging from 85.76±3.17 to 77.49±1.91 Ma. The field, geochemical and geochronological data suggest the following Late Cretaceous tectonomagmatic scenario for southeast Anatolia. The ophiolites were formed in a suprasubduction zone tectonic setting whereas the ophiolite-related metamorphic rocks formed either during the initiation of intraoceanic subduction or late-thrusting (∼90 Ma). These units were then overthrust by the Malatya–Keban platform during the progressive elimination of the southern Neotethys. Thrusting of the Malatya–Keban platform over the ophiolites and related metamorphic rocks was followed by the intrusion of the granitoids (88–85 Ma) along the Tauride active continental margin in the southern Neotethys.     

吉林伊通盆地莫里青断陷古近系双阳组储集层成岩作用研究

古近系双阳组是在吉林省伊通盆地莫里青断陷中，油气赋存的主要层位,储层主要为湖底扇和扇三角洲的砂体。依据双阳组储层的大量薄片、扫描电镜、粘土矿物分析的资料研究了该储集层的成岩作用。研究结果表明双阳组储集层：成岩作用经历了压实、压溶、胶结、交代和溶解6方面的作用。双储集层中的自生粘土矿物蒙皂石向伊利石转化具有明显的特征：主要演化过程经历了蒙皂石渐变带，第一迅速转化带和第二迅速转化带，相应的成岩作用阶段可划分为早成岩阶段B期、晚成岩阶段A1期和晚成岩阶段A2期。依据在垂向上的成岩变化,建立了莫里青断陷双阳组储集层的成岩作用演化序列。在垂向上成岩作用的类型和强度均存在明显的差异，造成了储层物性的垂向分带。     

桂北地区早石炭世杜内期的长身贝类的发现及其生物古地理意义

在广西北部兴安县高尚镇金子山剖面下石炭统鹿寨组底部，新发现了长身贝类腕足化石，包括1新种、1个相似种、6个未定种和2个属种未定类型。这些长身贝类以Productellidae和Productidae科的分子为主，另有少量Echinoconchidae和Monticuliferidae科的分子。这些长身贝类全部属于生活在静水环境中的薄壳类型，无一与华南同期地层中已知类型相同。它们之间的差异可能反映了不同沉积环境条件对腕足动物群属种的控制。在鹿寨组底部发现的长身贝类以及近年在桂林南边村和黔南睦化剖面腕足动物群的发现显示出华南台缘斜坡―盆地相区杜内阶中的腕足动物群具有极高的属种分异度，不但有大量见于世界其他地方同期动物群中的分子，也包含有不少原本认为只在维宪阶或更高层位出现的类型或全新的类型，说明华南台缘斜坡―盆地相区不但与世界其他地区的腕足动物群之间存在密切的生物地理区系联系，而且华南台缘斜坡―盆地相区是杜内期腕足动物起源和辐射演化的重要策源地之一。许多属种可能是在这里起源，并迁移扩散到其他地方。     

福建省大田县广平含煤区推覆构造特征及找煤预测

通过对区内推覆构造及地层等的研究，认为广平含煤区推覆体下蕴藏着丰富的煤炭资源，童子岩组煤系地层埋藏深度主要受发育于童子岩组上部的F1、F2推覆断层控制，并圈定出煤炭资源预测前景较好的3个区作为煤炭勘查后备基地。     

吉尔嘎朗图凹陷宝饶洼槽下白垩统层序地层与沉积体系

运用高分辨率层序地层学原理和方法,通过对钻井和地震资料的综合分析,在二连盆地吉尔嘎朗图凹陷下白垩统中识别出1个超长期基准面旋回(二级层序)SSC1和5个长期基准面旋回(三级层序):LSC1,LSC2,LSC3,LSC4,LSC5,分析了各旋回的发育特征。识别出五种类型的沉积体系:滨浅湖近岸水下扇、较深水湖浊积扇、滨浅湖扇三角洲、滨浅湖辫状河三角洲和河流沉积体系,并在等时地层格架内分析了各基准面旋回的沉积体系构成和储层砂体的发育情况。综合分析生、诸、盖条件后认为,在垂向上,LSC3旋回为本区最有利的储集层段,在平面上,本区的油气勘探应主要寻找宝饶构造带辫状河三角洲前缘砂体,主要储层砂体类型为前缘分流水道砂和前缘席状砂。     

华南下寒武统镍钼矿层中铜铅锌矿物的发现及意义

华南扬子地块是我国古热水沉积成矿作用最为发育的地区之一,其热水沉积特性最早引起我国学者的关注。华南下寒武统黑色岩系中赋存多个与热水沉积成矿作用相关的大型、超大型重晶石矿床与N i-Mo-U-V多金属富集层。进一步研究分布在华南扬子地块黑色岩系中的金属、非金属矿床成因及其地球化学特征,对认识华南乃至全球晚震旦—早寒武世生物与环境演化有着十分重要的意义。本文对华南下寒武统镍-钼富集层矿石进行电子探针研究,识别出黄铜矿、黝铜矿等铜的独立矿物;闪锌矿等锌的独立矿物;方铅矿、白铅矿等铅的独立矿物。研究表明,在镍-钼矿石中这些矿物的发现为镍-钼矿层是热水沉积作用产物提供了直接的矿物学证据。