论氢化物的形成及其在分析测试领域的应用

论述了氢化物形成的普遍性、氢化物的物理化学性质、元素周期系各类元素的氢化物类型。认为一些金属离子、非金属离子在酸性介质中与硼氢化钾（钠）作用及金属锌等强还原剂作用生成氢化物。综述了氢化物的形成在分析测试领域的应用：试样分解、分离富集、容量分析、光度分析、原子光谱分析、质谱分析。     

镇泾地区延长组河流相砂体分布与圈闭形成的关系研究

鄂尔多斯盆地镇泾地区侏罗系地层以三角洲-湖泊沉积体系为主,研究区范围内主要发育主河道和部分分流河道砂体。研究区构造平缓,主要为单斜地层、在东南部存在大型鼻状构造。通过对主要储层段(长6、8油层组)砂体分布及与构造之间关系进行研究,分析砂体走向与构造线方向的关系认为在构造单斜地区,当两者相交时(交角β≠0)是形成圈闭的关键因素之一,在大型鼻状构造地区因构造线的弯曲与河道砂体组合可以形成圈闭。根据研究区砂体分布和构造线组合出4种地层-岩性及岩性圈闭。利用构造图与砂体分布图对主要储层段存在的圈闭确定出长6、8油层组10个层圈闭。     

新疆北部石炭纪地层、岩相古地理与烃源岩

依据近几年新疆区域地质调查结果,结合新疆油田与吐哈油田最新勘探成果,通过区域构造背景和沉积充填演化特征推断石炭系沉积建造样式,理顺了新疆北疆地区石炭纪地层层序,目的是推断石炭纪烃源岩发育层段与主力生烃区范围。下石炭统有效烃源岩分布较广,主要发育于北疆西准噶尔达尔布特山前、博格达山前、准噶尔东部陆东—五彩湾地区早石炭世被动陆缘海相和海陆过渡相沉积盆地;上石炭统有效烃源岩分布相对局限,主要发育于东准噶尔克拉美丽山前石钱滩区、布尔津—吉木乃区及库普—三塘湖区海陆过渡相沉积盆地内。石炭系油气成藏严格遵循"源控论",有效生烃区决定其有效成藏范围,所伴随发育的火山岩体决定其富集程度。优选西准噶尔、东准噶尔、库普—三塘湖区、博格达山前区、布尔津—吉木乃区石炭系烃源岩发育区及其相邻构造带,作为今后石炭系油气勘探战略选区的重要领域和区带。     

CSAMT法在松辽盆地伊胡塔地区嫩江组中的定位应用

上白垩统嫩江组不仅是松辽盆地南部重要的生油层系,而且在本区砂岩型铀成矿中也起着非常重要的作用。从ZK4孔的方法过井测深试验以及地电结构的对比分析入手,对探区内嫩江组的空间分布范围进行了分析研究,通过钻探施工,证实了CSAMT法应用的有效性。     

川西南周公山及邻区下二叠统碳酸盐岩成岩作用对储集性的影响

川西南周公山及邻区下二叠统的中-低孔、中-低渗碳酸盐岩储层的储集空间以次生成因的溶孔、溶洞和构造裂缝为主.研究认为,多世代方解石胶结、化学充填作用以及埋藏期的压实(溶)作用是孔隙很难得到保存的主要原因;同生-准同生期的混合水云化作用和表生期、埋藏期的流体溶蚀作用则产生了大量的次生溶孔、洞,使储层的孔渗性得到明显的改善;构造破裂作用可以产生新的储集空间,还影响各储集体之间及单一储集体内部空隙的连通.成岩相分为混合水云化-溶蚀-破裂相、溶蚀-胶结相和胶结-压实-压溶相.各种成岩作用的叠加形成了现今下二叠统油气储层的分布格局.     

A New Female Cone, Araucaria beipoiaoensis sp. nov. from the Middle Jurassic Tiaojishan Formation, Beipiao, Western Liaoning, China and Its Evolutionary Significance

A new species of Araucaria, Araucaria beipiaoensis sp. nov., collected from the Middle Jurassic Tiaojishan Formation, southern hill of Shebudai village, near Beipiao city, western Liaoning is based on a permineralized female cone, which is ovate to elliptical in shape, about 11 cm × 7 cm × 4.5 cm in size. The cone bears rhomboid bracts that are spirally attached, texture thicker, with wings on both sides, with a detached lamina-like apex at the tip. In inner structure the ovuliferous scales are thicker and fused with bracts at the end with a ligular sulcns. There is one wingless ovule/seed per seed-scale complex embedded in the ovuliferous scale tissue, with the micropyle directed toward the cone axis. The ovules/seeds are long ovate or elliptical in shape, 1 cm long and near the base about 3 mm in diameter; the ovule/seed integuments have begun differentiation into 3 layers： the sarcotesta, sclerotesta, and endotesta. The nucellus is free from the enclosing integuments except in the chalazal region where it is fused to the inner layer （endotesta） of integument. Some ovules show cellularized nucellar tissue. Mature seeds exhibit the papery-thin wavy nucellus characteristically near to the micropyle. The embryonic tissue appears to be four cotyledons. The morphology and structure of the cone shows a close relationship to the araucarian cones of fossil and living genera but differs from any known species. The new species is distributed in the Middle Jurassic of the northern hemisphere, especially Asia, and has important significance for the evolution of the Family Araucariaceae.     

金沙江下咱日堆积体的成因和稳定性初步分析

下咱日堆积体的稳定性对拟建的梨园水电站大坝和附近的水力设施有着重要的意义。利用下咱日堆积体的勘察资料,本文分析后认为下咱日堆积体经历了中更新世的金江冰期和晚更新世的丽江冰期两次冰期的作用,是由冰碛物、河流沉积物、湖相沉积物及崩积物组成的复杂成因堆积体;稳定性初步分析认为,下咱日堆积体局部有坍塌,但是整体稳定,以后稳定与否的关键是堆积体中湖相沉积层及坡脚的松散砾石层的稳定性。     

塔里木盆地塔河地区下石炭统巴楚组沉积演化

以塔里木盆地加里东期和海西两期构造运动为背景,结合现有的岩心、露头、测井、录井和地震资料,对巴楚组可识别出早期的辫状河三角洲沉积,中期的渴湖沉积和盐湖沉积,以及晚期的咸化溻湖沉积。本文分别从横向上和纵向上对塔河地区巴楚组沉积演化进行深入分析;总结了巴楚组构造运动与沉积响应之间的关系,以期为该地区的下石炭统巴楚组的进一步勘探提供科学依据。     

Coalification in Carboniferous sediments from the Lötschberg base tunnel

Vitrinite reflectance (Rr), proximate analysis and carbon isotope composition (δ¹³C) have been used to characterise coal samples from two zones of Late Carboniferous sediments (Gastern and Ferden) in the Aar massif where they are penetrated by the Lötschberg base tunnel (constructed between 1999 and 2005). Samples are characterised by variable ash yields (21.7–93.9%; dry basis); those with ash yields of less than ~50% and with volatile matter content (V;dry ash-free basis) within the limits 2 < V% ≤ 8 are anthracite. Values of Rr range from 3.89% to 5.17% and indicate coalification to the rank of anthracite and meta-anthracite in both Gastern and Ferden Carboniferous zones. Samples of anthracite and shale from the Gastern Carboniferous exhibit a relatively small range in δ¹³C values (–24.52‰ to –23.38‰; mean: –23.86‰) and are lighter than anthracite samples from the Ferden Carboniferous (mean: –22.20‰). The degree of coalification in the Gastern and Ferden Carboniferous zones primarily depends on the maximum rock temperature (T) attained as a result of burial heating. Vitrinite reflectance based estimates of T range from ~290° –360 °C. For a proposed palaeogeothemal gradient of 25 ° C/km at the time of maximum coalification the required overburden is attributable to relatively thin autochtonous Mesozoic/Cenozoic sedimentary cover of the Aar massif and Gastern granite and deep tectonic burial beneath advancing Helvetic, Ultrahelvetic and Prealpine (Penninic) nappes in Early Oligocene to Miocene.