高压下玄武岩浆的不混溶及其对双峰式火山岩的成因意义

我们在温度850～1300℃,压力1.0～3.0GPa和含约2%水的条件下的碱性玄武岩熔融实验产物中发现在高于2.0GPa压力下玄武岩熔融后的淬火产物中存在着两种不同成分的玻璃,其中一种呈褐色,另一种为浅色或无色.玻璃的电子探针分析结果表明,褐色玻璃具有相对高的MgO、FeO和相对低的SiO2、K2O、Na2O含量及Na2O＞K2O的特征.熔体的不混溶间隙与温度无明显关系,但与压力关系密切,即在大于2.0GPa的压力条件下两种玻璃的不混溶间隙突然增大.因此,由不混溶作用形成的双峰式火山岩应来自大于2.0GPa的上地幔,且是能够提供酸性端员物质以及快速上升的构造环境.这与双峰火山岩可以产生于大陆裂谷环境或主要产于俯冲带的弧后拉张环境而不是岛弧前缘一致.     

内蒙古东部森林沼泽区1∶20万区域化探工作回顾

通过对内蒙古东部森林沼泽区开展1∶20万区域化探4个不同阶段工作方法技术及效果的回顾和总结,认为在不同时期的工作方法技术随着对森林沼泽区这一特殊景观的认识不断加深,其工作方法技术也在不断改进,发现矿点8处、矿化点17处,其中,银锌矿17处、金矿1处,取得了较好的地球化学勘查成果,所完成图幅较客观地反映了工作区区域构造、成岩成矿作用的表层地球化学面貌,大大提高了地球化学信息的可靠性和真实性。     

灰色GM(1,1)模型最优维数的研究

灰色GM(1,1)模型的维数对模型的预测精度有很大的影响,本文通过自编的FORTRAN程序,在合适的范围内对GM(1,1)模型的维数进行自动优化,通过对宁波市地面沉降数据的计算分析,得到了C和P的定性关系,确定了优化的评价标准,维数最优化后的模型能反映预测数列变化幅度的大小。     

灾害预报与鸡西煤矿瓦斯爆炸事件

2002年上半年,伴随着厄尔尼诺现象的日益加剧,全球性重大自然灾害频繁发生.6月20日发生在中国黑龙江省鸡西煤矿的瓦斯爆炸事件和6月22日发生在伊朗的强烈地震,时间恰逢月亮近地潮的6月19日和太阳潮半日形变最大值的夏至的6月21日附近,是地球形变和排气较强烈的时段.据国内外有关资料,月球与地球发震有关系的重要条件是“近地点兼朔、望”以及各大行星特定位置的配合,张元东称之为“特殊天象组合期”[1];郭增建等提出,月亮赤纬角或太阳黄赤交角最大时地球形变和排气最强烈[2～5].在此期间,中国各种大的突发性灾难,如空难、海难、火车事故、矿…     

柯坪塔格推覆构造几何学、运动学及其构造演化

大量野外构造地质调查和深部构造解释表明柯坪塔格推覆构造由多组倒转复式背斜、复式箱状背斜构成的推覆体及其前缘逆冲断裂组成 ,由寒武系—第四系组成的推覆体由北向南逆—斜冲 ,平面上构成向南凸出的弧形推覆构造 ;普昌断裂由各不相连的逆冲斜冲断裂段组成 ,而不是完整的一条走滑断层 ,各推覆体前缘逆冲断裂与各推覆体的普昌断裂段共同构成统一的前缘逆冲斜冲逆冲断裂和推覆构造系统 ;普昌断裂段以西的推覆体具有向东抬升、向西倾覆的鼻状构造特征 ,普昌断裂段以东的推覆体具有向西抬升、向东倾覆的鼻状构造特征 ,普昌基底隆起带是巴楚隆起隐伏在柯坪塔格推覆构造之下的部分。各推覆体前缘断裂在深部均归并于统一的寒武系底部的滑脱面 ,其南浅北深 ,东浅西深 (普昌隆起带以西 )或西浅东深 (普昌隆起带以东 ) (6 10km ) ,埋深较大区发育多组滑脱面。柯坪塔格推覆构造的形成时期为晚第四纪 ,为现今活动的推覆构造系统。文中认为各推覆体向南西的倾覆端基底滑脱面和中新生界内部的滑脱面没有贯通 ,是未来 6级以上地震的发震构造部位。     

Microbial Degradation of Tar Oil Compounds under Different Redox Conditions

The microbial transformation of typical tar oil compounds such as acridine, benzo(b)thiophene, dibenzofuran, indane, and indene under different redox conditions was investigated in microcosm studies. Under aerobic conditions the inherent contamination in polluted soil as well as the added N‐, S‐, O‐ heterocyclic and homocyclic compounds were transformed predominantly apart from thiophene. 1‐Indanone was detected by RP‐HPLC‐DAD and GC‐MS as an intermediate metabolite from indane and indene. Under nitrate and sulfate reducing conditions indane, benzo(b)thiophene, and dibenzofuran were transformed in assays with the polluted soil samples from well B 65 and B 66 within 426 days, whereas they were persistent in assays with the highly polluted soil B 67. All heterocyclic and homocyclic compounds added to the non‐contaminated soil from well B 85 were not degraded under nitrate and sulfate reducing conditions, too. The results indicate that for the decision, wether natural attenuation can be implemented in the remediation of contaminated site, in addition to BTEX and PAHs especially the fate of further tar oil compounds in anoxic aquifers has to be considered.     

Optimization of the Sampling Technique for the Determination of Dissolved Hydrogen in Groundwater

In this study a field‐sampling technique for dissolved hydrogen (H₂) in groundwater will be presented which allows the transport of gaseous samples into the laboratory for further analysis. The method consists of transferring the headspace trapped in a gas‐sampling bulb which is continuously purged by groundwater into previously evacuated vials using a gas‐tight syringe. Three transfer steps with preceding evacuation of the vial led to a H₂‐recovery of 100 % in laboratory experiments. The method has been applied to determine H₂ concentrations in an aquifer contaminated with chlorinated solvents. Tests concerning the effect of different pumping techniques on H₂ concentrations revealed that most reliable values were obtained with a bladder pump, while an electrically driven submersible pump generated considerable amounts of hydrogen due to electrochemical interactions with the sampled water. Concentrations of dissolved hydrogen in field and laboratory samples were about two orders of magnitude higher when sampling was performed with the electrically driven submersible pump compared to sampling with the bladder pump and a peristaltic pump. Lab experiments with a Plexiglas reservoir to produce H₂‐enriched water were used to study the effect of two tubing materials (PVC, polyamide) on H₂ losses. PVC tubing turned out to allow transfer of H₂‐enriched water over 25 m without significant losses, while PA‐tubing was not suitable for sampling of H₂.     

新技术在北极星天文方位角测量中的应用

使用GPS接收机的UTC作为北极星天文方位角测量的时间比对的标准时间，利用推估UTl与UTC的差值，将时间归算到UTl的方法，可满足各等级天文方位角测量的要求，现场计算零点恒星时和北极星坐标的精度满足北极星天文方位角测量的要求，实现了现场评估测量精度。     

自适应GM(1,1)模型进行地表沉降预报

提出采用自适应GM( 1 ,1 )模型进行地表沉降预报 ,并用于兖州某矿形变控制点的沉降预报 ,效果令人满意。说明此模型具有实用价值。     

A Reappraisal of Rb, Y, Zr, Pb and Th Values in Geochemical Reference Material BHVO-1

The geochemical reference material BHVO-1 was analysed by a variety of techniques over a six year period. These techniques included inductively coupled plasma-mass spectrometry and atomic emission spectroscopy (ICP-MS and ICP-AES, respectively), laser ablation ICP-MS and spark source mass spectroscopy. Inconsistencies between the published consensus values reported by Gladney and Roelandts (1988, Geostandards Newsletter) and the results of our study are noted for Rb, Y, Zr, Pb and Th. The values reported here for Rb, Y, Zr and Pb are generally lower, while Th is higher than the consensus value. This is not an analytical artefact unique to the University of Notre Dame ICP-MS facility, as most of the BHVO-1 analyses reported over the last ten to twenty years are in agreement with our results. We propose new consensus values for each of these elements as follows: Rb = 9.3 ± 0.2 μg g-1 (compared to 11 ± 2 μg g-1), Y = 24.4 ± 1.3 μg g-1 (compared to 27.6 ± 1.7 μg g-1), Zr = 172 ± 10 μg g-1 (compared to 179 ± 21 μg g-1), Pb = 2.2 ± 0.2 μg g-1 (compared to 2.6 ± 0.9 μg g-1) and Th = 1.22 ± 0.02 μg g-1 (compared to 1.08 ± 0.15 μg g-1).