钾玄岩系列:藏东玉龙铜矿带含矿斑岩元素地球化学特征

西藏东部玉龙铜矿带,包括玉龙、扎拉尕、莽总、多霞松多和马拉松多等斑岩型Ｃｕ,Ｍｏ,Ｐｂ,Ｚｎ,Ａｕ,Ａｇ和Ｐｔ等多金属矿床．由于分析技术条件的限制,前人所获得的含矿斑岩微量元素数据精度较低．采用先进的ＰＥＥｌａｎ６０００型电感耦合等离子质谱仪（ＩＣＰ－ＭＳ）分析微量元素（包括稀土元素）,结果表明含矿斑岩和共生的钾质碱性深成岩、火山岩和煌斑岩在时空上具一致性,岩石化学成分均富碱（ｗ（Ｋ２Ｏ）＋ｗ（Ｎａ２Ｏ）＞８％）,高钾和ｗ（Ｋ２Ｏ）／ｗ（Ｎａ２Ｏ）比值远大于１,微量元素富集Ｓｒ,Ｂａ等大离子亲石元素和轻稀土元素等,均显示出钾玄岩系列岩石的特征,暗示西藏东部玉龙铜矿带的含矿斑岩属于典型的钾玄岩系列的斑岩     

中甸岛弧带构造格架及斑岩铜矿前景

中甸岛弧带属于中国西南三江构造-岩浆-成矿带中义敦岛弧的南端,其中有2条蛇绿混杂岩带存在,即EW向展布的洛吉蛇绿混杂岩带和近NS向分布的属都蛇绿混杂岩带.前者是中甸岛弧带与扬子地台的构造分界线,而后者则将岛弧带内的东、西两个火山岛弧带分开.西部岛弧带较早,活动时期为250～237 Ma;而东部岛弧带相对较晚,活动时期在218～203 Ma.从岛弧带活动时段(250～203 Ma)分析,属都蛇绿混杂岩带所对应的洋盆(属都洋)的活动时段当在250 Ma之前后,与甘孜理塘洋活动时段相近.属于峨眉山大火成岩省的一部分.2条蛇绿混杂岩带内的玄武岩的岩石学特征均表现为大洋拉斑玄武岩.中甸地区岛弧带内东、西两个斑岩带的斑岩型铜矿的找矿远景极大,尤以东斑岩带前景最佳,普朗斑岩铜矿床远景规模在大型以上.中甸斑岩铜矿将成为中国又一重要的斑岩铜(多金属)矿矿产地,具有极好的找矿前景.     

天鹿铜矿床粉砂岩型铜矿石特征

天鹿铜矿床是前陆盆地古生代海相砂页岩型铜矿，铜矿石主要为粉砂岩型，包括辉铜矿矿石、辉铜矿斑铜矿矿石、斑铜矿矿石、黄铜矿斑铜矿矿石、黄铜矿矿石、黄铁矿黄铜矿矿石6种自然类型，矿石结构主要为结晶结构和交代结构，矿石构造以浸染状为主，主矿层中的矿化沿岩层厚度具有明显的垂直分带性，从底部到顶板为：辉铜矿→斑铜矿→黄铜矿→黄铁矿，为典型的化学沉积成因铜的硫化物排列组合特征，上述特点与我国及国外海相砂页岩型铜矿一致。     

古剂量勘查技术

本文首次报道了我国 An晕勘查法和石英电子自旋共振勘查法的理论和实现该方法研制出的微机化仪器和测量技术 ,以及古剂量勘查法应用于拉拉铜矿中得到的新认识     

小寺沟铜钼矿成岩-成矿系统浅析

河北小寺沟斑岩铜钼矿是华北地区一个大型铜钼矿床。本文通过分析小寺沟岩体地质特征,认为本岩体为脉动式侵入的浅成复式岩体,呈岩枝状产出,且岩石具典型的斑状结构;通过剖析岩体主量元素与稀土元素特征,认为属典型的Ⅰ型花岗岩;综合分异指数、Mg#指数和无铕异常等多方面特征,认为结晶分异作用在斑岩岩浆演化中不占主导地位,而岩浆来源于下地壳部分熔融与加入的玄武质岩浆。以上特征均与斑岩型铜钼矿床含矿岩体相当。最后,通过矿床硫同位素及硫化物稀土元素特征的研究,利用对比分析法,揭示研究大型斑岩型矿床的要素。     

高钙碳酸盐地质样品中铜镍的测定

用电感耦合等离子体质谱法和电感耦合等离子体发射光谱法测定高钙碳酸盐样品中的铜和镍。通过试验分析了高钙碳酸盐样品中钙对铜、镍测定的影响,并确定其影响因子,提出两套检测高钙碳酸盐样品中铜、镍的方案。方法经国家标准物质验证,测定值与标准值相符;相对标准偏差(RSD,n=10)两元素均小于2%。     

The Whole‐Rock Geochemical Composition of the Wudaogou Group in Eastern Yanbian,NE China–New Clues to Its Relationship with the Gold and Tungsten Mineralization and the Evolution of the Paleo‐Asian Ocean

The late Paleozoic Wudaogou Group, one of the oldest metamorphic units in the eastern Yanbian area, has important tectonic and metallogenic significance. Here, we provide new insights into their protoliths, tectonic setting of the metamorphic rocks and their relationships with the gold and tungsten mineralization, using new petrographic and whole‐rock geochemical data for various lithologies within the Wudaogou Group. The protolith of the metamorphic rocks of the Wudaogou Group was intermediate–basic volcanic rocks (e.g. basaltic andesite, trachyandesite, and basalt) and sedimentary rocks including argillaceous rocks, quartz sandstone, arkose and clayish greywacke, as well as pyroclastic sedimentary rock, covering tuffaceous sandstone. Before undergoing late Paleozoic epidote–amphibolite facies regional metamorphism, these protoliths were formed during the middle–late Permian in an island arc setting within a continental margin collage zone. Combined with the regional tectonic evolution, it can be speculated that the formation and the subsequent metamorphism of the protoliths of the metamorphic rocks from the Wudaogou Group were influenced by the change from subduction to collision of the Paleo‐Asian Ocean. Similarities of the rare earth element (REE) patterns and parameters among the metamorphic rocks within the Wudaogou Group, auriferous ores from the Xiaoxi'nancha gold (copper) deposit, and scheelites from the Yangjingou tungsten deposit, together with the favorable metallogenic element contents within the metamorphic rock series, imply that the Wudaogou Group could provide parts of metallic material for the gold and tungsten mineralization in the eastern Yanbian area, as exemplified by the Yangjingou deposit and Xiaoxi'nancha deposit, respectively. Further, the metamorphic sedimentary rocks, especially the metamorphic sandstones, quartz schists and quartz mica schists within the Wudaogou Group, have closer genetic relationships with the Yangjingou tungsten mineralization. However, the specific lithologies within this group which control the gold mineralization are still uncertain, and need further research.     

阿尔金山喀腊大湾铁矿田地质特征与形成时代

阿尔金山喀腊大湾铁矿田位于北东向阿尔金走滑断裂与东西向阿尔金北缘断裂所夹持的地区。通过对已有铁矿床地质特征的研究,确认喀腊大湾地区铁矿床属于火山沉积型,因此,铁矿床具有成带状分布的特点,由八八铁矿床、八八西铁矿床、7914铁矿床、7915铁矿床、7918铁矿床和7910铁矿床共同构成喀腊大湾铁矿田。铁矿田范围内的地层以向北陡倾的单斜层为主,倾角75~88°;仅矿田西段八八西铁矿床、八八铁矿床一带沿走向发生直立陡倾伏(背斜)褶皱,可见地层和含矿岩系局部发生褶皱重复,形成铁矿带和含矿层位呈横卧"勾"状形态。铁矿床的产出严格受火山沉积岩系的特定层位和岩性控制,即铁矿床均产在卓阿布拉克组第三亚组第一岩性段(下部玄武岩段)的上部,其北侧为卓阿布拉克组第三亚组第二岩性段(大理岩段)标志层。与铁矿床关系密切的中基性火山岩锆石SHRIMP U-Pb年龄为(517±7)Ma,显示该套火山沉积岩系中基性火山岩的时代为早古生代晚寒武世,因此,铁矿床的形成(火山-沉积)时代为晚寒武世。铁矿床形成之后主要发生2期地质构造事件,其一是发生了构造变形,致使铁矿体及含铁岩系均呈陡立状态,并形成褶皱;其二是中酸性岩浆侵入活动,使已经形成的铁矿床受到中酸性侵入岩的吞食破坏,并发生接触变质矽卡岩化改造。矽卡岩化改造时代为早奥陶世末期(辉钼矿铼锇等时线年龄480 Ma)。     

Geological characteristics and metallogenic prospect of marine volcanic rock-type copper deposits in eastern Kunlun Mountains area,Xinjiang

The Katelixi Cu-Zn deposit is a marine volcanic rock-type copper deposit discovered for the first time in the Tokuzidaban Group in eastern Kunlun Mountains area. It is hosted in the Lower Carboniferous Tokuzidaban Group volcanic strata. The orebodies are obviously controlled by the strata and their ore-bearing rocks are a suite of greyish-green mafic tuffs, generally parallel-stratiform, stratoid and lenticular in form, occurring in limestone as well as in the contact between limestone and carbon-bearing siltstone. This ore deposit possesses distinct characteristics of marine volcanic rock sedimentaion. The geological, petrochemical and REE characteristics of its occurrence pro-vide strong evidence suggesting that this deposit is of marine volcanic rock sedimention origin, basically identical to those of some typical marine volcanic rock-type copper deposits in Xinjiang and other parts of China. Marine vol-canic rocks are well developed in the Lower Carboniferous Tokuzidaban strata in eastern Kunlun Mountains area. In addition to this deposit, we have also found a number of copper polymetallic ore deposits or occurrences in associa-tion with marine volcanc activities in many places where there is a good metallogenic prospect. A breakthrough in the understanding of ore prospecting and genesis has not only filled up the gap in prospecting this type of ore depos-its in this area, but also is of great significance in directing exploration of this type of ore deposits in this area.     

易门狮子山铜矿流体包裹体研究

在总结狮子山铜矿床地质特征基础上,开展了流体包裹体岩相学、显微测温、成分分析等研究,结果表明狮子山铜矿成矿流体为H2O-NaCl体系,包裹体分三大类:含子矿物包裹体(S型)、液体包裹体(W型)和气体包裹体(V型)。S型包裹体为气液固三相包裹体,子矿物多为石盐,加热时常晚于气相均一为液相。均一温度范围广,在192～570℃之间,盐度在31.2%～69.63%NaCleqv之间,高温高盐度流体包裹体的存在说明有深源流体叠加;W型包裹体均一温度范围在98～583℃之间,盐度低至中等,在3.55%～22.98%NaCleqv之间;V型包裹体为高温(平均454℃)低盐度(平均9.54%NaCleqv)包裹体;矿区高温阶段不同相比的S型、V型、W型包裹体共生,且均一温度相同,说明成矿流体经过沸腾作用。