新疆小热泉子铜(锌)矿床同位素研究

小热泉子矿床是我国最近发现的一个中型富铜( 锌) 矿床,其矿床成因为众多的矿床学家所关注。本文对该矿床中不同类型矿石、矿物的S、O、H、Si 及稀有( 惰性) 气体He、Ar 同位素特征作了较祥细的论述,同时用KAr 法对硫化物的年龄测定进行了初步尝试。该矿床硫化物的δ34S 值为+ 1-5 ‰～+ 11-1 ‰,平均为6-15 ‰(46) ;3 He/4 He( 初始) 值为5 ×10 - 8 ～2-17 ×10 - 6 ,平均为0-64 ×10 - 6(6) ,40 Ar/36Ar 值为305-27     

LMWOA (low molecular weight organic acid) exudation by salt marsh plants: Natural variation and response to Cu contamination

This work aimed to evaluate, in vitro, the capability of roots of two salt marsh plants to release low molecular weight organic acids (LMWOAs) and to ascertain whether Cu contamination would stimulate or not organic acids exudation. The sea rush Juncus maritimus and the sea-club rush Scirpus maritimus, both from the lower Douro river estuary (NW Portugal), were used. Plants were collected seasonally, four times a year in 2004, during low tide. After sampling, plant roots were washed for removal of adherent particles and immersed for 2 h in a solution that matched salinity (3) and pH (7.5) of the pore water from the same location to obtain plant exudates. In one of the seasons, similar experiments were carried out but spiking the solution with different amounts of Cu in order to embrace the range between 0 and 1600 nM. In the final solutions as well as in sediment pore water LMWOAs were determined by high performance liquid chromatography. Plants were able to release, in a short period of time, relatively high amounts of LMWOAs (oxalate, citrate, malate, malonate, and succinate). In the sediment pore water oxalate, succinate and acetate were also detected. Therefore, plant roots probably contributed to the presence of some of these organic compounds in pore water. Exudation differed between the plant species and also showed some seasonally variation, particularly for S. maritimus. The release of oxalate by J. maritimus increased with Cu increase in the media. However, exudation of the other LMWOAs did not seem to be stimulated by Cu contamination in the media. This fact is compatible with the existence of alternative internal mechanisms for Cu detoxification, as denoted by the fact that in media contaminated with Cu both plant species accumulated relatively high amounts (29–83%) of the initially dissolved Cu. This study expands our knowledge on the contribution of globally dominant salt marsh plants to the release of LMWOAs into the environment.     

Accumulation of Cu and Zn in discarded antifouling paint particles by the marine gastropod, Littorina littorea

The short-term (5 day) accumulation of Cu and Zn in different tissues of the marine gastropod, Littorina littorea, has been studied in the presence of 10 mg l⁻¹ of antifouling paint particles and pre- or simultaneously contaminated algal food (Ulva lactuca). Accumulation of Cu was observed in the head–foot, digestive gland–gonad complex and gills to extents dependent on how and when food was contaminated and administered. However, retention of Zn was only observed in the gills and only when L. littorea and U. lactuca were simultaneously exposed to paint particles. Relative to the alga, faecal material was highly enriched in Zn, suggesting that the animal is able to rapidly eliminate this metal, most likely through the formation and egestion of insoluble phosphate granules. Thus, L. littorea is a useful biomonitor of marine contamination by antifouling applications in respect of Cu but not Zn.     

Predicting size effect on diffusion-limited current density of oxygen reduction by copper wire

The size effect of copper wire radius (0.04–0.82 mm) on the diffusion-limited current density of an oxygen reduction reaction in stagnant simulated seawater (naturally aerated 0.5 mol/L NaCl) is investigated by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) and compared with the results obtained in 0.5 mol/L H2SO4. In the oxygen diffusion-limited range, size effect is found to occur independent of electrolytes, which is attributed to non-linear diffusion. Additionally, to sati...     

长营岭—龙门冲原生晕异常及找矿预测

通过对珊瑚矿田长营岭－龙门冲地区岩石地球化学测量,圈定了该区Ｗ、Ｓｎ、Ｃｕ、Ｚｎ、Ａｓ、Ｂ、Ｆ等元素异常,原生晕严格受ＮＥ和ＮＷ两组断裂控制。综合评价认为处于长营岭钨锡矿带南延带的南风井多元素组合异常是矿异常,该异常明显地受ＮＥ（Ｆ９）断裂和ＮＷ（Ｆ１０）断裂控制,浓集中心位于Ｆ９断裂下盘,与长营岭矿区矿体在ＮＷ断裂下盘富集的规律相同。测区内,异常形态与北区具连续性,异常强度弱于北区,组分分带显示以隐伏花岗岩为成矿中心,但沿矿带由ＮＥ到ＳＷ并无明显的组分分带和元素组合变化,矿田内不仅矿带南延并向ＳＷ方向倾伏,而且很有可能深部隐伏花岗岩体亦分枝向南延伸。     

广东省典型矿区生态复绿遥感调查研究

以多期遥感数据为数据源,采用人机交互解译方法提取了广东省大宝山多金属矿、云浮硫铁矿、石菉铜矿3个典型矿区生态复绿的位置、面积、变化趋势,结合野外实地调查,查明了矿区生态复绿现状,结果表明:大宝山多金属矿共有3个生态复绿区,生态复绿面积总计约10.08万m~2;云浮硫铁矿生态复绿区主要位于东南部采场,面积总计约65.21万m~2;石菉铜矿总计有生态复绿区25.4万m~2,其中已复绿区15.4万m~2,正在复绿区10.0万m~2,还有大片区域急需复绿。最后总结了3个矿区生态复绿措施和效果,并提出值得借鉴的地方和存在的不足。该文采用的技术方法能够为其他矿区特别是大范围矿区生态复绿的快速提取提供有益的参考。     

新疆库车县盐水沟北铜矿床地质特征及成因探讨

盐水沟北铜矿区位于新疆库车县北部,其大地构造位置处于塔吉克-塔里木陆块区、塔里木陆块、塔里木北缘隆起、库车前陆盆地,区内构造活动强烈。铜矿床赋存于新近纪中新统康村组第一岩性段,矿体呈层状,严格受地层控制。区内共圈定10个铜矿体,矿石矿物主要为孔雀石、赤铜矿、水胆矾、自然铜等,矿体内无夹石,顶、底板围岩均为褐红色及浅红色粉质泥岩。该矿床为砂岩型铜矿床。     

中国中元古代裂谷作用及其对层控铜矿床的控制

本文以中国几个重要的层控铜矿为例,并以东川式铜矿及其成矿构造背景——昆阳拗拉谷为重点,分析了它们的大地构造背景和其它地质特征,指出它们均受裂谷—拗拉谷或类似的拉张-裂陷构造所控制,并归纳了这类矿床的主要特征。     

块状硫化物矿床的地球化学找矿标志

近年来国外发现了许多大型块状硫化物矿床，而我国进展还不大。原因之一是我们对这类矿床的地质特征，成矿条件尤其是找矿标志研究还不够。这是一类成矿物质通过热液作用在海底沉积而成的特殊矿床，故在找矿勘探讨既要研究沉积矿时形成的原生晕，又要研究热液经过围岩时蚀变而产生的次生晕?Ｍｎ晕，Ｔｌ，Ｈｇ，Ｂａ，Ａｓ和Ｚｎ等元素的异常，络合剂元素的富集，微量元素的分布，铅同位素，岩石化学异指数尤其是块状硫化物Ｃｕ矿中     

滇中郝家河砂岩铜矿的地球化学及其成因意义

本文论术字滇中生代地层与矿区及春外围马头山组中铜的时空分布与迁移富集规律，揭示了矿床的沉积－后期叠加改造成因。成矿作用经历了同生沉积形成矿源层，后期叠加改造形成矿体的过程。后期改造中铜元素发生了大量迁移，矿质主要来自矿体之下伏紫色矿源层。