CO2浓度升高对浮游藻类元素化学计量值的影响

通过梅梁湾和东太湖的四季原位实验,研究CO_2浓度升高对不同营养水平淡水生态系统中浮游藻类C、N、P元素计量值的影响.实验设置了270、380和750 ppm共3个CO_2浓度,分别代表工业革命前、当前和IPCC预测的21世纪末的CO_2浓度.结果表明梅梁湾水体营养盐浓度在四季均高于东太湖水体营养盐浓度,但梅梁湾原位实验中浮游藻类C、N、P含量却普遍低于东太湖原位实验中浮游藻类营养元素含量,并且前者在季节上变化更大.CO_2浓度升高使梅梁湾原位实验中浮游藻类C∶P比明显增加,N∶P比略有增加,这种增加归因于藻细胞内C、N含量的升高,而东太湖浮游藻类化学计量值对CO_2浓度变化的响应不显著.因此浮游藻类元素化学计量值对CO_2浓度变化的响应程度与水体营养盐的绝对浓度无关,而与浮游藻类的生长是否受营养盐限制有关,只有当藻类生长受到水体营养盐浓度限制时,CO_2浓度升高才会显著改变其元素组成.     

微囊藻CO2-浓缩机制基因型的动态变化及其对CO2的竞争效应

由于具有高效的CO₂-浓缩机制,蓝藻在低CO₂浓度条件下具有竞争优势。然而,随着大气中CO₂浓度急剧增加,蓝藻CO₂-浓缩机制如何响应的研究较少。因此,本文以常见水华蓝藻——微囊藻为研究对象,通过对滇池微囊藻水华动态及不同CO₂-浓缩机制基因型进行监测,探讨蓝藻CO₂-浓缩机制基因的微进化特征及其动态变化。同时,设置高(0.08%)、中(0.04%)、低(0.02%)CO₂浓度(V/V)进一步揭示微囊藻不同CO₂-浓缩机制基因微进化对CO₂的竞争效应。结果表明:滇池无机碳浓度在4个采样点存在空间差异性,均呈现先降低后升高的趋势,并以HCO₃^-为主要无机碳存在形式。调查期间,东大河、观音山、洛龙河和生态所4个采样点的微囊藻均以sbtA基因型占绝对优势,相对丰度远高于bicA基因型。在不同水华时期,bicA基因型和sbtA基因型呈现相反的变化趋势,即从...     

The influence of light intensity,SO2, NOx and C3H6 on sulfate aerosol formation

The photochemical oxidation of SO₂ in the presence of NO and C₃H₆ was studied in a 18.2 liter pyrex reactor. When light intensity, irradiation time and SO₂ concentration were constant, SO₄ ^2- concentration, derived from the total volume of aerosol produced, peaked when [C₃H₆]/[NO] was approximately 6.0. Another increase im SO₄ ^2- formation was reached at very high ratios (>50). The experimental observations are consistent with the two SO₂ oxidation mechanisms. At low [C₃H₆]/[NO] ratios, the processes proceed via the HO–SO₂ reaction, while at high ratios the O₃–C₃H₆ adduct is assumed to oxidize SO₂ to produce SO₄ ^2- aerosols.     

夏季金沙江下游水-气界面CO2、CH4通量特征初探

河流是连接大陆和海洋两大碳库的桥梁,在全球碳循环中的作用举足轻重.金沙江作为长江的上游段,对区域碳循环及区域化学风化的影响非常重要.于2015年8月8-18日对金沙江下游水-气界面CO_2与CH_4通量特征进行监测与分析.采用顶空平衡法结合薄边界层模型估算法计算表层水体CO_2与CH_4的分压以及水-气界面的交换通量,并分析环境变量与其之间的相关性.研究发现,金沙江下游表层水体p(CO_2)平均值为2724.84±477.18μatm,表层水体p(CH_4)平均值为59.96±6.74μatm;水-气界面CO_2通量平均值为2.24±0.50 mmol/(m2·h),CH_4通量平均值为0.000163±0.00009 mmol/(m2·h),通量与分压趋势基本保持一致.表层水体p(CO_2)与溶解性无机碳浓度、碱度均呈显著正相关,而p(CH_4)与水温、叶绿素a浓度均呈显著正相关,CO_2通量与p(CO_2)、溶解性无机碳浓度、碱度均呈正相关,CH_4通量与p(CH_4)、风速均呈正相关,其他环境因素对通量的影响不明显,仍需进一步研究.金沙江下游水-气界面CH_4扩散通量较低,而CO_2扩散通量在世界主要河流中属于中等水平.     

Spatial variation of flow characteristics in a subarctic meandering river in ice-covered and open-channel conditions: A 2D hydrodynamic modelling approach

To be able to understand year-round river channel evolution both at present and in the future, the spatial variation of the flow characteristics and their sediment transport capabilities under ice cover need to be detected. As the measurements done through cross-sectional drill holes cover only a small portion of the river channel area, the numerical simulations give insight into the wider spatial horizontal variation of the flow characteristics. Therefore, we simulate the ice-covered flow with a hydrodynamic two-dimensional (2D) model in a meandering subarctic river (Pulmanki River, Finland) in mid-winter conditions and compare them to the pre-winter open-channel low flow situation. Based on the simulations, which are calibrated with reference measurements, we aim to detect (1) how ice-covered mid-winter flow characteristics vary spatially and (2) the erosion and sedimentation potential of the ice-covered flow compared to open-channel conditions. The 2D hydrodynamic model replicated the observed flow characteristics in both open-channel and ice-covered conditions. During both seasons, the greatest erosional forces locate in the shallow sections. The narrow, freely flowing channel area found in mid-winter cause the main differences in the spatial flow variation between seasons. Despite the causes of the horizontal recirculating flow structures being similar in both seasons, the structures formed in different locations depended on whether the river was open or ice covered. The critical thresholds for particle entrainment are exceeded more often in open-channel conditions than during ice-covered flow. The results indicate spatially extensive sediment transport in open-channel conditions, but that the spatial variability and differences in depositional and erosional locations increase in ice-covered conditions. Asymmetrical bends and straight reaches erode throughout the year, whereas symmetrical, smaller bends mainly erode in open-channel conditions and are prone to deposition in winter. The long ice-covered season can greatly affect the annual morphology of the submerged channel. © 2019 John Wiley & Sons, Ltd.     

Revisiting the morphological method in two-dimensions to quantify bed-material transport in braided rivers

Research in the 1990s showed that bed-material transport rates could be estimated at the reach scale in both one-dimension and, over small spatial scales (10s of m), in two-dimensions. The limit on the latter was the spatial scale over which it was possible to obtain distributed data on morphological change. Here, we revisit the morphological method given progress in both topographical data acquisition and hydraulic modelling. The bed-material transport needed to conserve mass is calculated in both one and two dimensions for a 1600 m × 300 m Alpine braided river “laboratory”. High-resolution topographical data were acquired by laser scanning to quantify Digital Elevation Models (DEMs), and morphological changes caused by the flushing of the water intake were derived from repeated surveys. Based on DEMs of differences, 1D bed-material transport rates were calculated using the morphological method. Then, a 2D hydraulic model was combined with a topographic correction to route sediment through the network of braided channels and to obtain a spatially variable estimate of transport in both downstream and cross-stream directions. Monte Carlo simulation was applied to the routing model parameters, allowing identification of the most probable parameter values needed to minimize negative transport. The results show that within-section spatial compensation of erosion and deposition using the 1D treatment leads to substantial local errors in transport rate estimates, to a degree related to braiding intensity. Even though the 2D application showed that a large proportion of the total transport was actually concentrated into one main channel during the studied low flow event, the proportion of transport in secondary anabranches is substantial when the river starts braiding. Investigations of the effects of DEM resolution, competent flow duration and survey frequency related to ‘travelling bedload’ and sequential erosion-deposition emphasized the critical importance of careful data collection in the application of the morphological method. © 2019 John Wiley & Sons, Ltd.     

贺兰山—银川地堑及邻区重力异常特征及构造意义

贺兰山—银川地堑及邻区地质结构复杂,对该区域深浅结构特征的研究具有重要意义.本文采用重力归一化总梯度成像和二维小波多尺度分解方法对研究区内重力异常进行了垂向和横向构造分析.重力归一化总梯度成像结果显示高低转换带的倾角、倾向与地质上的贺兰山东麓断裂、银川断裂和黄河断裂分布吻合较好,贺兰山西麓断裂与贺兰山东麓断裂汇交深度约18 km,银川断裂与黄河断裂汇交深度约25 km;二维小波多尺度分解成像结果表明正谊关断裂、贺兰山西麓断裂、芦花台断裂和银川断裂为上地壳断裂,贺兰山东麓断裂、青铜峡—固原断裂以及黄河断裂为下地壳断裂,且这三大断裂可能分别是阿拉善地块东南边界和鄂尔多斯地块西南边界;1739年平罗M 8.0古地震震中与银川断裂在重力剖面深度约15 km汇交,其垂向高低梯度为强变形带,同时古地震震中位于重力正负异常转换部位的低值区,据此可推断此次古地震的发震构造是银川断裂.这些结论可提高对贺兰山—银川地堑及邻区地质结构的认识,为该区地壳动力学过程及强震的孕震机理研究提供一定的科学依据.     

CO2 saturation estimates at Sleipner (North Sea) from seismic tomography and rock physics inversion

CO₂ saturations are estimated at Sleipner using a two-step imaging workflow. The workflow combines seismic tomography (full-waveform inversion) and rock physics inversion and is applied to a two-dimensional seismic line located near the injection point at Sleipner. We use baseline data (1994 vintage, before CO₂ injection) and monitor data that was acquired after 12 years of CO₂ injection (2008 vintage). P-wave velocity models are generated using the Full waveform inversion technology and then, we invert selected rock physics parameters using an rock physics inversion methodology. Full waveform inversion provides high-resolution P-wave velocity models both for baseline and monitor data. The physical relations between rock physics properties and acoustic wave velocities in the Utsira unconsolidated sandstone (reservoir formation) are defined using a dynamic rock physics model based on well-known Biot–Gassmann theories. For data prior to injection, rock frame properties (porosity, bulk and shear dry moduli) are estimated using rock physics inversion that allows deriving physically consistent properties with related uncertainty. We show that the uncertainty related to limited input data (only P-wave velocity) is not an issue because the mean values of parameters are correct. These rock frame properties are then used as a priori constraint in the monitor case. For monitor data, the Full waveform inversion results show nicely resolved thin layers of CO₂–brine saturated sandstones under intra-reservoir shale layers. The CO₂ saturation estimation is carried out by plugging an effective fluid phase in the rock physics model. Calculating the effective fluid bulk modulus of the brine–CO₂ mixture (using Brie equation in our study) is shown to be the key factor to link P-wave velocity to CO₂ saturation. The inversion tests are done with several values of Brie/patchiness exponent and show that the CO₂ saturation estimates are varying between 0.30 and 0.90 depending on the rock physics model and the location in the reservoir. The uncertainty in CO₂ saturation estimation is usually lower than 0.20. When the patchiness exponent is considered as unknown, the inversion is less constrained and we end up with values of exponent varying between 5 and 20 and up to 33 in specific reservoir areas. These estimations tend to show that the CO₂–brine mixing is between uniform and patchy mixing and variable throughout the reservoir.     

Analysis of Stock Market Development and CO2 Emissions on OECD Countries via an Empirical Model

Accompanying economic growth, CO₂ emissions have polluted the natural environment worldwide. This study highlights the special problems with stock market development and CO₂ emissions in 25 Organization for Economic Cooperation and Development (OECD) countries during 1971–2007 to trace the trend of CO₂ emissions while countries grow their economies. A panel‐data model is applied to analyze the relationships between stock market (SM) development, energy consumption, gross domestic product (GDP), and CO₂ emissions in 25 OECD countries. Low‐GDP countries show different results from high‐GDP countries in the trends of SM development and CO₂ emissions, and dynamic effects occur in SM development and CO₂ emissions under various GDP conditions. There is a negative relationship between SM development and CO₂ emissions if countries enjoy high economic growth, which means that these countries avoid CO₂ emissions through SM development. However, a positive relationship is found between SM development and CO₂ emissions if countries experience low economic growth, which means that SM development does not show the boycott‐effect relationship with CO₂ emissions when countries experience low levels of economic development. This study shows a correlation between SM development and CO₂ emissions among OECD countries.     

太湖生态脆弱性特征与消除对策的初步探讨

本文研究了Ｈｇ＾２＋,Ｃｄ＾２＋对痧生经济植物莼菜冬芽茎叶叶绿素含量,叶绿素ａ／ｂ值,可溶性蛋白含量,Ｏ＾－２含量以及活笥氧清除系统活性（ＳＯＤ,ＣＡＴ,ＰＯＤ）的影响,实验结果表明：叶绿素含量,叶绿素ａ／ｂ值、可溶性蛋白含量随着Ｈｇ＾２＋,Ｃｄ＾２＋处理浓度的加大呈下降趋势;