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21.
Laura Chiaramonte Mark D. Zoback Julio Friedmann Vicki Stamp 《Environmental Geology》2008,54(8):1667-1675
This paper reports a preliminary investigation of CO2 sequestration and seal integrity at Teapot Dome oil field, Wyoming, USA, with the objective of predicting the potential risk
of CO2 leakage along reservoir-bounding faults. CO2 injection into reservoirs creates anomalously high pore pressure at the top of the reservoir that could potentially hydraulically
fracture the caprock or trigger slip on reservoir-bounding faults. The Tensleep Formation, a Pennsylvanian age eolian sandstone
is evaluated as the target horizon for a pilot CO2 EOR-carbon storage experiment, in a three-way closure trap against a bounding fault, termed the S1 fault. A preliminary geomechanical
model of the Tensleep Formation has been developed to evaluate the potential for CO2 injection inducing slip on the S1 fault and thus threatening seal integrity. Uncertainties in the stress tensor and fault
geometry have been incorporated into the analysis using Monte Carlo simulation. The authors find that even the most pessimistic
risk scenario would require ∼10 MPa of excess pressure to cause the S1 fault to reactivate and provide a potential leakage
pathway. This would correspond to a CO2 column height of ∼1,500 m, whereas the structural closure of the Tensleep Formation in the pilot injection area does not exceed
100 m. It is therefore apparent that CO2 injection is not likely to compromise the S1 fault stability. Better constraint of the least principal stress is needed to
establish a more reliable estimate of the maximum reservoir pressure required to hydrofracture the caprock. 相似文献
22.
H2O-undersaturated melting experiments of synthesized basalt (SiO2 = 50.7 wt.%, MgO = 8.3 wt.%, Mg# = 60) were conducted at fO2 corresponding to NNO+1 and NNO−1 to clarify the effects of pressure (2–7 kbar) and H2O on fractional crystallization in island arcs. H2O content was ranged from nominally anhydrous to 4.4 wt.%. Differentiation trends, namely the liquid lines of descent, change
sensitively according to pressure-H2O relations. Tholeiitic differentiation trends are reproduced with H2O ≤ ∼2 wt.% in primary magma. With such quantities of H2O, fractional crystallization is controlled by olivine + plagioclase at 2 kbar. Increasing the pressure from 2 to ≥4 kbar
induces early crystallization of orthopyroxene instead of olivine and therefore SiO2 enrichment in the residual melts is suppressed. Increasing H2O (≥ ∼2 wt.% in primary magma) stabilizes clinopyroxene relative to orthopyroxene and/or magnetite. Although the phase relations
and proportions strongly depend on fO2 and H2O content, differentiation trends are always calc-alkaline. 相似文献
23.
Serena C. Tarantino Michele Zema Tiziana Boffa Ballaran Paolo Ghigna 《Physics and Chemistry of Minerals》2008,35(2):71-76
High-pressure single-crystal X-ray diffraction measurements of lattice parameters of the compound Li2VOSiO4, which crystallises with a natisite-type structure, has been carried out to a pressure of 8.54(5) GPa at room temperature.
Unit-cell volume data were fitted with a second-order Birch-Murnaghan EoS (BM-EoS), simultaneously refining V
0 and K
0 using the data weighted by the uncertainties in V. The bulk modulus is K
0 = 99(1) GPa, with K′ fixed to 4. Refinements of third order equations-of-state yielded values of K′ that did not differ significantly from 4. The compressibility of the unit-cell is strongly anisotropic with the c axis (K
0(c) = 49.7 ± 0.5 GPa) approximately four times more compressible than the a axis (K
0(a) = 195 ± 3 GPa). 相似文献
24.
对陕西省白河县月儿潭风化严重的绿松石样品进行了岩石薄片观察、化学成分测试、X射线粉晶衍射和红外吸收光谱分析等研究.结果表明,绿松石风化分解由天蓝色退色成黄绿色,最后变成白色,结构也由致密细腻变得松散多孔,主要原因是发生了硫酸根对磷酸根的交代作用,最终的交代产物主要是磷钙铝矾. 相似文献
25.
Cd2+在甘肃靖远坡缕石粘土上的吸附作用研究 总被引:2,自引:1,他引:1
以提纯后的甘肃靖远坡缕石粘土作吸附剂,常温下对水中Cd2 进行吸附实验,考察了吸附时间、吸附剂用量、振荡速率及pH值对吸附效果的影响,并对吸附动力学过程和吸附平衡进行了探讨.XRD和红外光谱分析结果显示,原矿在提纯后杂质石英被有效分离,得到了坡缕石含量较高的提纯样品.吸附实验结果显示,约60 min吸附反应可达平衡;pH值对吸附效果有显著影响,吸附率随pH值的升高而增加,当平衡溶液pH>8时吸附率超过99%;吸附过程与pseudo-second-order Lagergren动力学模型方程有较好的一致性,吸附平衡同时符合Langmuir和Freundlich等温吸附模型,由Langmuir方程得到饱和吸附量为31.65 mg/g. 相似文献
26.
目的:基于生物信息学探讨骨质疏松症与 2 型糖尿病的关系。方法:通过基因表达汇编(GEO)数据库检索骨质疏松症和2型糖尿病的相关数据集,并筛选骨质疏松症-2型糖尿病共同差异表达基因,将数据导入STRING数据库找寻关键基因,以一个单细胞测序数据集作为检验集验证关键基因细胞层面的表达水平,对筛选结果进行基因本体(GO)功能及京都基因与基因组百科全书(KEGG)通路富集分析,并对关键靶点、相关中药进行频数统计及功效分类。结果:骨质疏松症与 2 型糖尿病相关通路集中在 ErbB信号通路、丝活化蛋白激酶(MAPK)信号通路、神经营养素信号通路、NOD样受体信号通路。频数统计结果显示,与骨质疏松症-2型糖尿病关键基因相关的中药有51味,以功效分类,可分为清热解毒药、止痛药、祛风药、补虚药、止呕药。结论:骨质疏松症和2型糖尿病都是复杂的代谢性疾病,涉及众多基因表达网络和信号通路。尽管两种疾病存在复杂的基因网络背景,但是分析结果表明两种疾病之间仍存在高度重合的差异基因表达和信号通路。这表明两种疾病的分子机制密切相关,可能存在共同调控的靶点,因此这些靶点可能成为药物同时干预两种疾病的治疗靶点。 相似文献
27.
Toru?Iwata Keiko?Yoshikawa Katsutoshi?Nishimura Yoshihisa?Higuchi Takao?Yamashita Shigeru?Kato Eiji?OhtakiEmail author 《Journal of Oceanography》2004,60(6):995-1000
The measurements of the vertical transport of CO2 were carried out over the Sea of Japan using the specially designed pier of Kyoto University on September 20 to 22, 2000. CO2 fluxes were measured by the eddy correlation and aerodynamic techniques. Both techniques showed comparable CO2 fluxes during sea breeze conditions: −0.001 to −0.08 mg m−2s−1 with the mean of −0.05 mg m−2s−1. This means that the measuring site satisfies the fetch requirement for meteorological observations under sea breeze conditions. Moreover, the eddy diffusivity coefficient used in the aerodynamic technique is found to be consistent with the coefficient used in the eddy correlation technique. The present result leads us to conclude that the aerodynamic technique may be applicable to underway CO2 flux measurements over the ocean and may be used in place of the bulk technique. The important point is the need to maintain a measuring accuracy of CO2 concentration difference of the order of 0.1 ppmv on the research vessels or the buoys. 相似文献
28.
Song Jinming 《海洋学报(英文版)》2003,22(1):57-68
Carbon cycle is connected with the most important environmental issue of Global Change.As one of the major carbon reservoirs, oceans play an important part in the carbon cycle. In recent years, iron seems to give us a good news that oceanic iron fertilization could stimulate biological productivity as CO2 sink of human-produced CO2. Oceanic iron fertilization experiments have verified that adding iron into high nutrient low chlorophyll (HNLC) seawaters can increase phytoplankton production and export organic carbon, and hence increase carbon sink of anthropogenic CO2, to reduce global warming. In sixty days, the export organic carbon could reach 10 000 times for adding iron by model prediction and in situ experiment, i.e. the atmospheric CO2 uptake and inorganic carbon drawdown in upper seawaters also have the same magnitude. Therefore, oceanic iron fertilization is one of the strategies for increasing carbon sink of anthropogenic CO2. The paper is focused on the iron fertilization, especially in situ o 相似文献
29.
以1,4—苯二酚和不同的短链脂肪酸为基本原料,经溴代、加成、形成酰卤和酰化等反应,合成了六种新的溴化脂肪酸—2,3,5,6—四溴—1,4—苯二酯。通过对产物的碳、氢、溴等元素的定量分析,以及红外吸收光谱和氢核磁共振谱的研究,验证了化合物的结构。 相似文献
30.
Nowadays there are some chronic serious environmental problems, such as eutrophication, blue tide and so on, in a complicated coastal zone or a semi-enclosed bay, because the water exchanges between an inner bay and an outer sea is weak compared with the supply of contaminant. Under this situation, a method to improve the water quality by 3-dimensional small unsymmetrical structures has been proposed by Komatsu et al. In this paper, several numerical simulations of the tidal current and concentration for various arrangements of bottom roughness in a semi-enclosed model bay are carfled out with a depth-averaged 2-D numerical model. The model is solved by the hybrid finite analytic method with nonstaggered grid. And the SIMPLES algorithm with Rhie and Chow' s momentum interpolation technique is used for the simulation. The effect of Komatsu' s method for water purification is examined by numerical simulation. The result of numerical experiment indicates that it is possible to generate a new tidal residual current and to activate a tidal exchange by bottom roughness arrangement only. 相似文献