凤太矿集区东塘子铅锌矿床S、Pb同位素组成对成矿物质来源的示踪

东塘子铅锌矿床是秦岭成矿带中典型的铅锌矿床之一,前人对东塘子铅锌矿床成矿作用研究较多,但受限于测试手段及认识的局限性,多年来对其物质来源的认识仍未统一。本文在充分研究东塘子铅锌矿床地质特征的基础上,开展了相关样品的S、Pb同位素分析,分析对象包括了不同类型的铅锌矿石,讨论了该铅锌矿床的成矿物质来源、区内岩浆岩与铅锌成矿的关系等。研究表明:东塘子铅锌矿床矿石硫化物δ34S值变化范围为1.8‰～12.5‰,平均7.50‰,计算获得成矿流体中总硫δ34S∑S为7.7‰,显示海水硫酸盐(蒸发膏岩)与岩浆硫的混合来源特征。矿石铅同位素组成稳定,铅源主要来自富U-Th-Pb的上地壳与深部,可能与深部岩浆活动有关。研究结果表明,东塘子铅锌矿床的成矿过程与南秦岭印支期大规模多阶段构造-岩浆-流体活动密切相关,为下一阶段区内找矿工作提供了新的思路。     

微生物勘探技术在潮汕坳陷油气勘探中的应用初探

东沙海域潮汕坳陷中生界研究程度相对较低,油气分布规律不明,为了加强对该区油气分布和富集规律的研究,针对潮汕坳陷西部地质目标首次应用微生物地球化学勘探技术(MGCE),探讨其含油气性。MGCE技术以轻烃微渗漏理论为基础,采用地质微生物学方法和地球化学方法检测研究区海底表层的微生物异常和吸附烃异常,预测研究区下伏地层中油气的富集区及其油气性质。检测结果显示研究区西部凹陷的斜坡区微生物异常呈块状发育,轻烃微渗漏强度变化大,可能为潜在油气富集区,酸解吸附烃成果显示可能的油气性质为干气和凝析油气。     

福建政和县东际金（银）矿床黄铁矿微量元素和硫-铅同位素及锆石年龄研究

东际金(银)矿床赋存于燕山晚期南园组火山岩中,是东南沿海地区一个隐爆角砾岩型贵金属矿床,已探明金资源量达12.5 t,银资源量135.9 t。通过开展主要金属硫化物黄铁矿电子探针和硫-铅同位素分析,讨论了成矿作用和成矿物质来源等问题。研究表明,东际金(银)矿床黄铁矿Co/Ni值3～94(平均值23)且Co含量为500×10-6～1070×10-6(均值799×10-6),Fe/(S+As)值0.827～0.871(均值0.860),Au/Ag值0.9～5.5(均值2.6),反映该矿床是与陆相火山作用有关的浅成中低温热液型矿床。黄铁矿δ34S在-6.6‰～-0.7‰,206Pb/204Pb为17.9801～18.4303,207Pb/204Pb为15.2689～15.9397,208Pb/204Pb为37.9052～38.7871,指示成矿物质主要来源于具有壳幔混源性质的花岗质岩浆,此外含矿热液也活化萃取了部分基底变质岩和火山岩围岩的金属元素。通过锆石U-Pb年代学研究和区域成矿资料对比,东际金(银)矿床成矿时代可被限定于早白垩世晚期。     

松辽盆地长岭凹陷乾安地区青山口组一段沉积相特征与古环境恢复——以吉页油1井为例

松辽盆地上白垩统青山口组一段富有机质泥页岩岩发育,层系内部滞留烃富集,具有可观的页岩油资源潜力。沉积古环境控制了泥页岩的分布、有机质发育特征及滞留烃富集程度。因此,恢复青一段泥页岩沉积古环境,明确沉积特征,对揭示青一段泥页岩中页岩油富集规律具有重要意义。本文基于长岭凹陷乾安地区青一段取心井——吉页油1井的岩心观察及测井曲线组合特征,划分了青一段泥页岩沉积微相,应用自然伽马能谱测井、岩性扫描测井数据,选取环境评价参数,对青一段沉积古环境及其演化过程进行了恢复,分析了古环境参数与泥页岩中滞留烃含量的相关性。结果表明:松辽盆地长岭凹陷乾安地区青一段泥页岩是在三角洲外前缘-浅湖-半深湖-深湖沉积体系中形成的,主要发育半深湖-深湖泥、浅湖泥沉积微相。青一段泥页岩沉积古环境经历了水深由浅变深,气候由半潮湿到潮湿,水体由淡水-微咸水,还原性由弱到强,水动力条件由中等到弱的演化,在青一段地层中存在明显的沉积环境变化界面,上下层段沉积环境不同。青一段泥页岩中滞留烃含量主要受沉积古气候、古氧化还原条件控制,潮湿气候还原条件下形成的泥页岩有机质类型好,以腐泥质为主,生油能力强,滞留烃含量高。     

内蒙古呼伦西白地区铌稀土多金属矿成矿特征及找矿标志

北山成矿带东缘的内蒙古呼伦西白地区近年来发现了多处铌稀土矿床(点),矿床(点)产于二叠纪二长花岗岩外接触带上,矿体赋存于滨浅海相碳酸盐岩-变碎屑岩内,其形态、产状、规模受构造-岩浆活动控制,并与磁异常对应,其中灰石山东北铌稀土矿区Nb2O5品位0.02%～0.56%、平均0.11%,REO品位0.13%～2.63%,平均0.93%,辉森乌拉西铌金矿区Nb2O5品位0.01%～0.1%,与白云鄂博Nb-REE-Fe超大型矿床特征类似,成矿潜力巨大。结合区域地质背景及铌稀土多金属矿成矿特征,初步认为区内该类型矿床的找矿标志为:二叠系滨浅海相碳酸盐岩-变碎屑岩地层、构造挤压形成的虚脱空间或韧-脆性转换部位、二叠纪二长花岗岩外接触带、放射性异常梯度带-磁异常位置、岩石蚀变(褐铁矿化、硅化、碳酸盐化等)和石英细网脉发育地段。对该地区铌稀土多金属矿成矿特征和找矿标志的研究有利于拓展北山地区三稀矿产的找矿思路,也可为此类矿产的找矿方向提供借鉴。     

Coupling relationship between reservoir diagenesis and hydrocarbon accumulation in Lower Cretaceous Yingcheng Formation of Dongling,Changling fault depression,Songliao Basin,Northeast China

The Lower Cretaceous Yingcheng Formation in the southern Songliao Basin is the typical tight oil sandstone in China. In order to better predict the petrophysical properties of the tight sandstone reservoirs in the Lower Cretaceous Yingcheng Formation, Songliao Basin, Northeast China, the diagenesis and porosity evolution was investigated using a suite of petrographic and geochemical techniques including thin section analysis, scanning electron microscopy, mercury intrusion and fluid inclusion analysis, on a set of selected tight sandstone samples. Combined with the histories of burial evolution, organic matter thermal evolution and hydrocarbon charge, the matching relationship between reservoir porosity evolution and hydrocarbon accumulation history is analyzed. The result showed that the tight sandstone reservoirs characterized of being controlled by deposition, predominated by compaction, improved by dissolution and enhanced by cementation. The hydrocarbon accumulation period was investigated using a suite of hydrocarbon generation and expulsion history, microfluorescence determination and temperature measurement technology. According to the homogenization temperature of the inclusions and the history of burial evolution, Yingcheng Formation has mainly two phases hydrocarbon accumulation. The first phase of oil and gas is charged before the reservoir is tightened, the oil and gas generated by Shahezi source rocks enter the sand body of Yingcheng Formation, influenced by the carrying capability of sand conducting layer, oil and gas is mainly conducted by the better properties and higher connectivity sand body and enriched in the east, which belongs to the type of densification after hydrocarbon accumulation. The second phase of oil and gas charge after densification, which belongs to the type of densification before the hydrocarbon accumulation.     

LA-ICP-MS in situ analyses of the pyrites in Dongyang gold deposit,Southeast China: Implications to the gold mineralization

The Dongyang gold deposit is a newly discovered epithermal deposit in Fujian Province, Southeast China, along the Circum-Pacific metallogenic belt. Herewith, the authors present mineralogical, scanning electron microscope, and laser ablation inductively coupled clasma mass spectrometry analysis to reveal the relations between Au and Te, As, S, Fe, etc., and discuss the gold precipitation process. The pyrites in this deposit are Fe-deficient, and are enriched in Te and As. The authors infer that As was mainly in form of As-complexes, and Te-Au-Ag inclusions/solid solution also exsits in the Py I. Along with the depletion of Te and As, they were less active chemically in the Py II, and Au may be incorporated into As-rich and Fe-deficient surface sites by chemisorption onto As-rich growth surfaces. Because of the incorporation of new fluid, Te and As became the most active chemically in the Py III, which was the main elements precipitation stage, and As dominantly substituted for S in the lattice of pyrite, due to the more reducing condition. The authors propose Au was in form of invisible gold, and the incorporation of gold can be considered as post-pyrite event, while the Au-bearing minerals were result of post incorporation of gold in arsenian pyrite.     

Evaluation of clayed silt properties on the behavior of hydrate production in South China Sea

Gas hydrate is one kind of potential energy resources that is buried under deep seafloor or frozen areas. The first trial offshore production from the silty reservoir was conducted in the South China Sea by the China Geological Survey (CGS). During this test, there were many unique characteristics different from the sand reservoir, which was believed to be related to the clayed silt physical properties. In this paper, simulation experiments, facilities analysis, and theoretical calculation were used to confirm the hydrate structure, reservoir thermo-physical property, and bond water movement rule. And the behavior of how they affected production efficiency was analyzed. The results showed that: It was reasonable to use the structure I rather than structure II methane hydrate phase equilibrium data to make the production plan; the dissociation heat absorbed by hydrate was large enough to cause hydrate self-protection or reformation depend on the reservoir thermal transfer and gas supply; clayed silt got better thermal conductivity compared to coarse grain, but poor thermal convection especially with hydrate; clayed silt sediment was easy to bond water, but the irreducible water can be exchanged to free water under high production pressure, and the most obvious pressure range of water increment was 1.9–4.9 MPa.     

Sequence stratigraphic framework and sedimentary model of Shanxi Formation in northeast Zhoukou Depression of the North China Plate

The sequence stratigraphic framework of Shanxi Formation in the northeast Zhoukou Depression was established based on detailed sequence stratigraphical and sedimentological analysis by utilizing the logging and core data of six wells drilled in the eastern tectonic unit of Zhoukou Depression. It was divided into three third-order sequences, namely SQs1, SQs2, and SQs3 from bottom to top. Each sequence can be divided into a transgressive system tract (TST) and a highstand system tract (HST). Furthermore, four sequence boundaries and three maximum flooding surfaces were identified, and they are the bottom interface SBs and maximum flooding surface mfss1 of SQs1, the bottom interface SBs1 and maximum flooding surface mfss2 of SQs2, the bottom interface SBs3 and maximum flooding surface mfss3 of SQs3, and the top interface SBx from bottom to top. Carbonate tidal flat –clastic tidal flat sedimentary system developed in Shanxi Formation in the northeast Zhoukou Depression (also referred to as the study area) under the control of regression. Meanwhile, four sedimentary microfacies were identified in the sedimentary system, which are lime-mud flats, sand flats, mixed flats, and mud flats. The transgression in the study area occurred from the southeast to the northwest. Therefore, the northwestern part is the seaward side, and the southeastern part is the landward side. As revealed by relevant drilling data, SQs1 of the Shanxi Formation is characterized by the development of limestone and carbonaceous mudstone, with limestone, dark mudstone, and carbonaceous mudstone mainly developing. Meanwhile, lime-mud flats were mainly deposited in it. During the periods of SQs2 and SQs3, the sedimentary environment of the study area changed from the carbonate tidal flats to clastic tidal flats as the coastline migrated towards the sea. In these periods, sand flats mainly developed near the maximum flooding surfaces and were relatively continuous in the eastern and southern parts of the transgressive system tract; mixed flats were relatively continuous in the western and northern parts of the transgressive system tract as well as the eastern and southern parts of the highstand system tract; mud flats widely developed in the highstand system tract. Peat flats mainly developed in the period of HSTs2, with coal seams relatively developing in the southeastern part of the study area as revealed by drilling data. The peat flats in SQs2 are favorable hydrocarbon source layers, the lime-mud flats in SQs1 and sand flats formed in the transgression periods of SQs2 and SQs3 constitute favorable hydrocarbon reservoirs, and the mud flats form in the transgressions periods serve as favorable cap rocks. Therefore, the study area features a reservoir-cap assemblage for self-generating and self-storing of hydrocarbon, and the southeastern part of the study area can be taken as a favorable exploration area.     

Mesozoic–Cenozoic stress field magnitude in Sichuan Basin,China and its adjacent areas and the implication on shale gas reservoir: Determination by acoustic emission in rocks

The Sichuan Basin is one of the vital basins in China, boasting abundant hydrocarbon reservoirs. To clarify the intensity of the tectonic stress field of different tectonic episodes since the Mesozoic and to identify the regional dynamic background of different tectonic movements in the Sichuan Basin and its adjacent areas, the characteristics of the acoustic emission in rocks in different strata of these areas were researched in this paper. Meanwhile, the tectonic stress magnitude in these areas since the Mesozoic was restored. The laws state that the tectonic stress varied with depth was revealed, followed by the discussion of the influence of structural stress intensity on structural patterns in different tectonic episodes. These were conducted based on the paleostress measurement by acoustic emission method and the inversion principle of the stress fields in ancient periods and the present, as well as previous research achievements. The results of this paper demonstrate that the third episode of Yanshanian Movement (Yanshanian III) had the maximum activity intensity and tremendously influenced the structural pattern in the study area. The maximum horizontal principal stress of Yanshanian III varied with depth as follows: 0.0168 x + 37.001 (MPa), R² = 0.8891. The regional structural fractures were mainly formed in Yanshanian III in Xujiahe Formation, west Sichuan Basin, of which the maximum paleoprincipal stress ranging from 85.1 MPa to 120.1 MPa. In addition, the law stating the present maximum horizontal principal stress varies with depth was determined to be 0.0159 x+10.221 (MPa), R²=0.7868 in Wuling Mountain area. Meanwhile, it was determined to be 0.0221 x+9.4733 (MPa), R²=0.9121 in the western part of Xuefeng Mountain area and 0.0174 x+10.247 (MPa), R²=0.8064 in the whole study area. These research results will not only provide data for the simulation of stress field, the evaluation of deformation degree, and the prediction of structural fractures, but also offer absolute geological scientific bases for the elevation of favorable shale gas preservation.