Li／TiS2电池中Lix（pc）yTiS2插入化合物的形成

常温二次Li/TiS_2电池放电时,阴极TiS_2可以形成一系列插入化合物,本实验研究结果发现,在不同条件下,既可以形成文献报导的Li_xTiS_2(d=6.11～6.14(?)),也会形成Li_x(pc)_yTiS_2(d=19.6;14.5(?))三元共插入化合物,TiS_2层距在这样大地膨胀下(大于原层间距1～2倍),脱插后,仍可恢复原来的结构而无严重破坏。     

等氯化锂含量下体系LiCl—NaCl—KCl—MgCl2—H2O的相关系

氯化锂含量对光卤石形成基本体系NaCl—KCl—MgCl_2—H_2O中的结晶区有显著影响,主要显现在涉及KCl的结晶区都变小,NaCl的结晶区变大,这支持我们关于LiCl对NaCl有显著盐析作用的结论。     

大柴旦盐湖硼,锂分布规律（续）

大柴旦盐湖硼、锂分布规律（续）李家棪（中国科学院青海盐湖研究所，西宁８１０００８）ＤｉｓｔｒｉｂｕｔｉｖｅＲｅｇｕｌａｒｉｔｙｏｆＢｏｒｏｎａｎｄＬｉｔｈｉｕｍｉｎＤａＱａｉｄａｍＳａｌｔＬａｋｅ￥ＬｉＪｉａｙａｎ（Ｑｉｎｇｈａｉｉｎｓｔｉｔｕｔｅｏ...     

卤水锂资源提取技术中国专利分析

对中国卤水提锂资源开发现状进行专利信息的数据挖掘和分析。借助专利申请趋势、区域分布、申请人分布、IPC分布、专利技术比较分析等展现卤水锂资源开发的技术概况、研发热点与态势。研究可为企业的后续研发提供数据支持。     

N523-TBP混合萃取体系从盐湖卤水中萃取锂的机理研究

研究了N523(N,N-二乙基己基乙酰胺)-TBP(磷酸三丁酯)混合萃取体系从盐湖卤水中萃取锂的共萃取效应、盐析效应及共存离子影响。FeCl_3、CoCl_2、NiCl_2、CuCl_2、ZnCl_2等过渡金属氯化物盐对锂的共萃取效应研究表明,FeCl_3是最佳的共萃剂,Fe/Li摩尔比为1.3时萃取效果最优。卤水中KCl、CaCl_2、NaCl、MgCl_2、Al Cl3的盐析效应研究表明,MgCl_2是萃取锂天然的最佳盐析剂。卤水中Na~+、K~+、Ca~(2+)等共存离子对锂萃取效果的影响研究表明,锂与共存离子的分离因数顺序为βLiMgβLiKβLiNaβLiCa。N523-TBP混合萃取体系特别适合从高镁卤水中萃取锂,但不适于从含钙较高的卤水中萃取锂。     

Geological characteristics,metallogenic regularity,and research progress of lithium deposits in China

China is rich in abundant lithium resources characterized by considerable reserves and a concentrated distribution of metallogenic zones or belts, with proven reserves of 4046.8×10³ t (calculated based on Li₂O) by 2021. China is also a big consumer of lithium. By 2019, China ’s lithium consumption in the battery sector alone had reached 99×10³ t, with an average annual growth rate of nearly 26%. China has become the world ’s largest importer of lithium resources, showing a severely unbalanced relationship between supply and demand for lithium resources. Therefore, there is an urgent need for the prospecting, exploitation, and study of lithium resources in China. This study collected, organized, and summarized the data on the major lithium deposits in China, analyzed and compared the spatial-temporal distribution patterns, geological characteristics, and metallogenic regularity of these lithium deposits, and summarized the prospecting and research achievements over the last decade. The major lithium deposits in China are distributed in provinces and regions such as Qinghai, Jiangxi, Sichuan, Tibet, and Xinjiang. These deposits are mostly small in scale. According to different genetic types, this study divided lithium deposits into granitic pegmatite type, granite type, saline lake brine type, underground brine type, and sedimentary type, as well as new types including hot spring type and magmatic-hydrothermal type, and summarized the characteristics and key metallogenic factors of these different types of deposits. Sixteen metallogenic prospect areas of lithium deposits were delineated according to the deposit types and the distribution patterns of metallogenic belts. The paper introduced the research progress in major metallogenic models and lithium extraction techniques made over the past decade. Based on the comprehensive analysis of the prospecting potential of lithium deposits, the authors concluded that the future prospecting of lithium resources in China should focus on lithium metallogenic belts, the deep and peripheral areas of currently determined large-scale pegmatite-type lithium deposits, geophysical-geochemical anomalous areas with mineralization clues, and areas with developed large-scale low-grade associated granite-type and sedimentary lithium resources. The study aims to serve as a guide for the future prospecting of lithium deposits in China.©2022 China Geology Editorial Office.     

锂矿主要类型、特征、时空分布及找矿潜力分析

锂是重要的能源金属,分布高度集中。目前可开发利用的锂矿床主要有盐湖卤水型、伟晶岩型、黏土型、锂沸石型、其他卤水型（包括油气田卤水亚类和地热卤水亚类）和离子吸附型6种类型。除伟晶岩型锂矿的时代呈幕式分布,其他类型的锂矿主要集中形成于新生代。新生代锂矿占全球已查明资源量的75%,主要分布于显生宙造山带如安第斯锂三角地区、中国川藏地区、北美科迪勒拉等地区,其余锂矿则主要分布在前寒武纪克拉通如西澳克拉通、刚果克拉通、西非克拉通和加拿大地盾等区域。盐湖卤水型和伟晶岩型锂矿找矿潜力大,是目前勘探开发的主要类型。     

Lithium isotopes in foraminifera shells as a novel proxy for the ocean dissolved inorganic carbon (DIC)

Past ocean pH and pCO₂ are critical parameters for establishing relationships between Earth's climate and the carbon cycle. Previous pCO₂ estimates are associated with large uncertainties and are debated. In this study, laboratory cultures of the foraminiferan genus Amphistegina were performed in order to examine the possible factors that control the Li isotope composition (δ⁷Li) of their shells. δ⁷Li is insensitive to temperature and pH variations but correlates positively with the Dissolved Inorganic Carbon (DIC) of seawater. Li/Ca ratio in the shells shows negative correlation with δ⁷Li, consistent with published data for planktonic foraminifera from core tops and from short periods during the Cenozoic. We propose that the sensitivity of δ⁷Li and Li/Ca ratio to DIC is a biological phenomenon and is related to biomineralization mechanisms in foraminifera. We used the published foraminiferal δ⁷Li records, and our experimental results, to determine the paleo-ocean DIC and pH for the last glacial–interglacial cycle. The results are consistent with published estimates of pH and pCO₂ based on boron isotopes and ice cores. We suggest Li and its isotopes may serve as a new complementary proxy for the paleo-ocean carbonate chemistry.     

锂离子二次电池及其电解质的研究

介绍了锂离子二次电池的发展以及与其它二次电池性能的比较,并对影响锂离子二次电池性能的几个问题作了阐述。着重论述了锂离子二次电池的电解质及其导电性能,以及制备六氟磷酸锂的方法。     

盐湖及相关资源开发利用进展

对近年来国内外盐湖资源开发利用的进展情况加以介绍 ,也涉及到国外钾、锂、镁、硼、碘等相关产品的生产、消费、价格等情况。还对资源开发的可持续发展以及我国盐湖及相关资源开发的某些问题加以讨论。