寄主岩浆硫化物和氧化物矿床的镁铁质-超镁铁质岩体对比分析与成矿过程评述

镁铁质-超镁铁质岩体是世界上岩浆硫化物(Ni-Cu-PGE)和氧化物(Fe-Ti-V-P)矿床的主要载体.全球主要岩浆硫化物和氧化物矿床均可以产于大火成岩省、克拉通区的裂谷带或伸展环境、褶皱带内的后碰撞伸展环境.寄主岩浆硫化物矿床的岩体规模相差甚大(从6×104km2到＜0.1km2),既有超镁铁质岩石组合也有镁铁质岩石组合,但其原生岩浆主要为拉斑玄武质岩浆.含镍铜的铂族元素矿床主要赋存于规模很大的层状岩体中,而镍铜硫化物矿床主要赋存于小岩体中.寄主钒钛磁铁矿或磁铁矿矿床的岩体主要是以辉长岩为主的层状杂岩体.寄主钛铁矿-磷灰石矿床的岩体均为层状的斜长岩-纹长二长岩-紫苏花岗岩岩体.尽管其岩石组合相差很大,但其原生岩浆均属拉斑玄武质.寄主硫化物矿床的岩体相对富Si、Mg、Cr、Ni,而寄主氧化物矿床的岩体相对富Fe-Ti-P-V,造岩矿物晶体化学也反映了这种差异.对全球主要含矿岩体的对比分析表明,导致这种反差的主要控制因素应该是岩浆生成时的压力状态,源区性质和熔融程度的差异可能只在局部范围内起作用.对岩浆硫化物矿床成矿过程的认识集中体现在金川模式和岩浆通道模式上,对岩浆氧化物矿床成矿过程的认识体现在氧化物和磷灰石是堆晶相还是从不混溶的矿浆中结晶的.对比分析表明,成矿过程具有多样性,试图用一种模式概括所有同类矿床成矿过程的想法未必可取.毫无疑问,适宜的氧化还原环境是形成岩浆矿床的必要务件,伴随岩浆演化及成矿过程的氧速度变化及其诱因问题尚待进一步探索.     

铂族元素作为地球化学指示剂有关问题讨论

铂族元素在研究地球化学过程中发挥着越来越重要的示踪作用。根据铂族元素在不同圈层中的分布,可以探索地球的形成历史和地外撞击事件。根据铂族元素之间的分异性,可用来研究岩浆的部分熔融程度、岩石的形成过程以及大地构造环境的判别等。然而,多年来,由于分析手段和分析方法等的限制,对铂族元素在地质作用过程中的化学行为的认识尚欠深入,对其作为地球化学指示剂的研究还存在诸多问题,许多现象尚不能得到很好的解释。本文提出,应加强地质样品中超痕量铂族元素的高精度分析方法研究和铂族元素在地质作用过程中分异行为、分异规律的研究。     

南天山花岗岩类的年代学,岩石学,地球化学及其构造环境

在南天山褶皱带,分布有大量的花岗岩类岩石。按照由老到新的侵位顺序,岩石类型依次为：闪长岩、似斑状花岗岩、二云母花岗岩和碱长花岗岩。精确的锆石Ｕ－Ｐｂ法研究证明,它们形成于石炭纪末期至早二叠世末期。闪长岩、似斑状花岗岩的岩相学和岩石化学具有Ｉ型花岗岩的特征,而二云母花岗岩充分表现了Ｓ型花岗岩的岩相学和岩石化学特征。与洋中脊花岗岩相比,它们不同程度地富集Ｋ２Ｏ、Ｒｂ、Ｔｈ而贫于Ｔａ、Ｎｂ、Ｚｒ,显示了碰撞造山阶段花岗岩的地球化学特征。碱长花岗岩主要由钾长石、钠长石、石英和富羟铁云母组分的黑云母组成。它们普遍具有高的ＳｉＯ２、Ｎａ２Ｏ＋Ｋ２Ｏ、Ｎｂ、Ｙ、ＲＥＥ（Ｅｕ除外）丰度和Ｆｅ／Ｍｇ比值,以及低的ＣａＯ、ＴｉＯ２、Ｓｒ、Ｂａ、Ｅｕ丰度。从而,系统地显示了Ａ２型花岗岩的普遍特征。证明它们形成于后造山垮塌阶段。各种岩石的εＳｒ（ｔ）界于＋３７．７５和＋２１００．７之间,而εＮｄ（ｔ）界于－４．４２和－６．５１之间,证明它们全部源自于陆壳物质的深熔作用。北天山古洋盆于晚石炭世的闭合导致了南天山碰撞造山作用。而在早二叠世末期,更大范围的大陆伸展作用与南天山的后造山垮塌作用同步。     

南秦岭勉略带两河弧内裂陷内火山岩组合地球化学

两河火山岩岩片位于秦岭微板块与扬子板块的分界断裂－巴山弧形构造混杂带内。岩石内亚碱性拉班系列玄武质岩石和钙碱性英安岩、流纹岩组成。基性岩和酸性岩均具有高Ｂａ,低Ｔｈ、Ｕ,显著的Ｎｂ、Ｔａ亏损和Ｔｉ的负异常等地球化学特征,玄武岩的Ｔｈ／Ｙｂ－Ｔａ和Ｔｉ／Ｚｒ－Ｔｉ／Ｙ不活动痕量元素组合特征指示这套火山岩可能产于弧间盆地环境。是勉略洋盆在古生代晚期－中生代早期发育期间洋壳俯冲及弧内裂陷的岩浆作用产物。     

Evaluation of elemental enrichments in surface sediments off southwestern Taiwan

Surface slices of 20 sediment cores, off southwestern Taiwan, and bed sediment of River Kaoping were measured for major and trace elements (Al, As, Ca, Cd, Cl, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, P, Pb, S, Si, Ti, V, and Zn) to evaluate the geochemical processes responsible for their distribution, including elemental contamination. Major element/Al ratio and mean grain size indicate quartz-dominated, coarse grained sediments that likely derived from sedimentary rocks of Taiwan and upper crust of Yangtze Craton. Bi-plot of SiO₂ versus Fe₂O₃^T suggests the possible iron enrichment in sediments of slag dumping sites. Highest concentrations of Cr, Mn, P, S, and Zn found in sediments of dumping sites support this. Correlation analysis shows dual associations, detrital and organic carbon, for Cr, P, S, and V with the latter association typical for sediments in dumping sites. Normalization of trace elements to Al indicates high enrichment factors (>2) for As, Cd, Pb, and Zn, revealing contamination. Factor analysis extracted four geochemical associations with the principal factor accounted for 25.1% of the total variance and identifies the combined effects of dumped iron and steel slag-induced C–S–Fe relationship owing to authigenic precipitation of Fe–Mn oxyhydroxides and/or metal sulfides, and organic matter complexation of Fe, Mn, Ca, Cr, P, and V. Factors 2, 3, and 4 reveal detrital association (Ti, Al, Ni, Pb, Cu, and V), effect of sea salt (Cl, Mg, Na, and K) and anthropogenic component (As and Zn)-carbonate link, respectively, in the investigated sediments.     

甘肃红石山蛇绿岩地球化学特征及构造环境

红石山蛇绿岩产出于塔里木板块北缘红石山深大断裂带中,主要由变质橄榄岩、辉长岩和玄武岩组成。玄武岩的主要地球化学特征与MORB相似,微量元素特征表明它属N-MORB。结合区域地质特征,认为红石山蛇绿岩早期为初始洋盆环境,晚期有洋脊扩张中心环境的玄武岩形成。早石炭世早期是洋盆发育的全盛期,早石炭世晚期洋壳发生消减,于二叠纪晚期构造侵位,伴有绿片岩相变质作用。     

阿尔泰南缘克朗盆地铁木尔特花岗岩体年龄、地球化学特征及成因

铁木尔特黑云母花岗岩出露于阿尔泰造山带南缘克朗盆地北西侧,岩体主要为黑云母花岗岩。锆石的SHRIMPU-Pb定年结果表明该岩体结晶年龄为459±4.9Ma。岩石具有高的SiO_2(71.92%～76.58%)和Al_2O_3(12.92%～14.55%)含量,富碱(K_2O+Na_2O=7.09%～8.11%)、高钾(K_2O/Na_2O=1.1～1.62)、低P_2O_5(0.14%)和MgO+FeO(5%)含量,强过铝质(ACNK=1.13～1.34);富集LREE和Th、U、Pb,贫Ba、P、Sr、Ti、Nb,呈现明显的Eu负异常(δEu=0.33～0.53);并具有低的Al_2O_3/TiO_2(100)比值和高的CaO/Na_2O(0.3)比值。以上特征表明该岩体属高钾钙碱性高温型强过铝花岗岩。同时岩石具有低的Sr初始值(~(87)Sr/~(86)Sr=0.701727～0.709951)和相对高的ε_(Nd)(459Ma)(-1.43～-0.98)值,两阶段Nd模式年龄较为均一(t_(2DM)=1.2～1.3Ga)。岩体的原始岩浆可能是富含白云母和黑云母的变泥质岩在大于875℃的条件下脱水熔融的产物,在部分熔融过程中有磷灰石、斜长石、钛铁矿等矿物的残留,并混入少量的幔源物质。结合阿尔泰南缘的区域地质背景综合分析,推测岩体形成于俯冲作用的初期,可能是在挤压背景下由于局部伸展减压以及异常地幔和深部热流不均匀上升提供的热影响发生的部分熔融产生。     

土壤化探元素预测天然气的探索

通过德阳新场气田化探成果与气田上有机物异常，物探异常和钻孔实际见气的对比，结合成都地区，宜宾地区综合研究，认为As,Ab,Hg,Ba,Mn五元素及Cu,Pb,Zn,Mo,Cd,Ni,V,P等是预测天然气的指示元素，用该指标对新场气和成都地区实际勘察结果映证预测指示元素是正确的，从而探索出一条利用化探元素异常寻找天然气的新路。     

赣南晚侏罗世九龙脑钨锡铅锌矿集区不同成矿类型花岗岩年龄、地球化学特征对比及其地质意义

九龙脑花岗岩体位于南岭东部,它周围分布着众多钨、锡和铅锌矿床(点).本文选择岩体北侧淘锡坑石英脉型钨矿、东侧宝山矽卡岩型铅锌矿底部的隐伏花岗岩,对比九龙脑岩体开展了成岩年代学、地球化学、Sr- Nd同位素研究.上述岩体的SHRIMP锆石U-Pb年龄分别是158.7±3.9Ma、157.7±2.7Ma、154.9±2.2...     

Evolution of the Neoproterozoic Delgo suture zone and crustal growth in Northern Sudan: geochemical and radiogenic isotope constraints

In the Delgo basement area of northern Sudan, low to medium grade metamorphosed volcanic, sedimentary and plutonic rocks are surrounded by high grade gneisses. A NNE-SSW trending suture zone can be defined by the lithological, chemical and structural characteristics of several distinct units. The early Proterozoic gneiss terrain is overlain by metasedimentary units, the metamorphism of which has been dated by the Sm-Nd whole rock-mineral technique (702 ± 27 Ma in the west, 592 ± 16 Ma in the east). In the central part, the Abu Sari volcanic rocks show geochemical signatures of formation at an arc, with a protracted tholeiitic, calc-alkaline and shoshonitic evolution. The overlying El Hamri ophiolite contains chemical features of a back-arc tectonic environments. The ophiolite was dated by the Sm-Nd whole rock method on metagabbros at 752 ± 48 Ma. The further extension of this oceanic basin into the Jebel Rahib in the south-west was dated at 707 ± 54 Ma (Sm-Nd whole rock and minerals).Widespread suite of syn-tectonic granitoid intrusives displays subduction-related characteristics. They where emplaced between 650 to 760 Ma (Pb-zircon evaporation method). Their Nd and Sr isotopic compositions indicate a changing pattern of island arc to active continental margin character along an east-west transect and suggest a west to north-west dipping subduction zone. All units were juxtaposed at the minimum age of 600 Ma and rearranged during an extensional event, which was dated by the Rb-Sr thin slab technique (546 ± 19 Ma) on a migmatite. The Delgo suture provides evidence of a complex terrane pattern in north-east Africa and crustal growth during the Pan-African event by the addition of oceanic material to pre-existing continental crust.