Direct observation of complex Tóthian groundwater flow systems in the laboratory

Based on the theory of gravity‐driven groundwater flow systems, we have developed a complex Flow System Sand‐Box Model (FSM). It enables the visual observations of the development and characteristics and temporal evolution of complex Tóthian flow systems in the laboratory. The configuration of the regional, intermediate and local flow systems can be controlled and observed; hydraulic head, flow direction and travel time can be measured; and the scale and shape of the sub‐flow systems as well as the path lines and flow lines can be observed directly. The experiments demonstrate the Tóthian flow systems in a small basin with multiple sources and sinks. Greater local topographic (water table) undulation will lead to larger local flow systems. Greater regional and less local topographic undulation will enhance the development of intermediate and regional flow systems. In homogeneous media, increasing fluid‐potential differences between source and sink increase the spatial scale of the generated flow systems. The FSM is a useful teaching aid and experimental device to study and develop an intuitive insight into gravity‐driven groundwater flow systems. It helps to visualize and understand the hydraulic properties and controlling factors of Tóthian flow systems and may be used to study problems related to the chemical and temperature characteristics of the flow systems as well. Copyright © 2010 John Wiley & Sons, Ltd.     

Genetic and ore-forming ages of the Fe–P–(Ti) oxide deposits associated with mafic–ultramafic–carbonatite complexes in the Kuluketage block,NW China

Abstract

During the past 50 years, many geological and ore-deposit investigations have led to the discovery of the Fe–P–(Ti)-oxide deposits associated with mafic–ultramafic–carbonatite complexes in the Kuluketage block, northeastern Tarim Craton. In this paper, we discuss the genetic and ore-forming ages, tectonic setting, and the genesis of these deposits (Kawuliuke, Qieganbulake and Duosike). LA-ICP-MS zircon U–Pb dating yielded a weighted mean ²⁰⁶Pb/²³⁸U ages of 811?±?5?Ma, 811?±?4?Ma, and 840?±?5?Ma for Kawuliuke ore-bearing pyroxenite, Qieganbulake gabbro and Duosike ore-bearing pyroxenite, respectively. The CL images of the Kawuliuke apatite grains show core–rim structure, suggesting multi-phase crystallisation, whereas the apatite grains from Qieganbulake and Dusike deposits do not show any core–rim texture, suggesting a single-stage crystallisation. LA-ICP-MS apatite ²⁰⁷Pb-corrected U–Pb dating provided weighted mean ²⁰⁶Pb/²³⁸U ages of 814?±?21?Ma and 771?±?8?Ma for the Kawuliuke ores, and 810?±?7?Ma and 841?±?7?Ma for Qieganbulake and Duosike ores, respectively. The core–rim texture in apatite by CL imaging as well as two different ore-forming ages in the core and rim of the apatite indicate two metallogenic events for the Kawuliuke deposit. The first metallogenic period was magmatic in origin, and the second period was hydrothermal in origin. The initial ore-forming age of the Kawuliuke Fe–P–Ti mineralisation was ca 814?Ma and the second one was ca 771?Ma. On the other hand, the ore-forming ages of the Qieganbulake and Duosike deposits were ca 810?Ma and ca 841?Ma, respectively. Qieganbulake and Duosike deposits were of magmatic origin. Combined with previous geochronological data and the research on the tectonic background, we infer that the Kawuliuke, Qieganbulake and Duosike Fe–P–(Ti)-oxide deposits were formed in a subduction-related tectonic setting and were the product of subduction-related magmatism.     

钛酸镧烧结物中游离氧化镧的测定

本文研究了La(Ⅲ)与甲基百里酚蓝和溴化十六烷基吡啶在pH7.8—11.0的NH_4OH-NH_4Cl介质中生成紫色络合物的显色反应,λ_(max)=628nm,ε=8.1×10~4,La量在0—90μg/25ml范围内遵循比尔定律,烧结物中一些常见的离子不干扰测定。本法用于烧结物中游离氧化镧的测定,结果满意。     

Attenuation properties of viscoelastic material

The attenuation properties of eight rheological models have been studied theoretically. The expressions forQ have been obtained by using dissipated and stored energies and/or complex modulus for each model. The dependence ofQ on frequency has been demonstrated. The three-element elastic model appears to be the best one to represent the viscoelastic nature of the earth's material for a finite value ofQ.     

北祁连山中段早中奥陶世蛇绿岩中席状岩墙杂岩的发现及其地质意义

作为蛇绿岩套重要组成部分之一的席状岩墙杂岩(Sheeted dyke complex)近来在北祁连山中段肃南县大岔大坂北坡的早中奥陶世蛇绿岩中被发现。这一发现对于祁连山早古生代蛇绿岩来说尚属首次,而且对于研究蛇绿岩的发展演化及探讨奥陶纪时洋底扩张都有重要意义。席状岩墙杂岩由一系列具单向冷凝边的辉绿岩墙组成,以一墙挨一墙的形式产出,岩墙间无任何填充物。席状岩墙杂岩在矿物组合上,常量元素、稀土元素及痕量元素地球化学特征和配分模式,甚至金属硫化物矿化作用方面都有类似之处。这些证据表明席状岩墙杂岩是连通其下岩浆房与其上枕状熔岩的通道。席状岩墙的单向冷凝边为岩浆上升方式和扩张洋脊的存在提供了令人信服的证据。根据Zr/Y—Zr关系图式,得出该区洋脊的扩张速率大约为2cm/a。     

钨、锡流-熔分配实验结果及其矿床成因意义

本文用实验确定了钨、锡在成分不同的花岗质熔体相与共存水热流体相的流-熔分配系数(D_(Me)~(V/L))及其与介质溶液(NaF,KF,HF,NaCl等水溶液)摩尔浓度间的函数关系。实验结果表明,钨、锡的分配行为明显不同。在相同条件下,随体系的不同,D_W~(V/L)比D_(Sn)~(V/L)大几倍至二十倍。钠和钾对钨、锡的流-熔分配行为的影响基本相同,而氟和氯对钨、锡的分配行为的影响相差甚远,花岗质熔体的主成分对D_W~(V/L)和D_(Sn)~(V/L)有复杂的影响。利用这些结果探讨与花岗岩有关的钨、锡矿床的成矿机理,得出了一些与前人不同的新认识。     

鄂东北大别杂岩中混合岩形成的动力学机制

本文针对中小位移量伸缩缝构造进行设计研究，提出了一种常温固化型桥梁伸缩缝。经过对伸缩量Δ２０ｃｍ，Δ＝４０ｃｍ的多座桥梁的实验应用表明，这是一种适用于中小位移量桥梁中性能良好的伸缩缝，施工简便。其桥缝具体结构为，在两侧拍击区采用钢纤维混凝土增，缝内用高分子聚合物与一定比例的水泥及掺合物拌和均匀，经一段时间与桥面和加固铺装层固化成具有较高弹性和一定强度的整体式桥梁伸缩缝。其效果良好，供应用参考。     

The Zoulang Nanshan Caledonian Subduct ion Complex in the Northern Qilian Mountains and Its Dynamics

The front of the Zoulang Nanshan Caledonian volcanic island arc zone in the northern Qilian Mountains is a forearc accretionary terrane, composed of multiple accretionary volcanic island arcs, flysch accretionary wedges,high-pressure metamorphosed detachment zones and remnants of ophiolites. It resulted from the northeastward subduction of the Early Palaeozoic Qilan oceanic crust beneath the Alxa block. High-pressure metamorphism, which occurred during the subduction, progressed through three stages: the initial stage of medium T-high P,the main stage of temperature decrease and pressure increase, and the lag stage of pressure decrease and temperature increase. Finally the paper presents a retrotrench subduction dynamic model indicative of northward subduction of the central Qilian block and southward accretion of the Alxa block during the period of 450-500 Ma.     

北京密怀平山区金矿成矿地质条件及成矿期的探讨

本文通过对密怀平山区金矿成矿地质条件的分析，将密怀平山区金矿的成矿期划分为早元古代吕梁成矿期、中生界印支成矿期及燕山成矿期三个成矿期。     

配位滴定法同时测定金属离子浓度的研究

将多元校正分析法应用于配位滴定中，以ＥＤＴＡ为滴定剂，玻璃电极为指示电极，饱和甘汞电极为参比电极。依据电位滴定原理，对混合三组分：Ｃｕ￣（２＋）、Ｃｄ￣（２＋）、Ｚｎ￣（２＋）、及Ｃｕ￣（２＋）、ＣＯ￣（２＋）、Ｎｉ￣（２＋）进行测定，各金属离子之间的△ｌｏｇＫ在０．０４～２．３４之间，计算误差一般小于土１０％。