Spectroscopic Characterization of Compost at Different Maturity Stages

We studied the physicochemical and molecular changes of compost during its maturation within 60, 90, and 150 days after the composting process. Moreover, the changes were also studied in compost residues after sequential removal of lipidic compounds. Infrared DRIFT spectrometry and ¹³C‐CPMAS‐NMR spectroscopy indicate that the molecular composition of compost changes dramatically during the stabilization period. The most decomposable components, mainly represented by bioavailable lipidic and peptidic structures, were progressively mineralized passing from 60 days to longer periods of compost stabilization. At increasing maturity stages, the composition of organic matter underwent a progressive enrichment in stable hydrophobic and ligno‐cellulosic material. The sequential extraction of lipidic compounds allowed an improved characterization of substrates and confirmed the outlined progressive transformation of compost. Compost may well be chosen on the basis of selected characteristics for environmental applications.     

喀斯特与非喀斯特区土壤含水量与植物叶片δ13C关系的对比研究—— 以贵州清镇市王家寨小流域为例

通过测定贵州省清镇市王家寨小流域内不同背景区(喀斯特与非喀斯特)土壤的含水量以及16种植物叶片的δ13 C值,比较了不同背景区从退化生态到非退化生态过程中各样地之间,以及石漠化和土山样地不同坡位之间土壤含水量与植物叶片δ13 C值的相关关系。研究结果表明,不管是喀斯特背景区还是非喀斯特背景区从退化到非退化的过程中,随着土壤含水量的逐渐增大,植物叶片的δ13 C值与土壤含水量呈现显著的负相关关系,即土壤含水量越大,植物的水分利用效率就越低;而从不同坡位土壤含水量与植物叶片δ13 C值的相关关系分析表明,石漠化样地植物叶片δ13 C值并不随坡位土壤含水量的不同呈现出规律性的变化,而坡位自上而下土山样地植物叶片的δ13 C值则表现出随土壤含水量的增大而逐渐趋负。这些研究结果均反映了植物叶片的δ13 C值对不同生境土壤水分条件的适应机制,其中石漠化样地上的植物对土壤含水量变化的响应最迅速和最敏感。      

Carbon accumulation, nitrogen and phosphorus use efficiency of Sophora davidii seedlings in response to nitrogen supply and water stress

A greenhouse experiment was conducted to explore whether additional nitrogen (N) supply could enhance carbon (C) accumulation, and phosphorus (P) use efficiency (NUE_P) of Sophora davidii seedlings under dry conditions. Two-month-old seedlings were subjected to a completely randomized design with three water (80, 40 and 20% water field capacity (FC)) and three N supply (N0: 0, Nl: 92 and Nh: 184 mg N kg⁻¹ soil) regimes. Water stress decreased C, N and P accumulation, NUE_P, N and P uptake efficiency (NUtE_N and NUtE_P) regardless of N supply. The S. davidii seedlings exhibited strong responses to N supply, but the responses were not consistent with the various N supply levels. Nl increased C, N and P accumulation, and improved NUE_P, NUtE_N and NUtE_P in the same water treatment. In contrast, Nh did few or even depress effects on C, N and P accumulation, and NUE_P, although NUtE_N and NUtE_P increased with Nh in the same water treatment. Even so, NUE_N decreased with increase of N supply in the same water treatment. The results suggested that appropriate or low N supply should be recommended for S. davidii seedling establishment in dry environment by improving C accumulation and NUE_P.     

磷酸亚铁锂碳复合物中碳、铁、磷含量的测定

采用重量法测定了自制磷酸亚铁锂碳复合物中的碳含量,且将碳过滤分离后,制得了样品溶液,用来测定其中的元素含量。采用EDTA络合滴定法和邻菲啰啉分光光度法测得铁离子质量分数分别为33.88%、33.77%,测定的RSD分别为0.1%、0.6%。两种方法的测定结果很接近,但是通过F检验法得到EDTA络合滴定法的精密度显著高于邻菲啰啉分光光度法的精密度。采用磷钼酸喹啉重量法和磷钒钼黄光度法测得磷的质量分数分别为19.22%、19.36%,测定的RSD为1.81%、1.89%。两种方法的测定结果很接近,通过F检验法发现两种方法的精密度不存在显著性差异,通过t检验法发现两种方法在置信度为90%时,不存在显著性差异。     

青海表土花粉分布规律及其与植被的关系

对青海地区63个样点进行植被调查及表土样点分析结果显示:青海地区山地针叶林、针阔混交林、高山灌丛-灌丛草甸、温带草原、灌木-半灌木荒漠及高寒荒漠植被区均有相对独特的花粉组合特征。乔木类中桦呈超代表性,云杉、柏、杨属呈低代表性;灌木、草本中白刺、沙拐枣、柽柳呈低代表性,蒿、藜、麻黄呈超代表性,蔷薇科金露梅、银露梅在自身为优势种的落叶灌丛群落中呈低代表性,在针阔叶林、灌丛草甸过渡带中呈适中代表性。禾本科、莎草科、菊科、豆科、十字花科呈低代表性。A/C值在不同生态环境下的变化幅度较大,但数据组显示A/C值中位数值由半干旱向干旱植被区逐次降低,如草甸和草原为4.14,高山灌丛为2.93,荒漠草原为1.22,荒漠灌丛为0.13,荒漠戈壁为0.05。可见,A/C值能很好地反映环境干湿程度,是环境干旱程度的良好指标。     

树轮资料(1511～1954)太阳活动的多尺度分析——EMD方法的应用

用EMD对Stu iver等提供的树轮14C资料进行分析,结果为:①得到太阳活动的准3、6、11、22、44、110、200、300 a的周期;从趋势项中可以得到准600 a甚至更长的周期波动;②可以判断太阳活动经典的极小期,与公认的极小期有一定的滞后性。从树轮14C含量的变化趋势中可以判断从1954~2100年的太阳活动变化逐渐变强,从2100~2350年太阳活动逐渐开始变弱;③从每个尺度周期波动的时变特征中可以得到,即使在太阳活动的极小期,太阳活动依然存在频率和强度不同的周期波动。     

西部中国沙棘叶片稳定碳同位素组成的空间特征及其气候意义

分析了西部中国沙棘（Hippophate rhamnoides sinensis）叶片稳定碳同位素组成特征及其与环境因子之间的关系。结果表明,中国沙棘叶片δ13C值在-30.40‰~-24.91‰之间变化,平均值约为-27.62‰,属于C3植物。随纬度和经度的升高,中国沙棘叶片δ13C值明显升高,而随海拔的升高而降低,具有明显的空间分布特征。中国沙棘叶片δ13C值与温度没有明显的关系,随蒸发量和日照时间的升高而升高,随降水量的升高有降低趋势,具有明显的气候意义。表明中国沙棘具有较高的水分利用效率,水分是控制中国沙棘δ13C值变化或生长的主导因子。     

Ar/Ar and C geochronology of the Albano maar deposits: Implications for defining the age and eruptive style of the most recent explosive activity at Colli Albani Volcanic District,Central Italy

New ⁴⁰Ar/³⁹Ar and ¹⁴C ages have been found for the Albano multiple maar pyroclastic units and underlying paleosols to document the most recent explosive activity in the Colli Albani Volcanic District (CAVD) near Rome, Italy, consisting of seven eruptions (Albano 1 = oldest). Both dating methodologies have been applied on several proximal units and on four mid-distal fall/surge deposits, the latter correlated, according to two current different views, to either the Albano or the Campi di Annibale hydromagmatic center. The ⁴⁰Ar/³⁹Ar ages on leucite phenocrysts from the mid-distal units yielded ages of ca. 72 ka, 73 ka, 41 ka and 36 ka BP, which are indistinguishable from the previously determined ⁴⁰Ar/³⁹Ar ages of the proximal Albano units 1, 2, 5 and 7, thus confirming their stratigraphic correspondence.     

三维地质建模及数值模拟技术在油藏开发中的应用

通过鄂尔多斯盆地油坊庄油田定31井区侏罗纪延长组长1油藏三维精细地质模型的建立,对该区油田地质储量、采油量、含水率和压力等进行了数值历史拟合,摸清该区剩余油的分布规律:剩余油主要分布在构造高部位、沉积主河道注水未波及部位、生产井泄油半径之外和生产井未补孔部位.针对该区剩余油的分布规律制定了新钻调整井和老井侧钻、注采井网完善、采油工艺挖潜3种方法进行开发方案调整,并对调整后的开发技术指标进行了数值模拟预测.