Actinic flux and photolysis frequency comparison computations using the model PHOTOGT

The accurate radiative transfer model GOMETRAN, initially designed to yield radiances at TOA in the wavelength range 240–790 nm, has been extended to allow for the computation of actinic fluxes down to 175 nm and for the calculation of photolysis frequencies in the atmosphere. The capability of the extended model PHOTOGT (PHOTOGOMETRAN) is demonstrated in a number of successful comparison studies both with recent experiments (ground-based, balloonborne, airborne) and model calculations of radiances, actinic fluxes and photolysis frequencies in the stratosphere and troposphere. In an atmospheric case study, the impact of new quantum yield data for the O₃ » O₂+O(¹ d) photodissociation channel on the photolytic production of O(¹ d) atoms in the lower atmosphere has been quantified.     

Weak-contrast approximation of the elastic scattering matrix in anisotropic media

The plane-wave reflection and transmission coefficients at a plane interface between two anisotropic media constitute the elements of the elastic scattering matrix. For a 1-D anisotropic medium the eigenvector decomposition of the system matrix of the transformed elasto-dynamic equations is used to derive a general expression for the scattering matrix. Depending on the normalization of the eigenvectors, the expressions give scattering coefficients for amplitudes or for vertical energy flux.Computing the vertical slownesses and the corresponding polarizations, the eigenvector matrix and its inverse can be found. We give a simple formula for the inverse, regardless of the normalization of the eigenvectors. When the eigenvectors are normalized with respect to amplitudes of displacement (or velocity), the calculation of the scattering matrix for amplitudes is simplified.When the relative changes in all parameters are small, a weak-contrast approximation of the scattering matrix, based on the exactly determined polarization vectors in an average medium, is obtained. The same approximation is also derived directly from the transformed elasto-dynamic equations for a smooth vertically inhomogeneous medium, proving the consistency of the approximation.For monoclinic media, with the mirror symmetry plane parallel to the interface, the approximative scattering matrix is given in terms of analytic expressions for the non-normalized eigenvectors and vertical slownesses. For transversely isotropic media with a vertical axis of symmetry (VTI) and isotropic media, explicit solutions for the weak-contrast approximations of the scattering matrices have been obtained. The scattering matrix for amplitudes for isotropic media is well known. The scattering matrix for vertical energy flux may have applications in AVO analysis and inversion due to the reciprocity of the reflection coefficients for converted waves.Numerical examples for monoclinic and VTI media provide good agreement between the approximative and the exact reflection matrices. It is, however, expected that the approximations cannot be used when the symmetry properties of the two media are very different. This is because the approximation relies on a small relative contrast between the eigenvectors in the two media.Presented at the Workshop Meeting on Seismic Waves in Laterally Inhomogeneous Media, Castle of Trest, Czech Republic, May 22–27, 1995.     

RATIONAL UTILIZATION OF MOUNTAIN SOILS IN SOUTHEAST QINGHAI-XIZANG (TIBETAN)PLATEAU

ISoil-fo~gEnvironmentandMainSoilTrocsThesoLItheastQinghai-Xizang(Tibetan)PlateauwheretheHengduanMoUnains,eastempartoftheThmalayanandNyainqentanglhamoUnainsarelocatedextendsfrom25'to34"Nand92'to1O5'Ewithanareaof5OO,OOOkm',oraboutone-fiffooftheentireQinghai-XiZangPlateau.ItisatransitionalzoneofdeePdisseCtedmoUntainseXtendingsoutheastWardpenpherallowlandsandwichedin-betWeenSichuanBasinandcentralYunnanPlateau.Whletheterrainofthesmponinclinestosoutheast,thealtitudeofthevaIleysraises…     

Subarcsec 10μm imaging of bipolar flow sources

We have started a program of high-resolution (0.4/pixel) 10m imaging of bipolar outflow sources using the 10m camera CAMIRAS. We present recent results obtained at the Canada France Hawaii Telescope which reveal extended emission or IR companions in several luminous objects. The extended emission we detected probably arises from transiently heated very small grains, while the newly discovered companions could contribute significantly to the outflow activity and extended far-IR emission usually attributed to the main optical source.     

Sub-arcsec 10 μm imaging of β pictoris and other star disk candidates

We have used the ESO 10 m camera, TIMMI, to image with a very high angular resolution (PFoV: 0.3; FWHM:0.9) several main-sequence star disk candidates. Information on the -Pictoris dust disk has been obtained in a region largely inaccessible to previous observations: 0–80 AU, with a resolution of about 5 AU after deconvolution. Another promising target for 10 m imaging, 51 Ophiuchi, appears point-like.based on data collected at the European Southern Observatory (ESO), La Silla, Chile     

On the pH-dependent formation constants of iron(III)-sulfur(IV) transient complexes

An experimental study is described of Fe(III)-S(IV) formation constants measured as a function of pH (1–3), ionic strength (0.2–0.5 M) and [Fe(III)] _T (2.5–5.0×10^–4 M) using a continuous-flow spectrophotometric technique to make observations 160 ms after mixing. Preliminary experiments using pulse-accelerated-flow (PAF) spectrophotometry to measure rate constants on a microsecond timescale are also described. The conditional formation constant at 25 °C can be modeled with the following equation: {ie307-1} where {ie307-2}K ₇ andK ₈ can be interpreted as intrinsic constants for the coordination of HSO ₃ ^– by FeOH²⁺ and Fe³⁺, respectively, but until further evidence is obtained they should be regarded as fitting constants. PAF spectrophotometry showed that the initial reaction of Fe(III) with S(IV) (pH 2.0) is characterized by a second-order rate constant of 4×10⁶ M^–1 s^–1 which is comparable to rate of reaction of FeOH²⁺ with SO ₄ ^2– . However, the PAF results should be regarded as preliminary since unexpected features in the initial data indicate that the reaction may be more complex than expected.     

Kinetics of redox cycling of iron coupled with fulvic acid

The kinetics of conversion of iron(III) (hydr)oxides to ferrous iron mediated by fulvic acid have been investigated in order to improve the understanding of the redox cycling of iron at the oxic-anoxic boundary in natural waters. Under the conditions similar to natural waters, fulvic acid is able to reduce the iron(III) (hydr)oxide. The kinetics of the reaction depend on the reactivity of iron(III) (hydr)oxides and the reducing power of the fulvic acid. The rate of reaction is 60 nm/h obtained under following conditions: total concentration of Fe(III) 1.0 × 10^–4 M, pH 7.5, fulvic acid 5 mg/L. The rate is considered as a net result of reduction and oxidation in the > Fe^III-OH/Fe(II) wheel coupled with fulvic acid. In a real natural water system, reductants other than fulvic acid may be of importance. The results obtained in the laboratory, however, provide evidence that the Fe(OH)₃(s)/Fe(II) redox couple is able to act as an electron-transfer mediator for the oxidation of natural organic substances, such as fulvic acid by molecular oxygen either in the absence of microorganisms or as a supplement to microbial activity.     

地下水非稳定流的LTFAM算法

渗流域内应用拉普拉斯变换(LT)建立相应的有限分析(FAM)方程,顾及渗流域内地下水流的初始条件和边界条件,可在LT空间构成一个封闭的以水头像函数为变量的线性方程组。将此方程组所得的解,通过Stehfest数值反演公式,可归化为时间域的解(水头)。由于时间t被隐含在数值方程内,从而克服了传统数值法按时段(△t)逐步迭代的缺陷,提高了计算效率,也为用嵌入法建立地下水流管理模型提供了一条捷径。     

基于土地适宜性评价与元胞自动机模型的城市开发边界划定方法

城市开发边界的划定可以在一定程度上引导城市空间的良性扩张。为了研究边界划定的方法,以我国某港口城市作为研究区域,在空间增长模拟的方向进行探索。研究中借助土地适宜性评价和元胞自动机边界工具,构建既符合生态资源环境要求又符合城市发展需要的边界划定,同时,为了实现城市用地健康和动态管控举措,提出了建立健全土地用地管理机制的要求。     

随钻测录井地质导向二维分解实时绘图方法

根据随钻测录井实时地质导向和大斜度、水平井评价成图技术需求，针对传统绘图方法存在的弊端，提出了将测录井信息、井眼轨迹和地质模型进行二维分解的实时绘图方法。针对二维分解绘图方法绘图时空复杂度较高的问题，给出了不同事件驱动下的局部实时计算和拷屏重绘算法，控制了对CPU和内存的消耗、提高了绘图效率，消除了实时绘图的闪烁和卡顿现象。应用实例表明，二维分解实时绘图方法能够实现大尺度随钻测录井地质导向图形的流畅、无卡顿实时绘图，可提高大斜度、水平井储层模型评价的刻画精度和时效。