Sedimentary evolution of the Holocene subaqueous clinoform off the southern Shandong Peninsula in the Western South Yellow Sea

Based on the stratigraphic sequence formed since the last glaciation and revealed by 3000 km long high-resolution shallow seismic profiles and the core QDZ03 acquired recently off the southern Shandong Peninsula, we addressed the sedimentary characteristics of a Holocene subaqueous clinoform in this paper. Integrated analyses were made on the core QDZ03, including sedimentary facies, sediment grain sizes, clay minerals, geochemistry, micro paleontology, and AMS 14 C dating. The result indicates that there exists a Holocene subaqueous clinoform, whose bottom boundary generally lies at 15–40 m below the present sea level with its depth contours roughly parallel to the coast and getting deeper seawards. The maximum thickness of the clinoform is up to 22.5 m on the coast side, and the thickness contours generally spread in a banded way along the coastline and becomes thinner towards the sea. At the mouths of some bays along the coast, the clinoform stretches in the shape of a fan and its thickness is evidently larger than that of the surrounding sediments. This clinoform came into being in the early Holocene(about 11.2 cal kyr BP) and can be divided into the lower and upper depositional units(DU 2 and DU 1, respectively). The unit DU 2, being usually less than 3 m in thickness and formed under a low sedimentation rate, is located between the bottom boundary and the Holocene maximum flooding surface(MFS), and represents the sediment of a post-glacial transgressive systems tract; whereas the unit DU 1, the main body of the clinoform, sits on the MFS, belonging to the sediment of a highstand systems tract from middle Holocene(about 7–6 cal kyr BP) to the present. The provenance of the clinoform differs from that of the typical sediments of the Yellow River and can be considered as the results of the joint contribution from both the Yellow River and the proximal coastal sediments of the Shandong Peninsula, as evidenced by the sediment geochemistry of the core. As is controlled mainly by coactions of multiple factors such as the Holocene sea-level changes, sediment supplies and coastal dynamic conditions, the development of the clinoform is genetically related with the synchronous clinoform or subaqueous deltas around the northeastern Shandong Peninsula and in the northern South Yellow Sea in the spatial distribution and sediment provenance, as previously reported, with all of them being formed from the initial stage of the Holocene up to the present.     

2010—2011年东海藻华高发区水体层化对东海原甲藻(Prorocentrum donghaiense Lu)藻华的影响

本文通过2010年和2011年不同时空角度对东海原甲藻藻华进行调查,研究水体层化对藻华发生和发展的影响。结果显示,起初东海原甲藻在50m等深线附近的外海繁殖与聚集,然后随着台湾暖流与长江冲淡水的相互作用,东海区域水体层化现象加剧,其细胞丰度越来越大,直至藻华发生并持续推进到近岸。大部分东海原甲藻细胞位于层化水体上方,而且当水体层化现象明显时,藻华的发展最为迅速且呈大规模爆发状态。结果还显示当出现叶绿素高值层时,总是伴随出现温盐突变现象。本项研究不仅第一次从时间角度记录了东海原甲藻藻华的发展动态,而且还发现了东海水体层化现象为东海原甲藻藻华的发生和发展提供了多种环境因子条件,这为该藻华的监控和预测提供了重要的科学依据。     

有孔虫初房特征变化在珠江三角洲晚全新世东亚夏季风降雨研究中的应用

研究中国降雨格局变化对理解东亚夏季风演化意义重大。本文分析了珠江三角洲柱状样ZJK03-Z中浅水底栖有孔虫常见种Rotalidium annectens的平均初房大小、微球型/显球型比值和壳体δ18O值,以及底栖有孔虫组合中瓷质壳的百分含量,探讨它们对由夏季风降雨引起的河口水体盐度变化的响应,得到了珠江三角洲3114—1260a BP季风降雨的强度变化,识别出了这期间14次季风降雨减少的偏干期。与南美洲Cariaco海盆的钛含量记录对比,二者一致的结果表明,珠江三角洲晚全新世的东亚夏季风降雨与热带辐合带(ITCZ)的南北移动密切相关:夏季风降雨减少,对应于ITCZ纬度位置的南移。     

800年来苏北废黄河三角洲的演变模式

根据历史资料、数据和相关研究,结合研究区域背景,分析苏北废黄河三角洲的演变。结果显示,岸线演变在发育阶段和侵蚀阶段分别为向海延伸约90 km和侵蚀后退约22 km,面积相差约800 km2,三角洲地貌演变表现为岸线平直-曲折-平滑-平直的过程。在废三角洲陆海相互作用的基础上,运用演化模式分析三角洲的演变过程。该三角洲演变可以分为7个演变阶段,发育期在径流和潮流作用下以沙洲并陆淤积延伸方式进行,侵蚀期在波浪和潮流作用下以沙洲合并侵蚀后退和淤积外长交替侵蚀的方式。泥沙输运、人类活动和气候变化对废三角洲的演变有重要影响,巨量的来沙是三角洲发育的原因,泥沙平衡被打破是侵蚀的主要原因。发育期中,泥沙输运影响淤积速度和位置,人类活动和气候变化影响黄河河道迁移、输沙量和产沙量;侵蚀期中,泥沙输运影响侵蚀状态,人类活动在一定程度上影响海岸带冲/淤,气候变化将影响三角洲的演变趋势。     

颗粒态有机物在长江口及其邻近海域的夏季分布和影响因素初析

利用气相色谱法对长江口及其邻近海域的表层颗粒态木质素(p-lignin)进行测定和分析,结合粒度、有机碳(OC%)、叶绿素a(Chl a)、碳稳定同位素(δ13C)等参数研究颗粒态有机物的夏季分布,并对其分布影响因素进行了初步分析。结果表明,悬浮颗粒物粒度组成以粘土和粉砂为主,平均粒径为7.9μm;OC%的值为0.57—7.41%,Chl a的值为0.35—3.71μg/L,δ13C的值为-25.7‰—–16.6‰,在口门外水华站位出现OC%、Chl a和δ13C的最大值,表明浮游生物的现场生产是主要贡献;紫丁香基酚类(S)、香草基酚类(V)和肉桂基酚类(C)8种木质素酚单体的含量Λ8(相对于总有机碳的含量)为0.0406—1.47mg/100mg OC;紫丁香基系列与香草基系列的质量比值(S/V)的分布范围较宽,为0.5—1.6之间,均值为0.8;肉桂基含量与香草基含量比值(C/V)的分布范围为0.02—0.2之间,均值为0.09;香草基酚类的酸醛比值[(Ad/Al)v]在0.24—2.30之间。盐度、总悬浮颗粒物(TSM)浓度是控制长江口内区与邻近海域颗粒态有机物来源与分布差异的重要控制因素,颗粒态木质素在向海输送过程中还会受到矿物组分、生物降解、浮游生物现场生产等各种因素的作用,使其组成成分和性质发生改变。木质素等参数表明最大浑浊带尽管对颗粒态有机物向海输送有改造作用,但是影响区域有限。     

Distributional characteristics of grain sizes of surface sediments in the Zhujiang River Estuary

Distributions of the parameters of sedimentary grain sizes and their correlations were studied to trace the sources of silts and their movement trends in the Zhujiang River Estuary based on the analyses of grain sizes from more than 1080 sedimentary samples. The distributions of the median diameter, public value, quartile deviation, and skewness of sediments were complex in the Zhuiiang River Estuary mainly because of the impact of the matter source regions, distances from the source regions, and hydrodynamic conditions, such as waves, tidal currents, and coastal currents. Analyses of the parameters of the grain sizes for the various types of sediments showed that the distributions of the surface sediments in the Zhujiang River Estuary were controlled by many factors. Their matter sources were mainly the sediments discharged from the runoffs and ebb tidal currents, and from the open sea. The sediments mainly moved by suspension movement. The silts formed a large area of sediments with suspended fine silts in the Zhujiang River Estuary by internal adjustment transportation in the area, and moved toward the western coast of the Zhujiang River Estuary under the effect of Coriolis forces and coastal currents.     

Lacustrine basin unconventional resource plays: Key differences

There has been a revival in hydrocarbon source rock characterization and development associated with growing interest in unconventional resources, where these fine-grained organic-rich rocks act as both source and reservoir. To-date, the exploration focus on shale reservoirs has been largely on marine systems. Lacustrine source rocks for conventional resources are geographically important, dominating regions such as China, Indonesia, and Brazil's resource-base. However, they have been generally untested for unconventional resources.There are a number of key differences in the nature of these hydrocarbon systems that should be considered when assessing whether lacustrine systems may represent future unconventional opportunities in areas where the conventional resource-base is dominated by lacustrine-sourced oil. Among the key differences between these depositional systems is the greater sensitivity to high frequency climatic variability within lacustrine systems. Lacustrine systems are highly sensitive to changes in the balance between precipitation and evaporation, which may lead to rapid changes in lake level, potentially exceeding 600 m. These changes in depositional conditions are geologically rapid and may occur over periods of thousands of years. Such changes can reduce the areal extent of potentially thick source rock intervals to only those portions of a basin where a permanent deep lake was present. Thus the core unconventional target area may be geographically limited compared with their marine counterpart. Although potentially areally limited, a review of many lacustrine source rocks suggests that their thicknesses are often significantly greater than marine source rocks. An examination of the more distal portions of lacustrine systems, where better source rock potential is present reveals that there is generally limited connectivity between source and conventional reservoir. In these settings, such as the Wind River basin (Waltman Shale), the hydrocarbons remain trapped within the shales, potentially leading to over-pressured hydrocarbon charged systems. Such conditions suggest that although areally limited, viable unconventional targets may exist, if suitable reservoir conditions are present. Finally, the character of the oils produced is different in these settings, with lacustrine oils being waxy and displaying different hydrocarbon generation and cracking kinetics. High wax oils display distinct flow characteristics, being more viscous, and may offer different production challenges than their non-waxy marine equivalents. Additionally, differences in their cracking kinetics may indicate that the timing of gas generation for shale gas plays may differ significantly from marine systems.     

Dispersal of the Zhujiang River (Pearl River) derived sediment in the Holocene

High-resolution Chirp profiling and coring reveals an elongated(ca. 400 km) Holocene Zhujiang River(Pearl River)-derived mud area(maximum thickness 20 m) extending from the Zhujiang River Delta, southwestward off the Guangdong coast, to the Leizhou Peninsula. Two depo-centers, one proximal and one distal, are identified. On the continental shelf off the west Guangdong Province, the mud is deposited in water depth shallower than 50 m; while to the southeast of the Zhujiang River Estuary, the mud area can extend to the-120 m isobath. A combined analysis with the stratigraphic sequences of other muddy deposits in the Western Pacific marginal seas(mainly Changjiang(Yangtze) and Huanghe(Yellow) Rivers derived) indicates that the initiation of the Zhujiang River muddy deposit can be further divided into two stages: Stage 1 is before the mid-Holocene sea-level highstand(ca. 7.0 cal. ka BP), the proximal mud was mostly deposited after 9.0 cal. ka BP, when the sea-level rose slowly after the Meltwater Pulse-1C; Stage 2, after the mid-Holocene sealevel highstand, clinoform developed on the continental shelf off the west Guangdong Province, extending ca. 400 km from the Zhujiang River Estuary. The proximal clinoform thins offshore, from ca. 10 m thickness around 5–10 m water depth to less than 1–2 m around 20–30 m water depth. In addition, we also find a developed distal clinoform in the east of the Leizhou Peninsula.     

九龙江-河口表层水体营养盐含量的时空变化及潜在富营养化评价

分别于2012年9月、2013年1、6月,对九龙江两大支流北溪、西溪及河口区开展了3个航次的营养盐监测.研究结果表明,河口区表层水体溶解无机氮（DIN）、总磷（TP）和活性磷酸盐（PO4-P）质量浓度范围分别为0.13-17.35、0.14-1.00和0.00-0.38 mg/dm3,受上游输入和海水稀释作用,营养盐浓度由淡水端至海水端逐渐降低.北溪表层水体的DIN、TP和活性磷酸盐质量浓度范围分别为1.99-24.92、0.12-1.47和0.04-0.68 mg/dm3,受龙岩地区工农业生产及城市进程影响,由上游至下游逐渐降低.西溪表层水体的DIN、TP和活性磷酸盐质量浓度范围分别为2.74-20.61、0.14-0.92和0.02-0.37 mg/dm3,受上游农业生产和下游漳州地区人类活动影响,上下游的DIN质量浓度较高.此外,九龙江沿岸的人类活动可能影响了该地区水体中的溶解无机氮形态组成：北溪和西溪上游的NH4-N和NO3-N占比分别较高.水期分析表明,2013年1月的DIN浓度显著高于其他水期,而不同区域TP和活性磷酸盐的水期波动不尽相同.营养盐结构分析表明,九龙江总体处于磷限制状态,但在河口及北溪部分站位,CDIN/CPO4-P比值已达到适合浮游生物生长繁殖的水平.潜在富营养化程度评价表明,九龙江河口多数站位均处于N或P限制的富营养化级别,但由于N、P营养盐的绝对浓度较高,具有水华暴发的潜在风险.     

商业平板式超滤膜包完整性检验：对海洋胶体生物地球化学研究的启示

The performance and integrity of a cassette cross-flow ultrafilter(Pellicon 2, Millipore) are examined with a suite of macromolecules of different molecular masses. The retention coefficient during the cross-flow ultrafiltration experiments increases with increasing molecular mass and reaches 90% with 10 kDa dextran in both milli-Q water and ultrafiltered seawater media. Based on a 90% retention coefficient, the molecular mass cut-off for the ultrafiltration membrane is defined at 10 kDa, which is ten times(1 kDa) that rated by the manufacturer. To further validate the accuracy of the laboratory calibration, the samples from the lower Zhujiang River and the Jiulong River Estuary are ultrafiltered with the cassette ultrafiltration membrane and the colloidal organic carbon abundances in these samples are quantified with the ultrafiltration permeation model based on time series permeation subsamples. The colloidal organic carbon abundances are 5.8%–21.1% in the Jiulong River Estuary and 5.6%–11.0% in the lower Zhujiang River. These are consistent with the reported values for both estuaries as well as with the colloidal organic carbon abundances in marine environments over the coastal and open oceans with 10 kDa cut-off membranes. Therefore, these field data support the laboratory calibration result and indicate the validity of the experimental and quantification procedure adopted. The discrepancy between the nominal molecular mass cut-off and the actual pore size of the ultrafiltration membrane should be of great concern for research in colloidal and nanoparticle biogeochemistry. Careful examination of the membrane integrity should be taken during ultrafiltration experiments in order to avoid misleading molecular mass cut-off information.