中天山地块南缘两类混合岩的成因及其地质意义

中天山地块是位于中亚造山带西南缘的西天山造山带的重要组成块体,其基底演化和构造亲缘性对恢复西天山的增生造山方式和大地构造格局具有重要意义。混合岩在中天山地块的高级变质地体中广泛分布,是揭示中天山地块基底演化和构造属性的窗口。本文通过开展锆石U-Pb年代学和Hf同位素及岩石地球化学研究,确定了中天山地块南缘乌瓦门杂岩的两类条带状混合岩的原岩性质和形成时代以及混合岩化作用时代和成因机制。第一类条带状混合岩的原岩为中基性岩屑砂岩,混合岩化时代为～1. 8Ga,是在同期角闪岩相变质过程中通过变质分异形成的。第二类条带状混合岩的古成体包括黑云角闪斜长片麻岩和黑云斜长角闪片麻岩,原岩均形成于～2. 5Ga,并叠加～1. 8Ga角闪岩相变质作用,是洋陆俯冲背景下由俯冲洋壳或岩石圈地幔部分熔融形成。侵入古成体的变基性岩墙形成于～1. 72Ga,具有Fe-Ti玄武岩的地球化学特征,起源于后碰撞伸展背景下的软流圈地幔。该类混合岩的浅色体同时穿插古成体和变基性岩墙,呈现突变的野外接触关系,与区域内约787～785Ma混合岩化同期,即混合岩化作用是外来岩浆注入的结果,可能是造山带垮塌引发地壳深熔作用的产物。乌瓦门杂岩记录的～2. 5Ga岩浆活动、～1. 8Ga变质作用和～790Ma混合岩化作用可以和塔里木北缘进行对比,暗示中天山地块是一个具有确切新太古代-古元古代结晶基底的微陆块,并且和塔里木克拉通存在构造亲缘性。     

扬子板块周缘MVT型铅锌矿床闪锌矿微量元素组成特征与指示意义:LA-ICPMS研究

扬子板块周缘铅锌多金属成矿带内分布着数以百计的沉积岩容矿型铅锌矿床,它们不仅是我国主要的铅锌矿产地,同时也是重要的稀散元素(Ge、Ga等)生产基地。本次研究采用LA-ICPMS技术分别测定了扬子板块西南缘的会泽铅锌矿床、金沙厂铅锌矿床、大梁子铅锌矿床,扬子板块北缘的马元铅锌矿床以及扬子板块东南缘的凤凰茶田锌(铅)汞矿床中闪锌矿的微量元素组成,以揭示闪锌矿中微量元素(稀散元素)的富集规律和赋存状态,并为矿床成因类型的厘定及稀散元素矿产资源综合利用提供更多依据。LA-ICPMS微量元素测定结果显示闪锌矿中不同微量元素(稀散元素)分布不均匀,但这些矿床中闪锌矿总体以富集稀散元素Ge、Ga、Cd,贫In、Se、Tl、Te为特征,其Fe、Mn含量要明显低于与岩浆热液有关的高温闪锌矿,指示了扬子板块周缘铅锌矿床可能形成于中-低温成矿流体,而与岩浆热液无直接的成因联系,此外这些矿床中闪锌矿富Ge贫In的特征与其他的密西西比河谷型铅锌矿床(MVT)一致。同时,本次研究综合分析了闪锌矿中不同微量元素(稀散元素)之间的相关关系,并与闪锌矿微量元素LA-ICPMS时间分辨率特征相结合,研究表明:这些铅锌矿床中稀散元素Ge可能主要通过3Zn2+?Ge4++2(Cu+,Ag+)和2Zn2+?Ge4++□(晶体空位)的替代方式进入闪锌矿,Ga在闪锌矿中富集机理主要为2Zn2+?(Cu,Ag)++(Ga,As,Sb)3+。此外,为进一步揭示不同成因类型铅锌矿床中稀散元素的富集规律,本文还系统对比了全球范围内不同类型铅锌矿床闪锌矿的稀散元素(均为LA-ICPMS数据)组成特征,并初步探讨了造成不同成因闪锌矿中稀散元素(Ge、Ga和In)差异性富集的主要控制因素,研究表明:(1) Ge在中低温盆地卤水成矿系统(MVT和SEDEX矿床)和岩浆-火山热液成矿系统(浅成脉状铅锌矿床和VMS矿床)形成的闪锌矿中均可能富集成矿,但中低温浅成脉状矿床中Ge的富集程度要明显高于高温脉状矿床,指示了成矿温度是控制闪锌矿中Ge富集的一个重要因素。(2)铅锌矿床闪锌矿中In主要为岩浆来源,In倾向于在成矿温度较高的岩浆及火山热液成因铅锌矿床中富集成矿,而壳源的MVT和SEDEX型铅锌矿床中闪锌矿均贫In。可见除形成温度外,成矿物质来源是决定闪锌矿是否富In的关键因素。(3)除矽卡岩型铅锌矿床外,其他不同成因类型、不同形成温度的铅锌矿床中闪锌矿均可能富Ga。矽卡岩型铅锌矿床闪锌矿具有明显的贫Ga、Ge的特征,这可能是由于矽卡岩化过程中稀散元素Ga、Ge大量进入早期矽卡岩矿物,进而导致了成矿流体以及随后形成的闪锌矿中Ga、Ge的贫化。综上所述,闪锌矿中稀散元素富集与否和富集程度受成矿物质来源、成矿流体性质以及流体演化过程等多因素的综合控制。(4)扬子板块周缘铅锌矿床闪锌矿的微量元素(稀散元素)组成特征指示了它们形成于中低温成矿环境,稀散元素的富集规律与其它MVT型铅锌矿床类似。     

“压稳防漏”固井工艺在旬邑-宜君区块的研究与应用

旬邑—宜君区块位于鄂尔多斯盆地伊陕斜坡南与渭北隆起结合部,目前处于开发初期阶段。由于三叠系延长组地层沉积环境及后期构造运动的原因,形成地层不整合接触裂缝和地层应力裂缝,造成在钻井与固井过程中易发生漏失,导致水泥浆上返不足,上部井段未得到有效封固。本文通过对工区地层情况、钻进方式和设备、水泥浆浆柱结构以及施工工艺方面进行研究,探究漏失发生的主要因素。为达到提高油气层封固质量的目的,在工程上针对性地提出防漏措施,优化水泥浆配方,使浆体具有一定堵漏性能,依据“压稳防漏”平衡固井理念,更改浆柱结构和施工工艺。通过采用新技术措施后,工区内油气井环空水泥浆返高及胶结质量满足后期压裂改造要求。     

扬子地块东缘新元古代造山后构造转化:瓮安穹隆构造岩石与年代学限定

扬子地块Rodinian造山后向伸展作用转化的过程与时间,一直是扬子地块新元古代构造演化的重要科学问题。扬子地块东南瓮安穹隆保存了新元古界板溪群至南华系的完整地层层序与角度不整合接触关系,是回答和理解新元古代造山后构造转化问题的理想区域。对新元古代浅变质板溪群沉积岩和南华纪南沱组沉积层序进行了调查,并采取系列样品进行碎屑锆石U-Pb定年分析和岩石地球化学分析。野外调查表明,南华纪南沱组角度不整合于板溪群之上;年代学分析结果表明,板溪群的沉积时代应在772 Ma之前,而南华纪南沱组沉积时代晚于691 Ma。瓮安穹隆新元古代板溪群沉积岩SiO₂含量中等,SiO₂/Al₂O₃平均值为5.53,K₂O/Na₂O平均值为7.14,TFeO+MgO平均值为3.47%。板溪群物源可能来自上地壳,原岩以长英质物源为主,为活动大陆边缘构造背景,其物源主要来自扬子地块西缘。南沱组沉积岩样品SiO₂含量中等,SiO₂/Al₂O₃平均值为4.69,K₂O/Na₂O平均值为20.41,TFeO+MgO含量平均值为6.64%;碎屑沉积岩稀土元素球粒陨石标准化曲线与上陆壳相似,以轻稀土富集、显著的铕负异常和重稀土平坦为特征。南沱组沉积岩物源可能来自上地壳,原岩以长英质物源为主,有少量中性岩混入,具有裂谷背景特征。综上所述,认为瓮安穹隆板溪群—南沱组地层层序代表了从造山作用向造山后伸展裂谷转化过程,其中板溪群可能与碰撞造山作用对应,主体约在772 Ma结束,而造山后裂谷的形成在691 Ma之后,因此,从造山作用向造山后伸展转化的时间大约为772~691 Ma。     

中牟区块太原组-山西组页岩气勘探井位优选

页岩气井位优选在于选准最佳的勘探层段、缩小目标范围,部署最有利页岩气区域,减少钻探风险,减低勘查成本,加速成果突破的目的。本文在中牟区块现有油气地质资料、钻井样品测试地化成果、三维地震勘探成果的基础上,综合研究后确定太原组-山西组泥页岩在2806m—2979m段为页岩气勘探井位最有利层位;依据沉积、构造、TOC、有机质成熟度、含气量、脆性、裂缝、可压性等成果数据要素,通过软件优选多要素叠加成图,圈定各项特征相对好的区域作为页岩气勘探目标区,圈定区块内四个页岩气勘探范围。已在优选范围部署一口探井现已排采试气,得了较好的页岩气显示。     

Ore geology,fluid inclusions and O-S stable isotope characteristics of Shurab Sb-polymetallic vein deposit,eastern Iran

The Shurab Sb-polymetallic mineralization is a subvolcanic rock-hosted epithermal deposit and located in north Lut Block, eastern Iran. It is one of the most important deposits of the Iranian East Magmatic Assemblage (IEMA) in which numerous Middle-Cenozoic precious and base metals deposits occur. The main lithological units in the area are Paleogene subvolcanic intrusions and minor Jurassic sedimentary rocks. Mineralization occurs as veins in a series of NW-SE and E-W trending faults and fractures in the Eocene-Oligocene dacite and andesite subvolcanic rocks. Mineralization at the Shurab deposit can be subdivided into four stages: pre-ore stage, Cu-Zn-Pb ore stage, Sb-Ag ± As ore stage and post-ore stage. The total sulfide content of the veins in the area is variable, ranging from 1 to 50%, and is dominated by stibnite, chalcopyrite, galena, Fe-poor sphalerite and pyrite with minor chalcostibite, Ag-tetrahedrite and bournonite; gangue minerals are mainly quartz and calcite. Silicic, argillic, propylitic, and sericitic, are the most obvious wall rock alterations. Microthermometric measurements of primary liquid-rich fluid inclusions in quartz and sphalerite indicate that the veins were formed at temperatures between 115 and 290 °C from fluids with salinities between 0.7 and 16.2 wt% NaCl eq., suggesting an epithermal origin. The δ³⁴S values of pyrite, chalcopyrite and galena vary between -2.5 and 0.8‰, and δ¹⁸O values of quartz range between 12.5 and 14.8‰. It is inferred that the Shurab mineralization is of epithermal origin, related to an Eocene-Oligocene magmatic geothermal system involving fluids of magmatic and meteoric origin.     

Petrogenesis and tectonic implications of Triassic A-type granites in southeastern China: insights from zircon U–Pb–Hf isotopic and whole-rock geochemical compositions of the Luoguyan and Guiyantou granites in northwestern Fujian Province

Triassic A-type granites in eastern South China Block (SCB) are abundant in the Wuyi–Yunkai tectonic domain and provide an important opportunity to explore the early Mesozoic evolution of continental crust of the SE part of the SCB. We carried out U–Pb zircon dating, Lu–Hf isotope analyses of zircon, and whole-rock geochemical analyses for two granitic plutons, the Guiyantou (GYT) and Luoguyan (LGY) granites, from northwestern Fujian Province. LA–ICP–MS U–Pb zircon analyses yielded ages of 232 ± 4 to 231 ± 7 Ma and 221 ± 5 Ma (Middle-Late Triassic) for the GYT and LGY granites. These two granites belong to metaluminous to weakly peraluminous high K calc-alkaline A-type granite that are enriched in K, Al, light rare earth element and Rb, Th, U, and Pb, and depleted in Nb, Ta, P, and Ti. Their rare earth element patterns are highly fractionated with (La/Yb)_N ratios of 2–21 and strong negative Eu anomalies (Eu/Eu* = 0.02–0.31). In situ Hf isotopic analysis of zircon from the GYT and LGY granites yielded ε_Hf(t) values ranging from –11.5 to –1.1, with corresponding two-stage Hf model ages from 1.98 to 1.33 Ga, from which it is inferred that the GYT and LGY magmas formed by partial melting of Proterozoic metasedimentary rock in the Cathaysia block. The two granites were emplaced at 232 and 221 Ma and together with Triassic A-type granites in coastal region of the SCB, which is in agreement with an extensional tectonic setting in the Middle-Late Triassic. We suggest that the Middle-Late Triassic A-type granites in eastern SCB were probably formed in an intracontinental, post-orogenic extensional regime that collision was between the SCB and an ‘unknown block’ or the eastern extension of Indochina block.     

Proterozoic VanDieland in Central Victoria: ages,compositions and source depths for late devonian silicic magmas

The Proterozoic to Cambrian VanDieland microcontinent was accreted to mainland Australia at ca 400?Ma, and its northern tip, the Selwyn Block, forms the basement in central Victoria. Here, mainly Late Devonian, silicic magmas were derived from the Selwyn Block and intruded into the shallow crust. We use the phase petrology of Late Devonian, S-type rhyolitic ignimbrites and a xenolith of pelitic migmatite, together with Nd-model ages for the silicic magmatic rocks to constrain the lithological characteristics of the metasedimentary component of the Selwyn Block, to infer minimum depths and temperature conditions here in the Late Devonian, and the likely ages of the source rocks for the S-type magmas. The most abundant source rocks are inferred to be volcaniclastic metagreywackes, with minor metadacites, meta-andesites and metapelites. The metapelitic xenolith cannot have been the source for any of the silicic magmas but constrains the upper amphibolite-facies part of the Selwyn Block to depths around 17?km, where temperatures reached ～775?°C. The older ignimbrite magma was formed by partial melting at perhaps 770?°C and a depth of at least 33?km, while the younger ignimbrite magma formed at ～23?km and 900?°C. These depths suggest source rocks in the Paleoproterozoic to Mesoproterozoic lower parts of the Selwyn Block. Nd-model ages of the silicic magmatic rocks confirm a dominance of Mesoproterozoic to Paleoproterozoic sources. If the inferred rock types in the Mesoproterozoic formations were as current correlations suggest, the sources for the Late Devonian silicic magmas would have to lie in the undocumented Paleoproterozoic basement of the Selwyn Block. Rock types here must include andesitic to dacitic volcanic components as well as volcaniclastic greywackes and minor pelites, which suggests a continental arc setting. The Late Devonian magmatism in the region may record the progression from amphibolite- to granulite-facies conditions during post-orogenic extension, with heat advected to the crust by mantle-derived mafic magmas. These processes would have resulted in mafitisation of the deep Selwyn Block.     

拉萨地体中部上白垩统达雄组的建立及构造隆升意义

拉萨地体中部措勤盆地内,呈东西向发育一套厚度巨大(~1800m)的晚白垩世陆相磨拉石沉积建造。通过对研究区内达雄村附近出露较好的虾格子剖面开展详细的测制工作,并将该套地层自底到顶分为5段,依次为中-粗粒砂岩层段、大套砾岩层段、中粒砂岩夹粉砂岩-泥岩层段、大套紫红色与绿色粉砂岩/泥页岩层段以及均质中粒砂岩层段。地层底部与下伏郎山组含圆笠虫灰岩呈沉积不整合关系,顶部被新生代沉积物覆盖。通过岩相组合与沉积结构构造分析研究,认为该套地层形成于冲积扇-辫状河沉积体系。通过地层顶部火山灰夹层和下伏郎山灰岩的圆笠虫化石显示其形成年龄约为98~91 Ma,这与获得的砂岩碎屑最年轻锆石年龄较为一致。砾岩砾石统计结果显示火山岩砾石为其主要成分。砂岩碎屑成分显示以大量火山岩岩屑为主。这些碎屑成分特征表明其主要来自岩浆弧的物源区。结合碎屑锆石U-Pb年代学和Hf同位素数据表明,中拉萨地体上广泛分布的则弄群火山岩可能为其主要的物源区。本文综合该套晚白垩世沉积的时空分布、岩性组合以及物源区特征,将其新命名为"达雄组",并将其与中拉萨地体北侧的竟柱山组对比表明,两者可能共同代表了中拉萨地体在晚白垩世早期(约98~91 Ma)所经历构造隆升,为青藏高原腹地在印度-亚洲大陆碰撞之前隆升提供了地质证据。     

扬子板块北缘早-中志留世硅质岩成因及古沉积环境的地球化学研究

本文对四川省若尔盖县北部-甘肃省迭部县中-下志留统[兰多维列统(Llandovery)-温洛克统(Wenlock)]富有机碳硅质岩进行了无机化学研究,目的是探讨其成因及形成环境,并建立研究区硅质岩形成及相关元素富集模式。主要对1个钻孔、2个剖面共28件硅质岩的岩相学、扫描电镜、主量、微量、稀土元素、有机碳及Si、O稳定同位素特征进行了研究。(1)岩相学、扫描电镜分析,Fe/Ti、Al/(Al+Fe+Mn)(0.08~0.79)均值0.31、(Fe+Mn)/Ti,(La/Yb)N(0.12~1.41)均值0.54、δEu(0.81~3.36)均值1.55、∑REE(7.59~253.48)均值82.90,Si同位素(-0.2‰~2.1‰)均值0.66‰、O同位素(13.5‰~21.8‰)均值19.53‰、同位素对成岩温度的反演,显示硅质岩为热水沉积成因,并伴有生物作用(Si、O稳定同位素显示),益哇硅质岩形成时陆源物质供给适量,导致与碳酸盐相关生物繁盛,少量样品受陆源物质影响显著。(2)岩相学、扫描电镜分析,MnO_2/TiO_2、Al2O3/(Al2O3+Fe2O3)、Al/(Al+Fe)(0.08~0.80)均值0.33、Th/U、V(28.6×10~(-6)~2261×10~(-6))均值454.42×10~(-6)、Ti/V,δCe(0.65~1.58)均值1.01、(La/Ce)N(0.60~1.314)均值0.97、有机碳(TOC)-微量元素二元图解,显示研究区硅质岩形成于大陆边缘的热水喷流导致海底局部水动力较强的缺氧环境[特别是δCe、(La/Ce)N、稀土配分模式],部分硅质岩由于富集热液元素导致其具有洋脊、大洋盆地硅质岩的特征。结合前人研究成果,认为研究区硅质岩形成于扬子板块北缘(古商丹洋南缘)热水喷流系统发育(导致海底水动能较强的)、缺氧状态的陆缘拉张裂陷环境,这种环境有利于U、V、Mo、Cu、Ni等变价元素的富集,扬子板块北缘早古生代(寒武纪-志留纪)黑色页岩系产自扩张的大陆边缘缺氧-还原环境。