Geochemical Characteristics and Geological Significance of Early Permian Baya’ertuhushuo Gabbro in South Great Xing’an Range

Field geological investigation and geochemical analysis are carried out on Baya’ertuhushuo Gabbro in South Great Xing’an Range. Field investigation reveals that the gabbro is a magmatic intrusion rather than a component of an ophiolite suite as previously thought. Zircon laser ablation inductively coupled plasma mass spectroscopy (LA-ICP-MS) U-Pb dating indicates the gabbro was formed in 274–275?Ma, just as the widespread volcanic rocks of Dashizhai Formation (P1d), monzogranites and miarolitic alkali-feldspar granites in the study area. The gabbro has SiO2 content between 47.23 wt% and 50.17 wt%, high MgO and FeOT contents of 6.95–11.29 wt% and 7.32–12.24wt%, respectively, and it belongs to low-K tholeiitic series in the SiO2-K2O diagram. The Chondrite-normalized rare earth element (REE) patterns and primitive mantle-normalized spider diagrams of the gabbro are similar to those of Normal Mid-Ocean Ridge Basalt (N-MORB) except for the enrichment of large ion lithophile elements (LILE), such as Rb, Ba and K. In trace element tectonic discriminative diagrams, the samples are mainly plotted in the N-MORB field, and Zircon in?situ Lu-Hf isotopic analysis also indicates the gabbro originated from depleted mantle. Through synthetic studies of the geochemical characteristics and petrogenesis of Baya’ertuhushuo gabbro, volcanic rocks of Dashizhai Formation and granitoids in the area, it is suggested that the early Permian magmatism in the Xilinhot-Xiwuqi area formed in the tectonic setting of asthenosphere upwelling, which was caused by breaking-off of the subducted Paleo-Asian Ocean slab.     

Prolonged Variscan to Alpine history of an active Eurasian margin (Georgia, Armenia) revealed by Ar/Ar dating

Variscan to Alpine magmatic activity on the North Tethys active Eurasian margin in the Caucasus region is revealed by ⁴⁰Ar/³⁹Ar ages from rocks sampled in the Georgian Crystalline basement and exotic blocs in the Armenian foreland basin. These ages provide insights into the long duration of magmatic activity and related metamorphic history of the margin, with: (1) a phase of transpression with little crustal thickening during the Variscan cycle, evidenced by HT-LP metamorphism at 329–337 Ma; (2) a phase of intense bimodal magmatism at the end of the Variscan cycle, between 303 and 269 Ma, which is interpreted as an ongoing active margin during this period; (3) further evolution of the active margin evidenced by migmatites formed at ca. 183 Ma in a transpressive setting; (4) paroxysmal arc plutonic activity during the Jurassic (although the active magmatic arc was located farther south than the studied crystalline basements) with metamorphic rocks of the Eurasian basement sampled in the Armenian foreland basin dated at 166 Ma; (5) rapid cooling suggested by similar within-error ages of amphibole and muscovite sampled from the same exotic block in the Armenian fore-arc basin, ascribed to rapid exhumation related to extensional tectonics in the arc; and finally (6) cessation of ‘Andean’-type magmatic arc history in the Upper Cretaceous. Remnants of magmatic activity in the Early Cretaceous are found in the Georgian crystalline basement at c. 114 Ma, which is ascribed to flat slab subduction of relatively hot oceanic crust. This event corresponds to the emplacement of an oceanic seamount above the N Armenian ophiolite at 117 Ma. The activity of a hot spot between the active Eurasian margin and the South Armenian Block is thought to have heated and thickened the Neo-Tethys oceanic crust. Finally, the South Eurasian margin was uplifted and transported over this hot oceanic crust, resulting in the cessation of subduction and the erosion of the southern edge of the margin in Upper Cretaceous times. Emplacement of Eocene volcanics stitches all main collisional structures.     

Phreatomagmatic boulder conglomerates at the tip of the ca 2772 Ma Black Range dolerite dyke,Pilbara Craton,Western Australia

Unusual volcanic conglomerates with a mixture of well-rounded granitic boulders (to 1.2 m diameter) derived from adjacent basement rocks, and smaller (1 – 10 cm) subspherical basaltic droplets with chilled margins occupy a linear zone along strike of the northern end of the Late Archaean Black Range dolerite dyke in the Pilbara Craton, Western Australia. The matrix of the volcanic conglomerates becomes more angular with decreasing grainsize and grades to rock flour, a trend opposite to that in sedimentary conglomerates. In other places, the matrix consists of chlorite that cuts through, and resorbs, granitic clasts, indicating an origin as volcanic melt. The volcanic conglomerates have peperitic contacts with immediately adjacent flows of the Mt Roe Basalt of the Fortescue Group. A welded volcanic tuff at the peperitic contact is dated at 2767 ± 3 Ma, within error of the 2772 ± 2 Ma Black Range dolerite dyke and the Mt Roe Basalt (2775 ± 10 Ma), confirming the contemporaneity of formation of these geological elements. Subsequent normal faulting has juxtaposed the higher level conglomerates down into their present exposure level along strike of the Black Range dolerite dyke. The linear zone of volcanic conglomerates is interpreted to represent a phreatomagmatic pebble dyke that formed immediately above, and as a result of intrusion of, the Black Range dolerite dyke. Interaction of magma with groundwater caused phreatomagmatic brecciation of the country rock, in situ milling of granitic boulders, incorporation of basaltic melt droplets, and the formation of a mixed matrix of devitrified volcanic glass and granitic material. This process was accompanied by along-strike epithermal Cu – Hg – Au mineralisation.     

Early Devonian synorogenic alluvial-fan deposits of the Maccullochs Range,western New South Wales

The Early Devonian, Maccullochs Range beds (new) of the Winduck Interval largely comprise non-marine fine-grained sheet-flood-deposited sandstones which lie in the southeast sector of the Darling Basin Conjugate Fault System. Deposition of the >2.5 km-thick sequence occurred on the Wilcannia, Towers and Coolabah Bore alluvial fans, that were sourced largely from lightly indurated sandstone caps overlying a large basement high lying north of the Darling River Lineament, and also from west of Maccullochs Range (Coolabah Bore Fan). Four lithofacies are recognised. Lithofacies 1, massive sandstone, is proximal and was deposited from hyperconcentrated sheet floods. The more distal lithofacies 2 is partly massive, partly laminated and partly affected by soft sediment slumping during its deposition. It contains 1.3 – 3.5 m-thick sheet-flood successions that rarely show cross-bedding. Lithofacies 3 and 4 are minor: lithofacies 3, stream-flood deposited, comprises coarse-grained, pebbly sandstone and lithofacies 4, transient playa lake deposits that are locally intercalated with lithofacies 2. In lithofacies 2, thick massive fine-grained sandstone is commonly overlain by laminated sandstone that was deformed when soft. Incised channel deposits in lithofacies 2 deposits are rare and palaeosols were not discovered. Permanency of the positions of two of the alluvial fans, and by inference their feeder streams, remained unchanged for ～9 million years. The fans overlie probable floodplain deposits observed in a quarry in the easternmost part of the study area. Marine fossils are very minor in the range—the brachiopod Howellella jaqueti at one locality indicates an Early Devonian age for one of the brief marine incursions into what was normally an alluvial-fan environment. Very brief marine incursions elsewhere in the group are deduced from the presence of very rare fossil gastropods.     

Lake George revisited: New evidence for the origin and evolution of a large closed lake,Southern Tablelands,NSW, Australia

Lake George contains the longest continuous sedimentary record of any Australian lake basin, but previous age models are equivocal, particularly for the oldest (pre-Quaternary) part of the record. We have applied a combination of cosmogenic nuclide burial dating, magnetostratigraphy and biostratigraphy to determine the age of the basal (fluvial) unit in the basin, the Gearys Gap Formation. Within the differing resolutions achievable by the three dating techniques, our results show that (i) the Gearys Gap Formation, began accumulating at ca 4 Ma, in the early Pliocene (Zanclean), and (ii) deposition had ceased by ca 3 Ma, in the mid late Pliocene (Piacenzian). Whether the same age control provides an early Pliocene (Zanclean) age for the formation of the lake basin is uncertain. During the Piacenzian, the vegetation at the core site was a wetland community dominated by members of the coral fern family Gleicheniaceae, while the surrounding dryland vegetation was a mix of sclerophyll and temperate rainforest communities, with the latter including trees and shrubs now endemic to New Guinea–New Caledonia and Tasmania. Mean annual rainfall and temperatures are inferred to have been ～2000–3000 mm, although probably not uniformly distributed throughout the year, and within the mesotherm range (>14°C <20°C), respectively. Unresolved issues are: (1) Does the basal gravel unit predate uplift of the Lake George Range and therefore provide evidence that one of the proposed paleo-spillways of Lake George, that above Geary's Gap, has been elevated up to 100–200 m by neotectonic activity over the past 4 million years? (2) Did a shallow to deepwater lake exist elsewhere in the lake basin during the Pliocene?     

Magma mingling in the Tungho area,Coastal Range of eastern Taiwan

Complex rocks, consisting of different lithologic breccias and sediments in the Tungho area of the southern Coastal Range, eastern Taiwan, were formed by magmas and magma–sediment mingling. Based on field occurrences, petrography, and mineral and rock compositions, three components including mafic magma, felsic magma, and sediments can be identified. The black breccias and white breccias were consolidated from mafic and felsic magma, respectively. Isotopic composition shows these two magmas may be from the same source. Compared to the white breccias, the black breccias show clast-supported structures, higher An values in plagioclase, higher contents of MgO, CaO, and Fe₂O₃ and lower SiO₂, greater enrichment in the light rare earth elements (LREE), and depletion in the heavy rare earth elements (HREE). The white breccias show matrix-supported blocks and mingling with tuffaceous sediments to form peperite. Physical and chemical evidence shows that the characteristics of these two components (mafic and felsic magmas) are still apparent in the mingled zone. According to their petrography, mafic and felsic magmas did not have much time for mingling. White intrusive structures and black flow structures show that mingling occurred before they solidified. Finally, the occurrence of mingling between magmas and sediments suggests that the mingling has taken place at the surface and not in the magma chamber.     

A 2000 year varve-based climate record from the central Brooks Range,Alaska

Varved minerogenic sediments from glacial-fed Blue Lake, northern Alaska, are used to investigate late Holocene climate variability. Varve-thickness measurements track summer temperature recorded at Atigun Pass, located 41 km east at a similar elevation (r ² = 0.31, P = 0.08). Results indicate that climate in the Brooks Range from 10 to 730 AD (varve year) was warm with precipitation inferred to be higher than during the twentieth century. The varve-temperature relationship for this period was likely compromised and not used in our temperature reconstruction because the glacier was greatly reduced, or absent, exposing sub-glacial sediments to erosion from enhanced precipitation. Varve-inferred summer temperatures and precipitation decreased after 730 AD, averaging 0.4°C above the last millennial average (LMA = 4.2°C) from 730 to 850 AD, and 0.1°C above the LMA from 850 to 980 AD. Cooling culminated between 980 and 1030 AD with temperatures 0.7°C below the LMA. Varve-inferred summer temperatures increased between 1030 and 1620 AD to the LMA, though the period between 1260 and 1350 AD was 0.2°C below the LMA. Although there is no equivalent to the European Medieval Warm Period in the Blue Lake record, two warm intervals occurred from 1350 to 1450 AD and 1500 to 1620 AD (0.4 and 0.3°C above the LMA, respectively). During the Little Ice Age (LIA; 1620 to 1880 AD), inferred summer temperature averaged 0.2°C below the LMA. After 1880 AD, inferred summer temperature increased to 0.8°C above the LMA, glaciers retreated, but aridity persisted based on a number of regional paleoclimate records. Despite warming and glacial retreat, varve thicknesses have not achieved pre-730 AD levels. This reflects limited sediment availability and transport due to a less extensive retreat compared to the first millennium, and continued relative aridity. Overall, the Blue Lake record is similar to varve records from the eastern Canadian Arctic that document a cool LIA and twentieth century warming. However, the occurrence and timing of events, such as the LIA and Medieval Warm Period, varies considerably among records, suggesting heterogeneous climatic patterns across the North American Arctic.

Genesis and evolution of hydrocarbons entrapped in the fluorite deposit of Koh-i-Maran, (North Kirthar Range, Pakistan)

The exceptional development of coeval hydrocarbon and aqueous fluid inclusions (FI) in fluorite from the MVT-type ore deposit of Koh-i-Maran, Baluchistan (North Kirthar range, Pakistan), provides samples which are representative of the ore-forming fluid and which support the hypothesis of petroleum migration in the province. Primary brines at 125°C (10 wt% equ. NaCl) and secondary CH₄-rich brines at 135°C (7 wt% equ. NaCl), are recognised to be associated with oil migration in the fluid inclusions. They support the model of a per ascensum MVT (Mississippi Valley Type) stratabound hydrothermal deposit. A pressure–temperature path of 120–125°C to 165–200 bars is calculated from microthermometric data and PVT modelling of hydrocarbon FI using the modified Peng–Robinson Equation of State (IFP software) from primary cogenetic inclusions (oil and brines).The composition of gas and oil fractions is obtained by a combination of Synchrotron FTIR microanalysis and gas chromatography performed on individual fluid inclusions. The oil entrapped as a coeval primary fluid phase is a light aliphatic normal oil in the range C₈–C₃₅ with a high CO₂ content. The brown solid phase found systematically in the oil is probably asphaltene resulting from precipitation after trapping of the heavy fraction, which commonly occurs by decreasing pressure and temperature and\or by CO₂ injection. Later CH₄-rich brine influx probably modified part of the oil in the primary fluid inclusions because degraded oil is observed within such inclusions. Biomarkers obtained by GC-MS analysis indicate a terpane distribution quite similar to the nearest oil seepage in the Gokurt area. This result and the high CO₂ content of organic fluid inclusions indicate a restricted/confined sedimentary environment for the source rock, which could correspond to the Eocene Carbonate formation with type-II organic matter. A possible additional input of gas from the Sambar formation is suggested as feasible. The link between the fluid inclusion data and the geodynamic evolution lead us to propose a circulation of basinal fluids driven mainly by the fault system during dewatering in the foredeep. In Pakistan, they are coeval to major compressional NW–SE Oligocene episode in the thrust belt. The origin of the fluorine may be found in the basin sediments as well as near the basement. The brines originated in salt structures recognized in eocambrian at the decollement level, the source rock was already mature.     

Evidence for the thrust emplacement of the ‘Lesser Himalaya’ Chur granite,Himachal Pradesh

Numerous peraluminous and porphyritic granitic bodies and augen gneisses of granitic compositions occur in the nappe sequences of the Lower Himalaya. They are Proterozoic-to-lower Paleozoic in age and have been grouped into the ‘Lesser Himalaya granite belt’. The mode of emplacement and tectonic significance of these granites are as yet uncertain but they are generally considered to be sheet-like intrusions into the surrounding rocks. The small and isolated granite body (the Chur granite) that crops out around the Chur peak in the Himachal Himalaya is one of the more famous of these granites. Several lines of evidence have been adduced to show that the Chur granite has a thrust (the Chur thrust) contact with the underlying metasedimentary sequence (locally called the Jutogh Group). The Chur granite with restricted occurrence at the highest topographic and structural levels represents an erosional remnant of a much larger sub-horizontal thrust sheet. The contact relations between the country rocks and many of the other granite and granitic augen gneisses in the Lesser Himalaya belt are apparently similar to that of the Chur granite suggesting that at least some of them may also represent thrust sheets.     

大兴安岭地区内生铜矿床的成因类型、成矿时代与成矿动力学背景

大兴安岭地区位于兴蒙造山带的东段,构造、岩浆活动强烈,蕴藏着丰富的内生有色金属、贵金属矿产资源。本文通过对该区内生铜矿床的地质特征、成因类型和年代学研究,初步将区内内生铜矿床划分为斑岩型、浅成热液高硫化型(铜银、铜锡)和接触交代型三种成因类型,除铜锡矿床外,它们的成矿作用均与高钾钙碱系列I型花岗质岩浆密切相关;其中斑岩型和浅成热液高硫化型(铜、银)的成矿分别发生在485Ma、180~170Ma和170~160Ma;而浅成热液高硫化型(铜锡)矿床与A型花岗质岩浆相关,成矿在150~135Ma之间;接触交代型与它们相伴生,主要发生在180~160Ma和150~135Ma。其成矿动力学背景分别与早古生代兴安地块与松嫩地块的拼合碰撞造山、中侏罗世的西伯利亚板块和华北板块的陆缘增生带碰撞缝合造山与早白垩世碰撞造山后的地壳伸展减薄作用过程相适应,矿床在不同阶段的造山挤压与伸展转换或造山期后的伸展阶段就位,这项研究为深入研究该区内生多金属成矿规律提供了科学依据。