Leaching of an oxide gold ore with chloride/hypochlorite solutions

An oxide gold ore was subjected to chloride/hypochlorite leaching at room temperature. The effects of three factors, including Ca(OCl)₂ vs. NaOCl, OCl⁻ concentration, and HCl concentration on gold leaching performance were investigated. Due to formation of CaOCl⁺ complex in solution and hence less reactivity, calcium hypochlorite produces a sluggish gold leaching kinetics, taking twice the time (46 h) to achieve maximum gold recovery of 58% compared to sodium hypochlorite. 10 g/L of total initial hypochlorite species in solution produces reasonable gold recoveries. The amount of added HCl and hence the initial pH was found to have a major effect on gold leaching kinetics and maximum gold recovery. A high level of 9 g/L of added HCl causes HClO to be very reactive, producing very fast kinetics, reaching 67% gold extraction in 4 h. It also causes a faster consumption of hypochlorous acid, through catalytic decomposition (by NiO and CuO) and disproportionation. Hypochlorous acid reactions with sulfide and ferrous content of ore proceed very slowly in the pH range of 4–11. Gold–chloro complexes are strongly adsorbed on quartz component of ore. To minimize this undesirable adsorption of gold–chloro species, the aging time must be limited to a few hours only.     

Eddy covariance measurements of carbon dioxide,latent and sensible energy fluxes above a meadow on a mountain slope

Carbon dioxide, latent and sensible heat fluxes were measured by means of the eddy covariance method above a mountain meadow situated on a steep slope in the Stubai Valley in Austria, based on the hypothesis that, due to the low canopy height, measurements can be made in the shallow equilibrium layer where the wind field exhibits characteristics akin to level terrain. In order to test the validity of this hypothesis and to identify effects of complex terrain in the turbulence measurements, data were subjected to a rigorous testing procedure using a series of quality control measures established for surface-layer flows. The resulting high quality dataset comprised 36% of the original observations, the substantial reduction being mainly due to a change in surface roughness and associated fetch limitations in the wind sector dominating during nighttime and transition periods. The validity of the high quality dataset was further assessed by two independent tests: (i) a comparison with the net ecosystem carbon dioxide exchange measured by means of ecosystem chambers, and (ii) the ability of the eddy covariance measurements to close the energy balance. The net ecosystem CO₂ exchange measured by the eddy covariance method agreed reasonably well with ecosystem chamber measurements. The assessment of the energy balance closure showed that there was no significant difference in the correspondence between the meadow on the slope and another one situated on flat ground at the bottom of the Stubai Valley, available energy being underestimated by 28% and 29%, respectively. We thus conclude that, appropriate quality control provided, the eddy covariance measurements made above a mountain meadow on a steep slope are of similar quality as compared to flat terrain.     

Boundary-Layer Turbulence Over The Nebraska Sandhills

Data from National Centre for Atmospheric Research (NCAR) Queen Air boundary-layer flights over the Nebraska Sandhills are analyzed to investigate the effects of these low hills on boundary-layer turbulence. The Sandhills are an area of anisotropic rolling terrain with characteristic wavelengths of order 2km and rms height variations of order 25m. The biggest impact is found in early morning flight data where horizontal velocity perturbations appear at the same wavelengths as the terrain and variances (normalised by u ² , where u is the local friction velocity) are significantly enhanced relative to standard flat terrain values. By contrast the vertical velocity variance seems less affected and terrain effects are much less evident in data from the afternoon convective boundary layer.     

The metahyaloclastitic matrix of a unique metavolcanic block reveals subduction in the Somozas Mélange (Cabo Ortegal Complex,NW Iberia): tectonic implications for the assembly of Pangea

The allochthonous Cabo Ortegal Complex (NW Iberian Massif) contains a ~500 m thick serpentinite‐matrix mélange located in the lowest structural position, the Somozas Mélange. The mélange occurs at the leading edge of a thick nappe pile constituted by a variety of terranes transported to the East (present‐day coordinates; NW Iberian allochthonous complexes), with continental and oceanic affinities, and represents a Variscan suture. Among other types of metaigneous (calcalkaline suite dated at 527–499 Ma) and metasedimentary blocks, it contains close‐packed pillow‐lavas and broken pillow‐breccias with a metahyaloclastitic matrix formed by muscovite–paragonite–margarite–garnet–chlorite–kyanite–hematite–epidote–quartz–rutile. Pseudosection modelling in the MnCNTKFMASHO system indicates metamorphic peak conditions of ~17.5–18 kbar and ~550 °C followed by near‐isothermal decompression. This P–T evolution indicates subduction/accretion of an arc‐derived section of peri‐Gondwanan transitional crust. Subduction below the Variscan orogenic wedge evolved to continental collision with important dextral component. Closure of the remaining oceanic peri‐Gondwanan domain and associated release of fluid led to hydration of the overlying mantle wedge and the formation of a low‐viscosity subduction channel, where return flow formed the mélange. The submarine metavolcanic rocks were deformed and detached from the subducting transitional crust and eventually incorporated into the subduction channel, where they experienced fast exhumation. Due to the cryptic nature of the high‐P metamorphism preserved in its tectonic blocks, the significance of the Somozas Mélange had remained elusive, but it is made clear here for the first time as an important tectonic boundary within the Variscan Orogen formed during the late stages of the continental convergence leading to the assembly of Pangea.     

A context for ecosystem-based fishery management: Developing concepts of ecosystems and sustainability

Ecosystems have been viewed both as chaotic, untamed nature, and as mechanical systems with predictable equilibrium states. A developing concept of ecosystems as “complex adaptive systems” lies between these extreme concepts, with recognizably patterned but not fully predictable behavior. Sustainability has also been redefined as humans have exploited and often depleted desirable natural resources. Fisheries management desires sustainable yield, but must rethink this concept within the ecosystem context. The most powerful union of “ecosystem” and “sustainability” acknowledges the defining characteristics of complex adaptive systems with the objective of identifying and sustaining healthy relationships within and between ecosystems, economies, and society.     

复杂地表条件下保幅高斯束偏移

高斯束偏移是一种准确、灵活、高效的深度域成像方法,其不但具有接近于波动方程偏移的成像精度,还保留了Kirchhoff偏移灵活、高效的特点以及对复杂地表条件良好的适应性.本文提出了一种适用于复杂地表条件的且具有相对振幅保持特点的高斯束偏移方法.通过考虑地表高程、倾角以及实际的道间距等信息,推导了基于高斯束表示的波场反向延拓公式,并结合反褶积成像条件,得到了复杂地表条件下的共炮域保幅高斯束偏移公式.同原有方法相比,本文方法不但可以直接在起伏的地表面进行局部平面波的分解,具有更高的成像精度,而且可以得到反映地下随角度变化反射系数的成像结果.数值模型的试算验证了上述结论.     

基于非结构化网格的边界积分方程方法的断层自发破裂模拟

地震自发破裂模拟是震源动力学研究的重要内容,了解复杂的断层动力学破裂过程对深入认识震源特征和解释运动学反演结果具有重要意义.基于边界积分方程方法的破裂模拟已经被广泛使用,大多采用的是平面断层模型的结构化网格划分.由于实际的断层往往具有较为复杂的几何特征,为了更为灵活地刻画断层几何复杂性,我们建立断层模型的三角形网格离散方案,通过精确的解析解形式来计算断层各个单元之间的应力格林函数,联立滑动弱化摩擦准则和非奇异边界积分方程,对断层的自发破裂过程进行了模拟.在简单的平面断层模型下,将计算结果与前人的结果进行了对比,验证了方法的正确性与有效性.对于几种常见的复杂断层模型,例如弯折、阶跃、含障碍体断层等,我们模拟了其破裂过程并对计算结果进行了比较与分析.模拟结果表明,非结构化网格划分的边界积分方程方法能够很好地模拟平面矩形断层或由其组成的规则断层,同时也能成功地模拟具有复杂几何形状的不规则断层上的动力学破裂过程.本研究的结果显示了边界积分方程方法在模拟复杂断层系统的动力学破裂问题上具有较广阔的应用前景.

     

吉林省大荒沟—板石沟早前寒武纪基底的岩石单元划分及其地质演化

根据１５万区域地质调查,将区内的早前寒武纪基底划分为变质上壳岩、中粗粒黑云长英片麻岩、变黑云母钾长花岗岩和变质基性岩四个岩石单元。通过对上述岩石单元岩石类型、地球化学特征、变质变形作用及同位素年代学研究,对其形成时序进行了讨论,由此确定了本区早前寒武纪基底的地质演化轮廓,即在中晚太古时期,本区经历了由玄武安山岩和英安岩双峰式火山建造为主体的上壳岩系的形成阶段,并于２．６Ｇａ遭受角闪岩相变质;随即伴有大规模的ＴＴＧ深成岩浆活动,晚太古末经历绿帘角闪岩相的区域变质作用;至早元古初期,深熔成因的钾质花岗岩侵位,区内已存的早期变质岩石受到该期钾质岩浆的交代改造,并在其成岩之后遭受绿片岩相的区域变质。