Leaching of an oxide gold ore with chloride/hypochlorite solutions

An oxide gold ore was subjected to chloride/hypochlorite leaching at room temperature. The effects of three factors, including Ca(OCl)₂ vs. NaOCl, OCl⁻ concentration, and HCl concentration on gold leaching performance were investigated. Due to formation of CaOCl⁺ complex in solution and hence less reactivity, calcium hypochlorite produces a sluggish gold leaching kinetics, taking twice the time (46 h) to achieve maximum gold recovery of 58% compared to sodium hypochlorite. 10 g/L of total initial hypochlorite species in solution produces reasonable gold recoveries. The amount of added HCl and hence the initial pH was found to have a major effect on gold leaching kinetics and maximum gold recovery. A high level of 9 g/L of added HCl causes HClO to be very reactive, producing very fast kinetics, reaching 67% gold extraction in 4 h. It also causes a faster consumption of hypochlorous acid, through catalytic decomposition (by NiO and CuO) and disproportionation. Hypochlorous acid reactions with sulfide and ferrous content of ore proceed very slowly in the pH range of 4–11. Gold–chloro complexes are strongly adsorbed on quartz component of ore. To minimize this undesirable adsorption of gold–chloro species, the aging time must be limited to a few hours only.     

Eddy covariance measurements of carbon dioxide,latent and sensible energy fluxes above a meadow on a mountain slope

Carbon dioxide, latent and sensible heat fluxes were measured by means of the eddy covariance method above a mountain meadow situated on a steep slope in the Stubai Valley in Austria, based on the hypothesis that, due to the low canopy height, measurements can be made in the shallow equilibrium layer where the wind field exhibits characteristics akin to level terrain. In order to test the validity of this hypothesis and to identify effects of complex terrain in the turbulence measurements, data were subjected to a rigorous testing procedure using a series of quality control measures established for surface-layer flows. The resulting high quality dataset comprised 36% of the original observations, the substantial reduction being mainly due to a change in surface roughness and associated fetch limitations in the wind sector dominating during nighttime and transition periods. The validity of the high quality dataset was further assessed by two independent tests: (i) a comparison with the net ecosystem carbon dioxide exchange measured by means of ecosystem chambers, and (ii) the ability of the eddy covariance measurements to close the energy balance. The net ecosystem CO₂ exchange measured by the eddy covariance method agreed reasonably well with ecosystem chamber measurements. The assessment of the energy balance closure showed that there was no significant difference in the correspondence between the meadow on the slope and another one situated on flat ground at the bottom of the Stubai Valley, available energy being underestimated by 28% and 29%, respectively. We thus conclude that, appropriate quality control provided, the eddy covariance measurements made above a mountain meadow on a steep slope are of similar quality as compared to flat terrain.     

Boundary-Layer Turbulence Over The Nebraska Sandhills

Data from National Centre for Atmospheric Research (NCAR) Queen Air boundary-layer flights over the Nebraska Sandhills are analyzed to investigate the effects of these low hills on boundary-layer turbulence. The Sandhills are an area of anisotropic rolling terrain with characteristic wavelengths of order 2km and rms height variations of order 25m. The biggest impact is found in early morning flight data where horizontal velocity perturbations appear at the same wavelengths as the terrain and variances (normalised by u ² , where u is the local friction velocity) are significantly enhanced relative to standard flat terrain values. By contrast the vertical velocity variance seems less affected and terrain effects are much less evident in data from the afternoon convective boundary layer.     

Integrated Interpolation Methods for Geophysical Data: Applications to Mineral Exploration

Any mine planning requires careful prediction of both the head grade andtonnage ofmineralization. There are various methods of interpolation that attempt to provide reasonable estimatesat unsampled locations. All of these give realizations that are unduly smooth and extremevalues that occur in reality are not reflected in these estimates. Such methods, therefore,provide limited scope for accurate risk assessment. An alternative approach that is rapidlygaining popularity is the method of conditional simulation. This approach attempts to reproduceboth the grade distributions of the sample data as well as its spatial variability. In this paper,a case study is presented on a platinum mineralization to demonstrate and compare sequentialGaussian and sequential conditional simulation techniques and to quantify and discuss therelevant sensitivities.     

The metahyaloclastitic matrix of a unique metavolcanic block reveals subduction in the Somozas Mélange (Cabo Ortegal Complex,NW Iberia): tectonic implications for the assembly of Pangea

The allochthonous Cabo Ortegal Complex (NW Iberian Massif) contains a ~500 m thick serpentinite‐matrix mélange located in the lowest structural position, the Somozas Mélange. The mélange occurs at the leading edge of a thick nappe pile constituted by a variety of terranes transported to the East (present‐day coordinates; NW Iberian allochthonous complexes), with continental and oceanic affinities, and represents a Variscan suture. Among other types of metaigneous (calcalkaline suite dated at 527–499 Ma) and metasedimentary blocks, it contains close‐packed pillow‐lavas and broken pillow‐breccias with a metahyaloclastitic matrix formed by muscovite–paragonite–margarite–garnet–chlorite–kyanite–hematite–epidote–quartz–rutile. Pseudosection modelling in the MnCNTKFMASHO system indicates metamorphic peak conditions of ~17.5–18 kbar and ~550 °C followed by near‐isothermal decompression. This P–T evolution indicates subduction/accretion of an arc‐derived section of peri‐Gondwanan transitional crust. Subduction below the Variscan orogenic wedge evolved to continental collision with important dextral component. Closure of the remaining oceanic peri‐Gondwanan domain and associated release of fluid led to hydration of the overlying mantle wedge and the formation of a low‐viscosity subduction channel, where return flow formed the mélange. The submarine metavolcanic rocks were deformed and detached from the subducting transitional crust and eventually incorporated into the subduction channel, where they experienced fast exhumation. Due to the cryptic nature of the high‐P metamorphism preserved in its tectonic blocks, the significance of the Somozas Mélange had remained elusive, but it is made clear here for the first time as an important tectonic boundary within the Variscan Orogen formed during the late stages of the continental convergence leading to the assembly of Pangea.     

基于双变网格算法的地震波正演模拟

为了适应对局部复杂模型的精细模拟,本文实现了可变网格算法,对速度场进行局部加密,从空间上有效地提高模拟精度同时又降低计算机内存需求.但是在数值模拟中,由于稳定性条件的限制,当空间网格变化时,时间稳定性仍然必须满足最短波长的原则,从而增加了时间汁算量.为了配合空间可变网格技术,本文对时间层计算也进行了局部变化,提出了双变...     

南非布什维尔德岩浆型Cu-Ni-PGE硫化物矿床成因探讨

南非布什维尔德杂岩体(BIC)是世界上最大的镁铁质层状侵入体(东西长450km,南北宽250km),也是世界上单个蕴藏铂族金属( PGE)、铬铁矿和钒钛磁铁矿的最重要矿床,其中PGE储量为65 473 t,含有全球75％的PGE,是全球最大的PGE矿床.沿着Rustenburg镁铁质-超镁铁质层状岩套(RLS,厚度7～...     

Thermal gradients in the Sri Lankan granulite terrane: a garnet–biotite thermometric approach

Thermal zoning of the Highland Complex, Sri Lanka has been delineated using the Fe²⁺–Mg distribution coefficient between garnet and biotite from garnet–biotite gneiss samples collected with wide geographical distribution. In order to minimize the potential for retrograde Fe–Mg exchange and maximize the potential for retaining peak equilibrium K_D (garnet–biotite) and temperature, garnet and biotite included within feldspar and quartz without other mineral inclusions have been selected. The calculated results indicate four distinct temperature contours with K_D values varying from 1.84 to 6.38 and temperature varying from 996 to 591 °C. From the present results, it is possible to divide the Highland Complex into two major metamorphic zones: a high‐temperature area in the central region and a low‐temperature area in the south‐western and north‐eastern region. In conjunction with the metamorphic pressure variations estimated from the granulites of the Highland Complex in previous studies, it is shown that the high‐ and low‐temperature areas are complemented by a high‐pressure region towards the eastern side and a low‐pressure region towards the western side of this complex. This thermal dome is interpreted to be an artifact of the different crustal levels exhumed following Pan‐African metamorphism.     

Two-stage decompression in orthopyroxene–sillimanite granulites from Forefinger Point, Enderby Land, Antarctica: implications for the evolution of the Archaean Napier Complex

Magnesian metapelites of probable Archaean age from Forefinger Point, SW Enderby Land, East Antarctica, contain very-high-temperature granulite facies mineral assemblages, which include orthopyroxene (8–9.5 wt% Al₂O₃)–sillimanite ± garnet ± quartz ± K-feldspar, that formed at 10 ± 1.5 kbar and 950 ± 50°C. These assemblages are overprinted by symplectite and corona reaction textures involving sapphirine, orthopyroxene (6–7 wt% Al₂O₃), cordierite and sometimes spinel at the expense of porphyroblastic garnet or earlier orthopyroxene–sillimanite. These textures mainly pre-date the development of coarse biotite at the expense of initial mesoperthite, and the subsequent formation of orthopyroxene (4–6 wt% Al₂O₃)–cordierite–plagioclase rinds on late biotite.
The early reaction textures indicate a period of near-isothermal decompression at temperatures above 900°C. Decompression from 10 ± 1.5 kbar to 7–8 kbar was succeeded by biotite formation at significantly lower temperatures (800–850°C) and further decompression to 4.5 ± 1 kbar at 700–800°C.
The later parts of this P–T evolution can be ascribed to the overprinting and reworking of the Forefinger Point granulites by the Late-Proterozoic ( c . 1000 Ma) Rayner Complex metamorphism, but the age and timing of the early high-temperature decompression is not known. It is speculated that this initial decompression is of Archaean age and therefore records thinning of the crust of the Napier Complex following crustal thickening by tectonic or magmatic mechanisms and preceding the generally wellpreserved post-deformational near-isobaric cooling history of this terrain.