Mineral-chemistry and stable-isotope constraints on the magmatism, hydrothermal alteration, and related PGE–(base-metal sulphide) mineralisation of the Mesoarchaean Baula-Nuasahi Complex, India

The Baula-Nuasahi Complex, on the southern flank of the Singhbhum Archaean nucleus in north-eastern India, exposes a series of Mesoarchaean igneous suites. These are (1) a gabbro–anorthosite unit, which is petrographically homogeneous, although mineral-chemistry data hint at a subtle eastward differentiation; (2) a peridotite unit (with three chromitite layers) together with (3) a pyroxenite unit which display cumulate textures, modal layering, and (for the peridotite unit) differentiation trends in both mineralogy and mineral chemistry; and (4) the Bangur gabbro (~3.1 Ga), which defines an oblong intrusion, crosscutting the older igneous suites in the southern part of the complex, with a curvilinear NW-trending apophysis, 2 km long and up to 40 m wide. Magmatic breccia comprising ultramafic and chromitite wall-rock clasts in a gabbro matrix is exposed at the contact of the main Bangur gabbro body and also forms the entire Bangur gabbro apophysis. Concentrations of platinum-group minerals (PGMs) are found where the breccia contains abundant chromitite clasts, and two types of platinum-group-element (PGE) mineralisation are recognised. Type 1 (Pt 1.1–14.2, Pd 0.1–2.1 ppm, with an average Pt/Pd=8–9) is a contact-type mineralisation which occurs in the breccia at the contact between the Bangur intrusion and its ultramafic host. The PGMs—Pt alloys (isoferroplatinum) and sulphides (braggite, malanite)—are enclosed by pyroxene and plagioclase, reflecting a magmatic origin. Significant wall-rock assimilation by the magma (giving rise to the Bangur gabbro) is indicated by changes in pyroxene composition and by the presence of relicts of chromite (from the host) now altered to secondary ferritchromite in the contact zone. Type 2 PGE mineralisation (Pt 0.3–1.6, Pd 1.8–6.0 ppm, with Pt/Pd~0.5–3.0) is restricted to the breccia apophysis of the Bangur gabbro where it occurs in the breccia matrix, associated with an intense hydrothermal alteration which does not exist in the contact zone. PGMs (PGE arsenides, tellurides, bismuthides and antimonides) and, where present, base-metal sulphides (BMSs) form intergrowths with hydrous silicates, reflecting a hydrothermal origin. Oxygen isotope geothermometry documents the main stages of hydrothermal alteration within a decreasing temperature range between 700–1,000 and 500–600 °C, and oxygen, hydrogen and sulphur isotopes show that the hydrothermal fluids were derived from the magma rather than an external source. Pervasive hydrothermal alteration in the breccia apophysis likely represents upward channelling of late-magmatic fluids along a narrow, near-vertical, subplanar conduit which led away from the main magma chamber. We suggest that Type 2 mineralisation was produced by late-magmatic hydrothermal remobilisation and reconcentration of Type 1 PGE mineralisation, and that the composition of the hydrothermal fluids controlled whether BMSs were enriched along with the PGMs.Editorial handling: P. Lightfoot     

Covariance functions and models for complex-valued random fields

In Geostatistics, primary interest often lies in the study of the spatial, or spatial-temporal, correlation of real-valued random fields, anyway complex-valued random field theory is surely a natural extension of the real domain. In such a case, it is useful to consider complex covariance functions which are composed of an even real part and an odd imaginary part. Generating complex covariance functions is not simple at all, but the procedure, developed in this paper, allows generating permissible covariance functions for complex-valued random fields in a straightforward way. In particular, by recalling the spectral representation of the covariance and translating the spectral density function by using a shifting factor, complex covariances are obtained. Some general aspects and properties of complex-valued random fields and their moments are pointed out and some examples are given.     

Spinel–cordierite symplectites replacing andalusite: evidence for melt-assisted diapirism in the Bushveld Complex, South Africa

Spinel–cordierite symplectites partially replacing andalusite occur in metapelitic rocks within the cores of several country rock diapirs that have ascended into the upper levels of layered mafic/ultramafic rocks in the Bushveld Complex. We investigate the petrogenesis of these symplectites in one of these diapirs, the Phepane dome. Petrographic evidence indicates that at conditions immediately below the solidus the rocks were characterized by a cordierite‐, biotite‐ and K‐feldspar‐rich matrix and 5–10 mm long andalusite porphyroblasts surrounded by biotite‐rich fringes. Phase relations in the MnNCKFMASHT model system constrain the near‐solidus prograde path to around 3 kbar and imply that andalusite persisted metastably into the sillimanite + melt field, where the fringing relationship between biotite and andalusite provided spatially restricted equilibrium domains with silica‐deficient effective bulk compositions that focused suprasolidus reaction. MnNCKFMASHT pseudosections that model these compositional domains suggest that volatile phase‐absent melting reactions consuming andalusite and biotite initially produced a moat of cordierite surrounding andalusite; reaction progressed until all quartz was consumed. Spinel is predicted to grow with cordierite at around 720 °C. Formation of the aluminous solid products was strongly controlled by the receding edge of andalusite grains, with symplectites forming at the andalusite‐cordierite moat interface. Decompression due to melt‐assisted diapiric rise of the floor rocks into the overlying mafic/ultramafic rocks occurred close to the thermal peak. Re‐crossing of the solidus at P = 1.5–2 kbar, T > 700 °C resulted in preservation of the symplectites. Two features of the silica‐deficient domains inhibited resorption of spinel. First, the cordierite moat armoured the symplectites from reaction with crystallizing melt in the outer part of the pseudomorphs. Second, an up‐T step in the solidus at low‐P, which may be in excess of 100 °C higher than the quartz‐saturated solidus, resulted in high‐T crystallization of melt on decompression. Even in metapelitic rocks where melt is retained, preservation of spinel is favoured by decompression.     

The late thermal history of the Ronda area, southern Spain

The Betic–Rif belt, in the western Mediterranean, experienced a pre-Alpine history and was later extensively reworked by major Alpine tectonics. There is abundant data showing that the Betic chain suffered very high cooling rates during its Alpine history, constrained mainly by geochronology using various isotopic systems and by palaeontological age determinations. In the westernmost part of the chain the high closure-temperature isotopic systems recorded Miocene high-grade metamorphism in the country rocks. In order to constrain the later stages of cooling, fission-track analysis has been applied to both zircon and apatite. The results point to extremely high rates of cooling (400 °C/Ma) between 21 and 19 Ma. Rates slowed to 100 °C/Ma for the time period 19 to about 12 Ma. The fission-track analysis also confirms the existence of an extensional tectonic stage between 19 and 17 Ma.     

东喜马拉雅构造结南迦巴瓦岩群的解体

通过对研究区南迦巴瓦岩群的大比例尺填图工作，根据南迦巴瓦岩群的原岩建造、变质程度的不同、变形样式的差异，将其解体为在区域上具有可填性3套岩石组合——直白岩组、派乡岩组和多雄拉混合岩，三者之间均以构造面接触。     

新疆喀喇昆仑地区甜水海岩群发现青白口纪叠层石

2 0 0 3年在对新疆喀喇昆仑地区原划长城系甜水海岩群进行地质填图及实测剖面的工作中,采集到了大量叠层石化石,时代为新元古代青白口纪。该群岩石变形非常强烈,变质达绿片岩相。本次区调依据其岩石变形变质特征,结合叠层石化石资料,对其形成时代进行了重新厘定。     

Transboundary biodiversity conservation of the Pha Taem Protected Forest Complex: A bioregional approach

With the financial assistance from the International Tropical Timber Organization (ITTO), the Thailand's Royal Forest Department (RFD) has initiated a strategy for cooperation in transboundary biodiversity conservation with Cambodia and Laos. The Pha Taem Protected Forest Complex (PPFC) in northeastern region was chosen as a pilot project because of the increasing pressure on biodiversity from illegal trade in plants and wildlife across the tri-national borders. The PPFC covers five protected areas in Thailand and adjoins the Phouxeingthong National Biodiversity Conservation Area (NCBA) in Laos and the Cambodia's Protected Forest for Conservation of Genetic Resources of Plants and Wildlife. Two important outputs derived from the project phase I (2001–2004) were a long-term management plan in a framework of transboundary biodiversity conservation and initiative cooperation between the three countries. Cooperation is achieved at certain level and Laos is reluctant to nominate the Phouxeingthong NBCA for inclusion in the project's second phase. In addition, forest cover in buffer zone has been encroached for agricultural practices. The ecological management zones using bioregional approach was developed to provide a framework for transboundary biodiversity conservation in the adjoining protected forests and reducing the conflict of resource uses by local residents in the buffer zone.     

Formation of Al-rich titanite (CaTiSiO4O–CaAlSiO4OH) reaction rims on ilmenite in metamorphic rocks as a function of fH2O and fO2

Reaction rims of titanite on ilmenite are described in samples from four terranes of amphibolite-facies metapelites and amphibolites namely the Tamil Nadu area, southern India; the Val Strona area of the Ivrea-Verbano Zone, northern Italy, the Bamble Sector, southern Norway, and the northwestern Austroalpine Ötztal Complex. The titanite rims, and hence the stability of titanite (CaTiSiO₄O) and Al–OH titanite, i.e. vuaganatite (hypothetical end-member CaAlSiO₄OH), are discussed in the light of fH₂O- and fO₂-buffered equilibria involving clinopyroxene, amphibole, biotite, ilmenite, magnetite, and quartz in the systems CaO–FeO/Fe₂O₃–TiO₂–SiO₂–H₂O–O₂ (CFTSH) and CaO–FeO/Fe₂O₃–Al₂O₃–SiO₂–H₂O–O₂ (CFASH) present in each of the examples. Textural evidence suggests that titanite reaction rims on ilmenite in rocks from Tamil Nadu, Val Strona, and the Bamble Sector originated most likely due to hydration reactions such as clinopyroxene + ilmenite + quartz + H₂O = amphibole + titanite and oxidation reactions such as amphibole + ilmenite + O₂ = titanite + magnetite + quartz + H₂O during amphibolite-facies metamorphism, or, as in the case of the Ötztal Complex, during a subsequent greenschist-facies overprint. Overstepping of these reactions requires fH₂O and fO₂ to be high for titanite formation, which is also in accordance with equilibria involving Al–OH titanite. This study shows that, in addition to P, T, bulk–rock composition and composition of the coexisting fluid, fO₂ and fH₂O also play an important role in the formation of Al-bearing titanite during amphibolite- and greenschist-facies metamorphism.     

Field investigations and monitoring as tools for modelling the Rossena castle landslide (Northern Appennines, Italy)

In the evening of February 28, 2004, a landslide took place in the village of Rossena (Northern Apennines, Italy), built at the base of a crag shaped in a basalt mass and wrapped in highly deformed formation of clay and shale with blocks. The failure damaged some houses, roads and fields but, fortunately, the medieval Rossena Castle, lying on the crag, was not involved at all. The goal of the study was to attain a technical and geological model of the slope to generate a landslide risk zonation, for regularity and development planning, so that the most correct action plans could be proposed. A detailed geological and geomorphological survey allowed for distinguishing the different gravitative landform of this area. It was very helpful to plan direct and indirect investigation, including borehole drillings, samplings, seismic (tomography), and electrical surveys. A monitoring system was built up immediately after the event (three wire extensometers and one inclinometer), then progressively substituted by a more complete one (two tiltmeters, two jointmeters, four inclinometers, two incremental extensometers, and two piezometers). The phenomenon can be divided in different parts. The central sector of the slope is interested by compound slides likely affecting the bedrock and can be considered, at present, the ‘engine’ of the whole instability framework. Indeed, as a consequence, in the upper portion of the slope the huge blocks in which the outer part of the crag is disjointed experienced vertical displacements and, locally, topplings. Finally, the lowest sector is affected by slow movements, probably connected to bedrock creep or rock flow, while the toe, really at the foot of the slope, by shallow landslides. This instability framework is the result of a complex evolution, starting almost more than 9,000 years ago, as testified from a radiocarbon dating. In more recent time (19th century), the Rossena landslide was also triggered by an earthquake that induced the partially breaking up of the crag, causing rock falls and cracks in the ground.     

Update of a Footprint-Based Approach for the Characterisation of Complex Measurement Sites

Horizontal heterogeneity can significantly affect the flux data quality at monitoring sites in complex terrain. In heterogeneous conditions, the adoption of the eddy-covariance technique is contraindicated by the lack of horizontal homogeneity and presence of advective conditions. In addition, uncertainty concerning the sources or sinks influencing a measurement compromises the data interpretation. The consideration of the spatial context of a measurement, defined by a footprint analysis, can therefore provide an important tool for data quality assessment. This study presents an update of an existing footprint-based quality evaluation concept for flux measurement sites in complex terrain. The most significant modifications in the present version are the use of a forward Lagrangian stochastic trajectory model for the determination of the spatial context of the measurements, and the determination of effective roughness lengths with a flux aggregation model in a pre-processing step. Detailed terrain data gathered by remote sensing methods are included. This approach determines spatial structures in the quality of flux data for varying meteorological conditions. The results help to identify terrain influences affecting the quality of flux data, such as dominating obstacles upwind of the site, or slopes biasing the wind field, so that the most suitable footprint regions for the collection of high-quality datasets can be identified. Additionally, the approach can be used to evaluate the performance of a coordinate rotation procedure, and to check to what extent the measured fluxes are representative for a target land-use type.