(NH_4)_2SO_4浸取EDTA-Zn测定试样中RE_2O_3

稀土元素的分析主要采用有机试剂萃取。偶氮试剂做为显色剂的比色分析,分析手续繁琐,也不易得到满意的分析结果,本文在EDTA容量法的基础上,采用较为简便的(NH4)2SO4浸取EDTA-Zn滴定法直接测定新型稀土总量,大大简化了试样的分析过程和操作手续。     

氯化铁对磷酸铁锂中锂浸出性能研究

随着新能源电动汽车的发展,磷酸铁锂(LiFePO₄,LFP)电池的报废量逐年剧增,由于其有价金属锂含量低,回收经济性差,近年来废旧LFP的低成本回收成为研究热点。基于同构诱导置换浸出,以FeCl₃为浸出剂,在固-液反应体系中探究了FeCl₃对LFP中的锂浸出的影响因素,利用未反应核收缩模型探究了两个浸出阶段的宏观动力学。结果表明,增大FeCl₃/LFP摩尔比、减小固液比和升高反应温度可以显著促进锂的浸出;在浸出前4 min内,锂浸出速率主要受固态产物层内扩散过程控制,表观活化能为6.68 kJ/mol; 4 min后锂浸出速率受流体膜外扩散、产物层内扩散和化学反应混合机制的控制。     

Release of toxic elements from rocks and mine wastes at the Furtei gold mine (Sardinia, Italy)

The Furtei gold mine in Sardinia (Italy) exploits a volcanic-hosted high-sulphidation epithermal deposit. Large amounts of materials derived from exploitation are present in open pits, waste rock dumps and cyanidation tailings impoundment. Mineralized rocks in outcrops and waste dumps contain significant amounts of sulphides (mainly pyrite and enargite). These materials have a high potential for acid drainage generation and release of toxic elements (notably Cu and As, but also Al, Ni, Co and Cd) as pointed out by laboratory leaching tests and in agreement with chemical composition of waters draining the mining area, that show pH as low as 2, up to 180 mg/L Cu, up to 5 mg/L As, and up to 788 mg/L Al. On the other hand, leaching solutions and waters interacting with mineral assemblages of the propylitic alteration zone (mainly composed of chlorite, quartz, and calcite, with relic magmatic plagioclase) show higher pH, and lower metal loads. Leachates from cyanidation tailings show variable pH (between 6.2 and 9.7, depending on sulphide content in tailings); cyanide concentration varies between 110 µg/L and about 3 mg/L, whereas contents of toxic elements in leachates are, with the exception of Hg, within the limits of Italian regulations for non-dangerous industrial wastes. Reclamation plans provide for confinement of tailings within specific repositories. This measure should effectively reduce the environmental impact of these materials. Reclamation plans should also include an adequate management of other high-sulphide wastes.     

Changes in mobility and speciation of heavy metals in clay-amended incinerator fly ash

The generation of municipal solid waste incinerator fly ash (MSWIF) has been increasing significantly over the recent past, and its disposal is problematic and costly due to high concentration of leachable heavy metals present in the material. This study explored a potential stabilization of MSWIF by blending with a natural sorbent material with low permeability, clay, and assessed the potential release of heavy metals from the stabilized mixtures under various simulated subsurface environments. The leachability of heavy metals such as Pb, Cd, Cr, Zn and Cu in the MSWIF-clay mixtures cured for 1 to 360 days was investigated by performing leaching tests and sequential chemical extractions (SCE). Leaching tests were performed at acidic, neutral and alkaline pH values. The leaching test results suggested that the natural clay could turn the MSWIF into non-hazardous material. All the MSWIF-clay mixtures demonstrated leaching behavior different from that of the original MSWIF. SCE results revealed that the acidic and reducing conditions were the most unfavorable to the immobilization of the heavy metals in the stabilized MSWIF-clay matrix. Conversely, the oxidizing and alkaline conditions were not critical to the stabilized MSWIF-clay mixtures. Apparently, clay in the mixtures could function as an adsorptive micro-barrier to retain the heavy metals within the MSWIF-clay matrices.     

成都粘土环境中铅的环境容量研究

铅在成都粘土环境中的行为，至今未见研究报道。本文通过现场调研取样，在收集大量第一手资料的前提下，以实验室内淋滤试验为手段．研究铅在成都粘土环境中的特征，计算铅的平均迁出系数，利用环境容量模式，预测成都粘土环境中铅的污染。     

湘南─粤北铁锰多金属矿床的表生风化作用

湘南－粤北是我国一个重要的铁锰多金属矿化带，该矿化带中重要的铁锰多金属矿 经历了海相沉积，热液改造和表生风化等多种地质作用。由沉积作用和热液改造作用形成的原生铁锰多金属矿化岩石，由于其中的成矿元素Ｆｅ，Ｍｎ，Ｐｂ，Ｚｎ和Ａｇ的含量低，有害元素Ｓ的含量高，工业价值不大。     

Leaching of mobile forms of metals in overburden: development and application

A procedure for sequential leaching of various mobile forms of metals in overburden (MOMEO) has been developed. Previous work showed that selective extraction techniques developed for base metals are ineffective for Au extraction. The mobile forms of Au in overburden occur not only as ionic or complex forms but also as ultrafine particles (submicron to nanometer) dispersed in, or bound onto, water-soluble salts, colloidal particles, organic matter, iron and manganese oxides or clay minerals. The conventional approach of partial leach methods, developed for base metals, involves using appropriate extractants to attack the host materials and release the trapped mobile forms of metals into solution. But the ultrafine Au particles thus released from the host are either insoluble in the mild extractant or reabsorbed by colloids. Therefore a two-stage selective leaching scheme has been developed for Au, a sequential leaching procedure to destroy the host materials, followed by a second treatment to place the Au released from the first stage into solution for analysis. This method has been used widely in detailed, regional and strategic exploration in overburden terrains. Case studies from different climatic and geographic settings show that selective leaching of optimum mobile forms of metals in different settings can be effective in finding indications of mineralization. In temperate alluvial terrains, water-extractable and adsorbed or exchangeable forms of metals give the most prominent expression. In arid sandy desert terrains, water-extractable metals and metals in oxides are the best indicators. In cold grasslands, organically bound and water-extractable metals are the most effective indicators of mineralization at depth.     

硫酸盐型盐湖盐田泻利盐矿硫酸镁浸取结晶工艺条件研究

本研究利用盐田高硫酸镁混盐矿—泻利盐矿和提钾老卤为原料,通过中温溶浸、冷却结晶的方法制取工业级硫酸镁。盐田高硫酸镁混盐矿热溶浸取最佳配矿条件,泻利盐矿:提钾老卤:淡水=1∶1.8∶0.8,溶浸温度(55±5)℃,溶浸时间1～2 h;将热滤液分别进行自然蒸发和冷冻结晶处理,得到的粗品经水洗均可达到工业级硫酸镁产品标准,采用冷冻结晶法收率较高,达到80.25%。     

生活垃圾卫生填埋及地质环境效应概论

论述当前世界各国城市建设中必不可少的重要工程设施类型之一——生活垃圾处置工程。总结当前垃圾处置的主要方式,分析卫生填埋在各种处理方式中独具的优势,并简要介绍组成卫生填埋工程的各个部分及其功能;论述垃圾填埋体中进行的各种化学和生物化学作用及其变化;指出垃圾填埋体是其中的核心部分,填埋体结构的优化设计是控制污液污染地质环境的关键,提出填埋体结构设计的技术路线和系统方法。最后,根据当前卫生填埋场实施中存在的问题,为进一步有效地控制垃圾填埋处置对地质环境污染中的研究不足,提出意见和建议     

浓酸熟化——一种有效的硬岩铀矿浸出方法

本文通过对某中生代火山岩型铀矿床矿石进行铀浸出试验研究,认为浓酸熟化浸出法是处理硬岩铀矿石、提高其铀浸出率的一种有效方法。本文所研究的铀矿石,在浸出条件相同的情况下,浓酸熟化法的铀浸出率比常规酸浸法高20％左右。