Response to the Discussion by B. Robins and F. Chiodoni of “Geochemistry of cumulates from the Bjerkreim–Sokndal Intrusion (S. Norway). Part I: Constraints from major elements on the mechanism of cumulate formation and on the jotunite liquid line of descent”

Merging our data with those of Robins and Chiodoni [Robins, B., Chiodoni, F., 2007. Poles apart: A discussion of the « Geochemistry of cumulates from the Bjerkreim–Sokndal layered intrusion (S. Norway). Part I: Constraints from major elements on the mechanism of cumulate formation and on the jotunite liquid line of descent ». Lithos doi:10.1016/j.lithos.2007.03.007], we examine the major-element compositions of 135 samples of so-called phi-C cumulates of the Bjerkreim–Sokndal layered intrusion. We show the limits of the TiO₂/MgO ratio vs. Al₂O₃ diagram in order to ascertain the proportions of cumulus minerals (ilmenite and orthopyroxene) in the ilmenite leuconorite mafic pole. We also discard anomalous samples as we did in the previous paper. The rest of the samples (124 phi-C, i.e. 92% of the whole population) are then used to confirm the existence of plagioclase and mafic poles. It is shown that the mafic pole is indeed a mixture of ilmenite and orthopyroxene, not induced by “spurious correlation”.     

论扬子地块西缘元古宙铁氧化物铜金型矿床与大地构造演化

探讨和总结了扬子地块西缘大地构造演化、元古宙重大构造-岩浆事件与铁氧化物铜金型(IOCG)矿床关系,以促进对深部隐伏IOCG矿床勘查和新技术研发。在新太古界-古元古界小溜口岩组顶部和不整合面之下,含矿层状-似层状碱性方解石钠长石岩中锆石SHRIMP U-Pb年龄为2520±14 Ma,这种似层状铜矿床和其上不整合面型Cu-Co-AuAg-REE-Fe矿体,以云南东川因民铁铜矿床深部小溜口岩组中铜矿床为代表。总体上,IOCG矿床与扬子地块大地构造演化之间关系为:(1)扬子地块于东川运动(中条运动/Hudsonian Orogeny,1800 Ma)形成了陆壳基底。在中元古代初期(1700±50 Ma)发生了地幔热物质上涌侵位的构造-岩浆事件,导致古扬子地块发生裂解并形成裂谷构造和大陆裂谷盆地。在近东西向大陆裂谷盆地发育初期,构造动力学特征为火山地堑式断陷成盆。在碱性铁钠质基性岩、铁钾质粗面岩和铁质辉绿辉长岩形成过程中,形成了第一期IOCG矿床成岩成矿高峰期(1650±50 Ma),以云南大红山IOCG矿床为代表。(2)在裂谷盆地成熟发育期,构造动力学特征为裂陷沉降成盆。因民期和黑山期两次地幔热物质上涌侵位,导致了构造-岩浆-成岩成矿事件发生。在铁钠质基性火山岩、铁钾质粗面岩、水下火成碳酸岩、火山喷溢-火山热水喷流沉积相等形成过程中,形成了第二期IOCG矿床的成岩成矿高峰期(1500±50 Ma),以云南迤纳厂IOCG矿床为代表。(3)在小黑箐运动/满银沟运动(格林威尔造山期,1000 Ma±),扬子地块南缘形成了近南北向洋壳俯冲和陆缘侧向挤压收缩体制,碱性铁质辉长岩-辉绿岩体上涌侵位,伴随同构造期脆韧性剪切带形成和沉积盆地构造反转,形成区域性不整合面(小黑箐运动/满银沟运动)和后期沉积型-火山沉积型铁矿床,为IOCG矿床第三期成岩成矿高峰期(1000±100 Ma)。以白锡腊深部和新塘IOCG矿床为代表,形成IOCG矿床和IOCG矿床的叠加成岩成矿。(4)晋宁-澄江期为多重构造体制耦合与转换格局,扬子地块内部和陆缘具有造山带-沉积盆地-深部地幔柱上涌侵位,深部地幔柱上涌侵位形成的碱性铁质辉长岩具有OIB源区特征,形成了第四期IOCG矿床的成岩成矿高峰期(800±50 Ma),以四川拉拉IOCG矿床受碱性铁质辉长岩侵位与叠加成岩成矿为代表。在澄江期"盆→山"耦合与转换,IOCG矿床和东川型铜矿中进一步发生了盆地流体叠加改造富集(810~700 Ma)。     

Geochemistry of cumulates from the Bjerkreim–Sokndal layered intrusion (S. Norway) Part II. REE and the trapped liquid fraction

Rare earth elements in bulk cumulates and in separated minerals (plagioclase, apatite, Ca-poor and Ca-rich pyroxenes, ilmenite and magnetite) from the Bjerkreim–Sokndal layered intrusion (Rogaland Anorthosite Province, SW Norway) are investigated to better define the proportion of trapped liquid and its influence on bulk cumulate composition. In leuconoritic rocks (made up of plagioclase, Ca-poor pyroxene, ilmenite, ±magnetite, ±olivine), where apatite is an intercumulus phase, even a small fraction of trapped liquid significantly affects the REE pattern of the bulk cumulate, together with cumulus minerals proportion and composition. Contrastingly, in gabbronoritic cumulates characterized by the presence of cumulus Ca-rich pyroxene and apatite, cumulus apatite buffers the REE content. La/Sm and Eu/Eu* vs. P₂O₅ variations in leuconorites display mixing trends between a pure adcumulate and the composition of the trapped liquid, assumed to be similar to the parental magma. Assessment of the trapped liquid fraction in leuconorites ranges from 2 to 25% and is systematically higher in the north-eastern part of the intrusion. The likely reason for this wide range of TLF is different cooling rates in different parts of the intrusion depending on the distance to the gneissic margins. The REE patterns of liquids in equilibrium with primitive cumulates are calculated with mass balance equations. Major elements modelling (Duchesne, J.C., Charlier, B., 2005. Geochemistry of cumulates from the Bjerkreim–Sokndal layered intrusion (S. Norway): Part I. Constraints from major elements on the mechanism of cumulate formation and on the jotunite liquid line of descent. Lithos. 83, 299–254) permits calculation of the REE content of melt in equilibrium with gabbronorites. Partition coefficients for REE between cumulus minerals and a jotunitic liquid are then calculated. Calculated liquids from the most primitive cumulates are similar to a primitive jotunite representing the parental magma of the intrusion, taking into account the trapped liquid fraction calculated from the P₂O₅ content. Consistent results demonstrate the reliability of liquid compositions calculated from bulk cumulates and confirm the hypothesis that the trapped liquid has crystallized as a closed-system without subsequent mobility of REE in a migrating interstitial liquid.     

大兴安岭南段朝克乌拉地区晚侏罗—早白垩世辉长岩年代学和地球化学研究

基于内蒙古朝克乌拉地区开展的1∶5万区域地质调查工作,发现一期以辉长岩为主的基性岩浆活动。研究表明：朝克乌拉地区辉长岩锆石U- Pb年龄为142.6±0.5 Ma、145.1±2.1 Ma,显示岩石为晚侏罗—早白垩世产物。辉长岩为拉斑系列岩石,具有低硅、低钛、贫碱且高钠低钾特点,分异作用极弱,Eu异常不明显,微量元素Ba、Ta、Sr、Hf富集, Rb、Th、Nb、P亏损。辉长岩岩石地球化学显示其岩浆源区为亏损尖晶石二辉橄榄岩地幔发生30%以上的部分熔融形成,存在流体影响的地球化学特征。岩浆在演化过程中存在一定程度的分离结晶作用,地壳混染作用极其微弱。通过与贺根山蛇绿岩配套岩系的类比,结合研究区古生代至中生代构造背景和贺根山缝合带壳幔电性结构全面分析,推断晚侏罗—早白垩世辉长岩具有的岛弧印记特征为贺根山洋发育时期古岛弧环境的反映,辉长岩只是伸展背景下幔源岩浆沿深大断裂上涌作用的产物。     

柴北缘乌兰北部三叠纪辉长岩的年代学和地球化学特征

柴北缘乌兰地区中生代岩浆岩分布广泛，主要出露辉长岩、闪长岩、花岗闪长岩和花岗岩。乌兰北部两件辉长岩样品的LA-ICP-MS锆石U-Pb测年显示其加权平均年龄分别为（241.9±0.9） Ma和（245.4±1.9） Ma，说明其形成于中三叠世早期。辉长岩的w（SiO₂）为47.94%和52.01%，全碱质量分数较低（ALK为1.25%和1.47%），里特曼指数为0.33和0.26，属钙碱性系列岩石；w（Cr）（1 661.00×10^-6和1 418.00×10^-6）、w（Ni）（394.00×10^-6和280.00×10^-6）和Mg^#值（81和79）极高，具幔源原生玄武岩浆特征。轻、重稀土元素分馏较弱，LREE/HREE为3.92和3.44，无明显负Eu异常，表明未发生明显的岩浆分异作用；富集K、Rb等大离子亲石元素，不同程度地亏损Nb、Ta、Ti等高场强元素，表现为与俯冲作用相关的弧岩浆岩特征。辉长岩的ε_Hf（t）值（-3.0~9.3）变化较大，暗示来自地幔的基性岩浆中有地壳组分的加入。结合区域地质演化特征研究成果，认为辉长岩形成于古特提斯洋向北俯冲背景下的大陆边缘弧环境，俯冲的洋壳板片脱水产生的流体导致上覆地幔楔部分熔融，形成玄武质岩浆，岩浆上升侵位过程中遭受地壳物质混染或与壳源岩浆发生混合作用。     

内蒙古狼山地区乌花辉长岩的年代学、地球化学和Sr-Nd-Hf同位素组成:对地幔源区特征和岩石成因的约束

内蒙古狼山地区乌花辉长岩体主要由橄榄辉长岩和角闪辉长岩组成,其锆石LA-ICP-MS U-Pb同位素测年结果表明,岩体形成于(319.8±1.8)～(325.4±1.6) Ma,属于早石炭世末期岩浆活动的产物。地球化学特征上,乌花辉长岩属低钾钙碱性玄武岩系列,具有较高的Mg^#(多在76.70～80.35之间)、Al₂O₃(13.55%～25.13%)和较低的TiO₂(0.18%～1.35%)。稀土总含量较低(∑REE=8.92×10^-6～40.10×10^-6),稀土元素分馏程度不高,呈现出轻稀土元素(LREE)略微富集、重稀土元素(HREE)相对亏损((La/Yb)_N =1.74～3.06)的特点,Eu呈明显的正异常(δEu=1.156～3.86)。岩石富集Pb和K、Rb、Ba、Sr等大离子亲石元素,明显亏损Nb、Ta、Zr、Hf、Th等高场强元素,较低的Zr含量(4.38×10^-6～26.6×10^-6...     

吉林中部敖花村角闪辉长岩锆石U-Pb定年、Hf同位素和岩石地球化学特征

古太平洋板块的俯冲在欧亚大陆东缘的区域构造演化中发挥了重要作用,但其发生的时间尚不清楚。本文报道了吉林中部新发现的敖花村角闪辉长岩的锆石U-Pb年龄、Hf同位素组成和岩石地球化学数据。锆石U-Pb定年显示,角闪辉长岩形成于早侏罗世(180.3±2.3 Ma),锆石εHf(t)值高且均一(9.6～11.3)。岩石地球化学分析显示样品低Si和Al,高Fe、Mg和Ca,富集轻稀土和大离子亲石元素(如Rb、Ba、U、K和Sr),亏损重稀土和高场强元素(如Nb、Ta和Ti),具有弱Eu负异常(δEu=0.67～0.98)。岩石起源于板片流体交代的亏损岩石圈地幔,形成过程中分离结晶、地壳混染和堆晶作用不明显。结合东北地区东段早中生代火成岩组合及时空分布,认为古太平洋板块向欧亚大陆下的俯冲开始于早侏罗世,敖花村角闪辉长岩形成于与古太平洋俯冲密切相关的弧后环境。     

An example of post-collisional mafic magmatism: the gabbro–anorthosite layered complex from the Tin Zebane area (western Hoggar, Algeria)

The Tin Zebane gabbro–anorthosite layered mafic intrusion represented by plagioclase-rich cumulates forms a set of small lenticular to round-shaped mainly undeformed bodies intruding the Pan-African high-pressure metamorphic rocks from western Hoggar (Tuareg shield, southwest Algeria). The coarse-grained anorthosites are mainly made of slightly zoned bytownite (An_86–74) with the higher anorthite content at the cores. Anorthosites are interlayered with leucogabbros and gabbros that show preserved magmatic structures and with olivine gabbros characterised by coronitic textures. The primary assemblage in gabbros includes plagioclase (An_93–70), olivine (Fo_77–70), zoned clinopyroxene (En_43–48Fs_05–13Wo_41–49 with Al₂O₃ up to 4.3 wt.%) and rare orthopyroxene (En_73–78). Pyroxenes and olivine are commonly surrounded by Ca-amphibole. The olivine–plagioclase contact is usually marked by a fine orthopyroxene–Cr-spinel–amphibole symplectite. A magnesian pigeonite (En_70–75Fs_19–20Wo_6–10) is also involved in corona. The coronitic minerals have equilibrated with the primary mineral rims at P–T–a_H2O conditions of 797 ± 42 °C for a_H2O=0.5 and 808 ± 44 °C for a_H2O=0.6 at 6.2 ± 1.4 kbar. The Tin Zebane gabbroic rocks are depleted in REE with a positive Eu anomaly, high Sr (>10 * chondrite) and Al₂O₃ concentrations (17–33%) that support plagioclase accumulation with the extreme case represented by the anorthosites. The REE patterns can be modelised using plagioclase, clinopyroxene and orthopyroxene REE signature, without any role played by accessory minerals. High MgO content points to olivine as a major cumulate phase. Anorthositic gabbros Sr and Nd isotopic initial ratios are typical of a depleted mantle source (Sr_i=0.70257–0.70278; _Nd=+5.9 to +7.8). This isotopic signature is identical to that of the 10-km wide 592 Ma old dyke complex composed of alkaline to peralkaline granites and tholeiitic gabbros and one single bimodal complex can be inferred. The source of the Tin Zebane basic rocks corresponds to the prevalent mantle (PREMA). The Tin Zebane complex was emplaced along the mega-shear zone bounding to the west the Archaean In Ouzzal metacraton. The model proposed suggests a linear lithospheric delamination along this rigid and cold terrane due to post-collisional transtensional movements. This allowed the asthenosphere to rise rapidly and to melt by adiabatic pressure release. Transtension along a rigid body allowed these mantle melts to reach the surface rapidly without any crustal contamination.     

东昆仑印支晚期幔源岩浆活动

东昆仑造山带印支晚期广泛发育一期幔源岩浆活动,其代表性岩石类型为角闪辉长岩、煌斑岩和辉绿岩。石灰沟外滩岩体是这类岩体中最大的一个,40Ar/39Ar同位素定年结果为220Ma左右,具有明显的结晶分异特征。根据地质学、岩石学与地球化学特征,岩浆起源于深度大于90km的上地幔源区,富含挥发分(H2O)的条件使橄榄石在部分熔融过程中更趋稳定,辉石和尖晶石组分更多地进入岩浆,从而制约了岩浆中高Cr低Ni的特点。幔源岩浆的广泛出现是该区软流圈-岩石圈系统对特提斯洋闭合的响应,是在加厚陆壳的底部幔源玄武质岩浆底侵作用的结果。     

西藏西部普兰蛇绿岩中的MOR型辉长岩:岩石学和年代学

西藏普兰蛇绿岩位于雅鲁藏布江缝合带的西段,主要由地幔橄榄岩、辉长岩和玄武岩组成.在拉昂错南侧有一个辉长岩体,面积约1 km2,与其相邻的地幔橄榄岩为侵入接触关系.辉长岩为中细粒辉长结构,块状构造,主要矿物为半自形板柱状基性斜长石和他形-半自形粒状辉石.岩石化学成分显示其具有MOR型岩石特点,表现为中等含量的TiO2(1％～1.77％),低含量的K2O(0.08％～0.21％)和P2O5(0.1％);轻稀土元素(LREE)轻微亏损的近平坦型稀土元素球粒陨石标准化模型,(La/Ce)N、(La/Sm)N和(La/Yb)N等特征比值分别为0.73～0.80、0.44～0.58、0.53～0.65;岩石的高场强元素(HFSE)为相互平行的具有接近1的平坦型分配型式.微量元素的N-MORB标准化图解显示富集大离子亲石元素(LILE)如Rb,高场强元素(HFSE)轻微亏损.辉长岩锆石的LA-ICP-MS U-Pb年龄为130±3Ma,指示了普兰蛇绿岩形成的时代,与邻区休古嘎布、东波蛇绿岩的形成时代相一致.