胶东新城金矿矿床地质特征及开采评价

位于焦家断裂带的新城金矿床矿体主要赋存于主裂面(断层泥)下盘的黄铁绢英岩化碎裂岩带和黄铁绢英岩化花岗闪长质碎裂岩带内。根据勘探资料和测试数据对矿床内Ⅰ号和Ⅴ号主要矿体的赋存特征进行分析, 并结合矿区水文和环境特点对矿床进行了开采评价。研究结果表明, 新城金矿区工程地质条件简单; 矿床开采形成的采空区对矿区岩体稳定性产生的影响较小, 研究区内的主矿体为地质环境条件良好型矿体。      

内蒙古巴彦哈尔金矿床地质特征及成因初探

内蒙古巴彦哈尔金矿床位于华北陆块北缘艾力庙-锡林浩特中间地块西北缘.矿床赋存于中元古代温都尔庙群的绢云石英片岩和绿泥石片岩中.矿床的形成与区内韧性剪切带及华力西期岩浆活动关系密切.矿区内共圈定出5个矿体,总体走向为北西向,矿体呈似层状或透镜状产出,矿石类型包括石英脉型和糜棱蚀变岩型.金矿化与硅化和黄铁绢英岩化蚀变关系密切.结合矿床的矿体地质、矿物成分、矿物嵌布及围岩蚀变特征以及前人包裹体测温结果,认为矿床类型为浅成低温热液型金矿.     

辽宁省凌源-阜新金成矿带地质特征及找矿标志

凌源-阜新金矿成矿带是辽西及辽宁省至关重要的金成矿带.区内出露的各时代地层较齐全,与成矿关系最密切的为建平群小塔子沟组.构造运动发育从太古宙到中生代均有较大规模的构造活动,同时这些构造运动也控制了岩浆岩的侵入和金矿的形成与分布.成矿带内发育含金石英脉型金矿和次火山热液型金矿两种类型的金矿.通过对区域地质背景、典型矿床特征分析,总结了凌源-阜新金成矿带的金矿的赋矿层位、构造对金矿的控制作用及侵入岩与金矿的时空关系等3个方面的找矿标志.     

三山岛断裂在海域北延位置的确定及成矿预测

胶东金矿集中区是中国最重要的黄金基地,三山岛金矿带位于该金矿集中区之胶西北成矿区的西部,近年来深部和海域隐伏区找矿取得重大突破。作为该区域重要的赋矿构造,三山岛断裂带进入海域后向两端延伸位置未能确定。为了查明三山岛断裂在南北两端进入海域后的延展位置,使用海底重力仪开展了海上大比例尺重力测量工作,对其位置进行了推断。在布伽重力异常图上,三山岛断裂表现为规模大、水平变化率大的重力梯级带,在平面上呈"S"形,向北由三山岛金矿延伸入海,向南从新立西延入渤海,跨海后经仓上、潘家屋子东延入渤海。为了确定三山岛断裂带向北东方向穿过三山岛北部海域超大型金矿床后的延展位置,根据重力异常推断的三山岛断裂北延位置,结合该金成矿带地质矿产特征,部署钻孔进行验证。钻孔内主要岩性有中细粒(含黑云母)二长花岗岩、钾化二长花岗岩、碎裂状二长花岗岩、绢英岩化花岗岩等,暗色脉岩有辉长岩及少量黑云母闪长岩、闪长玢岩等,其中暗色矿物黑云母等略具定向排列,脉岩均发生不同程度的蚀变。构造蚀变(矿化)带宽206.25m(876.59~1082.84m),与上盘围岩分界较为清楚,与下盘围岩呈渐变关系,圈定7层矿体,累计厚度28.3m,最厚的单层矿体视厚度16.06m。钻孔位置位于重力梯度变化宽缓的"鼻状区",且空间位置符合等距分布、对应产出、分段富集等分布规律,钻孔中见到多为黄铜矿化、方铅矿、黄铁矿等多金属硫化物矿化,为典型的第一矿集群特征,可以确定该地区继三山岛北部海域470吨超大型金矿发现之后,其北部区域又出现一个很有找矿前景的靶区。     

Geology,geochronology and fluid characteristics of the Pingqiu gold deposit,Southeastern Guizhou Province,China

The junction of the southeastern Guizhou, the southwestern Hunan, and the northern Guangxi regions is located within the southwestern Jiangnan orogen and forms a NE-trending ∼250 km gold belt containing more than 100 gold deposits and occurrences. The Pingqiu gold deposit is one of the numerous lode gold deposits in the southeastern Guizhou district. Gold mineralization is hosted in Neoproterozoic lower greenschist facies metamorphic rocks and controlled by fold-related structures. Vein types present at Pingqiu include bedding-parallel and discordant types, with saddle-reefs and their down limb extensions dominating but with lesser discordant types. The major sulfide minerals are arsenopyrite and pyrite, with minor sphalerite, galena, chalcopyrite, and rare pyrrhotite, marcasite, and tetrahedrite. Much of the gold is μm- to mm-sized grains, and occurs as fracture-controlled isolated grains or filaments in quartz, galena, sphalerite, pyrite, and wallrock.Three types of fluid inclusions are distinguished in hydrothermal minerals. Type 1 aqueous inclusions have homogenization temperatures of 171–396 °C and salinities of 1.4–9.8 wt% NaCl equiv. Type 2 aqueous-carbonic inclusions yield final homogenization temperatures of 187–350 °C, with salinities of 0.2–7.7 wt% NaCl equiv. Type 3 inclusions are carbonic inclusions with variable relative content of CO₂ and CH₄, and minor amounts of N₂ and H₂O. The close association of CO₂-rich inclusions and H₂O-rich inclusions in groups and along the same trail suggests the presence of fluid immiscibility. The calculated δ¹⁸O_H2O values range from 4.3‰ to 8.3‰ and δD_H2O values of fluid inclusions vary from −55.8‰ to −46.9‰. A metamorphic origin is preferred on the basis of geological background and analogies with other similar deposit types.Two ore-related sericite samples yield well-defined ⁴⁰Ar/³⁹Ar plateau ages of 425.7 ± 1.7 Ma and 425.2 ± 1.3 Ma, respectively. These data overlap the duration of the Caledonian gold mineralization along the Jiangnan orogen, and suggest that gold mineralization was post-peak regional metamorphism and occurred during the later stages of the Caledonian orogeny.Overall, the Pingqiu gold deposit displays many of the principal characteristics of the Bendigo gold mines in the western Lachlan Orogen (SE Australia) and the Dufferin gold deposit in the Meguma Terrane (Nova Scotia, Canada) but also some important differences, which may lead to the disparity in gold endowment. However, the structural make-up at deposit scale, and the shallow mining depth at present indicate that the Pingqiu gold deposit may have considerable gold potential at depth.     

Texture and chemistry of pyrite at Chah Zard epithermal gold–silver deposit,Iran

Gold mineralization at Chah Zard, Iran, is mostly concentrated in breccia and veins, and is closely associated with pyrite. Optical and scanning electron microscopy-backscattered electron observations indicate four different pyrite types, each characterized by different textures: porous and fractured py1, simple-zoned, oscillatory-rimmed, framboidal and fibrous py2, colloform py3, and inclusion-rich py4. Laser ablation ICP–MS analysis and elemental mapping reveal the presence of invisible gold in all pyrite types. The highest concentrations (161–166 ppm Au) are found in py2 and py4, which correlate with the highest As concentrations (73,000–76,000 ppm). In As-poor grains, Au concentrations decrease by about two orders of magnitude. Copper, Pb, Zn, Te, Sb, and Ag occur with invisible gold, suggesting that at least part of the gold occurs in nanoparticles of sulfosalts of these metals and metalloids. Gold distribution patterns suggest that only negligible Au was originally trapped in py1 from the initial ore fluids. However, most, if not all, Au was transported and deposited during subsequent overprinting hydrothermal fluid flow in overgrowth rims around the margins of the py2 and within microfractures of py4 grains. Oscillatory zonation patterns for Co, Ni, Sb, Cu, Pb, and Ag in pyrite reflect fluctuations in the hydrothermal fluid chemistry. The LA-ICP–MS data reveal that Cu, Pb and Ag show systematic variations between different pyrite types. Thus, Cu/Pb and Pb/Ag ratios in pyrite may provide a potentially powerful exploration vector to epithermal gold mineralization at Chah Zard district and elsewhere.     

江苏仑山金矿床流体包裹体、稳定同位素和成矿年代学研究

仑山金矿床位于宁镇矿集区东端。成矿期分为沉积成矿期和热液成矿期,后者可进一步划分为热液Ⅰ阶段和热液Ⅱ阶段。流体包裹体研究表明,热液Ⅰ阶段石英中的气液两相流体包裹体均一温度多集中在330~366℃之间,盐度w(Na Cl_(eq))变化于4.96%~6.74%之间,热液Ⅰ阶段方解石中气液两相流体包裹体均一温度多集中在150~240℃之间,w(Na Cl_(eq))变化于0.71%~9.80%之间,成矿流体为中高温低盐度流体;热液Ⅱ阶段石英、方解石和萤石的流体包裹体均一温度变化于124~260℃,盐度w(Na Cl_(eq))变化于1%~8%之间,成矿流体为中温低盐度流体。氢、氧同位素研究表明,热液Ⅰ阶段成矿流体为岩浆流体,热液Ⅱ阶段成矿流体以大气降水占主导,但仍有少量岩浆流体。硫同位素研究表明,仑山金矿床沉积成矿期硫除来源于三叠系青龙群膏盐层外,有机质也参与了沉积成矿期中金矿的形成。热液Ⅰ阶段硫来源于沉积成岩阶段黄铁矿的活化迁移和富集,岩浆硫也提供了成矿物质。萤石Sm-Nd测年分析表明,仑山金矿床热液Ⅱ阶段成矿年龄为(93.7±3.1)Ma,推断主成矿阶段形成于晚白垩世。仑山金矿床的形成代表着长江中下游成矿带最晚期的成矿作用。     

粤西黄泥坑金矿床地质地球化学特征和成矿时代

粤西黄泥坑金矿是近年来新发现的一个中-大型金矿床。其成矿作用分为石英-黄铁矿阶段、石英-多金属硫化物阶段和石英-碳酸盐阶段。其中,石英-黄铁矿阶段为金的主成矿阶段。对含金石英脉进行了流体包裹体Rb-Sr同位素定年,获得等时线年龄为(233.4±8.6)Ma(MSWD=2.3,n=5),表明黄泥坑金矿形成于印支期。对矿区花岗闪长岩进行了锆石LA-ICP-MS U-Pb定年,获得的206Pb/238U加权平均年龄为(451.1±2.7)Ma(MSWD=2.1,n=21),表明其形成于加里东期。综合分析花岗闪长岩和矿石的微量元素分析数据及已有的研究成果显示,黄泥坑金矿床中金的来源并非加里东期花岗闪长岩,可能来自于寒武系及隐伏的晚期岩浆岩。矿床的形成主要受罗定-广宁推覆构造控制,挤压推覆后拉张剪切作用形成的剪切破碎带及其热液蚀变作用与成矿密切相关。     

山东谢家沟金矿床流体包裹体研究及成矿机制的探讨

谢家沟金矿床位于胶东隆起西北缘的焦家断裂带和招平断裂带之间。矿床赋存在中生代玲珑花岗岩体中,矿体主要受NNE向和NNW向断裂构造控制,主要呈脉状或透镜状产出。矿石矿物主要有黄铁矿、黄铜矿、方铅矿、闪锌矿、自然金、银金矿以及少量的碲银矿和辉银矿。围岩蚀变主要有钾长石化、硅化、黄铁绢英岩化、绿泥石化和碳酸盐化等。成矿作用从早到晚可划分为4个阶段:石英-黄铁矿阶段(Ⅰ)、石英-绢云母-黄铁矿阶段(Ⅱ)、石英-多金属硫化物阶段(Ⅲ)、碳酸盐-萤石阶段(Ⅳ)。流体包裹体显微测温和激光拉曼成分分析表明,成矿早期流体温度为308~377℃,盐度为6.29%~8.55%,压力为350 MPa,属于H_2O-CO_2-NaCl流体体系;主成矿期的流体温度为226~331℃,盐度为4.87%~10.29%,压力为280~300 MPa,属于H_2O-CO_2-NaCl±CH_4流体体系。包裹体显微测温及岩相学观察发现,主成矿期的成矿流体发生了不混溶作用,这可能是导致金矿化的主要原因之一。硫同位素研究表明,谢家沟金矿床主成矿期黄铁矿的δ34S值接近或略低于胶东典型金矿床成矿期黄铁矿的δ34S值,暗示这些金矿床的成矿物质可能来自相同的源区;氢、氧同位素对比研究表明,谢家沟金矿床成矿流体表现出较明显的岩浆水特征,可能有大气降水的参与,但参与程度较弱。大气降水与岩浆水混合引起的温度降低、挥发分含量的降低可能是导致金矿化的另一原因。     

闽北大药坑金矿床黄铁矿成分标型及硫、铅同位素组成研究

闽北政和-建瓯矿集区内大药坑金矿床是一个赋存于韧性剪切带中的小型矿床。在野外地质调查基础上,通过分析载金矿物黄铁矿电子探针成分和硫化物硫、铅同位素组成,探讨了大药坑金矿床的成矿作用问题。研究表明,大药坑金矿床黄铁矿的Co/Ni比值大多在1~5之间,为岩浆热液成因黄铁矿,成矿热液的温度和盐度均较高,也表现出岩浆热液的性质;金属硫化物的δ~(34) SCDT均为靠近0的较低正值(0.1‰~3.4‰),说明成矿物质为岩浆来源,硫化物的铅同位素比值以及高μ(~(238)U/~(204)Pb)和ω(~(232)Th/~(204)Pb)等特征,说明成矿物质具有壳幔混源特征。结合区域研究资料,认为大药坑金矿床形成于东南沿海区域强烈壳幔作用时期,与燕山期火山-侵入杂岩有关,矿床成因类型为岩浆期后热液型。