中-哈-吉-乌天山变形带容矿金矿床:成矿环境和控矿要素与找矿标志

天山是全球第二大金矿富集区,世界级和大型-超大型金矿床东西成带横贯中国新疆中部—哈萨克斯坦东南部—吉尔吉斯斯坦—乌兹别克斯坦,构成巨型跨境金成矿带。天山巨型跨境金成矿带和重要金矿床形成的地质环境、成矿的控制要素、找矿勘查的标志都是学术界和工业界高度关注的重大地质和找矿问题。通过广泛、深入地文献调研和境内外天山较全面野外地质矿产调查与研究,本文认为中-哈-吉-乌天山大规模金成矿主体形成于晚石炭世—早二叠世古亚洲洋闭合后的陆块拼贴变形过程,部分形成于中—晚二叠世陆内走滑变形过程。中天山南、北缘古缝合带及其附近的大型脆性/韧-脆性变形带是巨量金成矿的关键控制因素,多期叠加复合成矿是天山变形带容矿金矿床的显著特征。地壳初始富集、构造变形活化、岩浆热液叠加是天山变形带容矿金矿床的主控因素。“碳质细碎屑岩+脆韧性变形带+海西末期岩体”是中-哈-吉-乌天山变形带容矿大型-超大型金矿的找矿标志组合。     

江南造山带(湖南段)金矿成矿规律与资源潜力

扬子地块—华夏地块经历武陵期—雪峰期增生造山-碰撞造山形成江南造山带,构成统一的华南板块,进入板内演化阶段。本文从构造-岩浆作用-沉积建造角度,结合地质年代学、古地磁、岩相古地理分析,加里东运动、印支运动属陆内作用,造就了加里东期、印支期两次主要的金矿成矿事件。湖南雪峰山—幕阜山(俗称“金腰带”)加里东期和印支晚期金矿床分区成带产出,构成一条复合型造山型金矿带。区域性构造导矿、次级构造交汇或叠加控矿明显;矿石普遍发育条带状构造,属韧性剪切递进变形的产物。通过对区域成矿背景、金矿成矿理论,金矿床(体)地质特征,结合同位素地球化学、地质找矿成果及深部验证情况等多方面研究表明该成矿带深部找矿潜力巨大,2000 m以浅金远景资源量有望达到3000 t。     

Recognition of two contrasting structural-and mineralogical-gold mineral systems in the Youjiang basin,China-Vietnam:Orogenic gold in the south and Carlin-type in the north

The gold deposits in the Youjiang basin,totaling 25 Moz gold,have traditionally been thought to be of Carlintype,particularly those with extensional structural geometries in the northern basin dominated by platform sedimentary sequences.However,the structural geometries,mineralization styles and alteration types for the Jinya,Gaolong and Nakuang gold deposits in the south-central part of the basin are remarkably similar to those of unequivocal orogenic gold deposits.Structural studies show that gold mineralization in the three gold deposits was controlled by tight "locked-up"anticlines with NW—SE-to E-W-trending and/or concomitant thrusts and/or shear zones,which resulted from NE-SW-to N-S-trending compression or transpression following the Early Triassic closure of the Paleo-Tethyan Ocean.Alteration zones in these deposits are dominated by silicification(quartz),sericitization,sulfidation and carbonation.Zoned pyrites in these deposits comprise Au-poor cores and invisible Au-bearing rims with minor external free gold.Euhedral to subhedral auriferous arsenopyrites also contribute to the gold budget.These features indicate that the three gold deposits are sediment-hosted orogenic gold deposits that contrast markedly with the Carlin-type gold deposits in the northern part of the Youjiang basin in terms of structural geometry and timing,mineralization style and nature of associated alteration.Although additional reliable ages using robust methodologies are still required,the older isotopic ages of the gold deposits in the south-central Youjiang basin are also consistent with earlier formation during transpression that predated extension during orogenic collapse,the period of formation of the Carlin-type gold deposits in the northern Youjiang basin.     

张宣地区大白阳金矿床包裹体特征及矿床剥蚀保存

华北克拉通破坏及其成矿事件已引起地学界的广泛关注,其中张宣地区是华北克拉通的重要金矿集中区之一,通过对张宣地区大白阳金矿成矿类型、成矿深度及剥蚀保存的探讨,为区内深部找矿提供了重要的参考依据。文章通过流体包裹体研究对大白阳金矿成矿温度及成矿深度进行计算,利用矿物压力计对矿区周边岩体侵位深度进行估算。流体包裹体研究结果显示大白阳金矿成矿温度160~220℃、盐度w（NaCl_eq）=9%~15%,密度0.78~0.97 g/cm³、压力46.3~104.6 MPa,成矿流体主要属于NaCl-H₂O体系,成矿过程中流体温度和盐度都呈现明显的降低趋势。采用黑云母压力计,针对大白阳金矿周边谷嘴子、杨家营以及前坝口花岗质岩体的侵位深度进行估算,并对大白阳金矿自形成以来的剥蚀保存情况进行了探讨,估算结果显示,谷嘴子岩体（236.0 Ma）成岩深度7.02 km、杨家营岩体（138.6 Ma）成岩深度2.66 km、前坝口岩体（140.2 Ma）成岩深度3.13 km。结合前人的裂变径迹结果,认为张宣地区自中生代以来剥蚀速率为0.022~0.029 km/Ma,剥蚀量为3 km。按照前述成矿压力46.3~104.6 MPa换算,大白阳金矿成矿深度6.93 km,剥蚀量小于矿床成矿深度,说明该矿深部仍具有良好的找矿前景。     

金活动态提取剂提取-电感耦合等离子体质谱法测定深穿透地球化学样品中的金

金的地球化学勘查基于金的准确测定,地球化学样品中金含量通常处于ng/g水平,需先进行分离富集,再采用电感耦合等离子体质谱法(ICP-MS)或石墨炉原子吸收光谱法(GFAAS)进行测定。当前,隐伏矿床勘查是地球化学探测技术的发展前沿,金活动态提取技术是寻找隐伏金矿的有效手段之一。相比于全量分析,金的活动态含量更低,需要解决选择性提取、高效预富集与准确测定等一系列难题。本文采用柠檬酸铵与土壤中黏土矿物及次生矿物作用促使吸附和可交换组分的金进入提取液,以硫脲和硫代硫酸钠络合金使活动态金向提取液中扩散,达到选择性提取的目的,建立了提取液中金的预富集及ICP-MS测定方法。实验确定的分析条件为:采用5g/L柠檬酸铵-2g/L硫脲-5g/L硫代硫酸钠为提取剂,提取时间24h,在酸性硫脲介质下用活性炭富集金,金吸附率可达89.6%～109.2%,灰化解吸温度为650～700℃。本方法检出限为0.05ng/g,相对标准偏差(RSD)为9.4%～10.2%,加标回收率为91.2%～93.4%。与已报道的硫酸铁-硫脲-硫代硫酸钠溶液提取再GFAAS测定的方法相比,本方法具有检出限低、测试线性范围宽、测试速度快的优势;应用于森林覆盖区黑龙江东安金矿区地球化学探测试验,金活动态异常与隐伏金矿位置一致。     

LA-ICP-MS in situ analyses of the pyrites in Dongyang gold deposit,Southeast China: Implications to the gold mineralization

The Dongyang gold deposit is a newly discovered epithermal deposit in Fujian Province, Southeast China, along the Circum-Pacific metallogenic belt. Herewith, the authors present mineralogical, scanning electron microscope, and laser ablation inductively coupled clasma mass spectrometry analysis to reveal the relations between Au and Te, As, S, Fe, etc., and discuss the gold precipitation process. The pyrites in this deposit are Fe-deficient, and are enriched in Te and As. The authors infer that As was mainly in form of As-complexes, and Te-Au-Ag inclusions/solid solution also exsits in the Py I. Along with the depletion of Te and As, they were less active chemically in the Py II, and Au may be incorporated into As-rich and Fe-deficient surface sites by chemisorption onto As-rich growth surfaces. Because of the incorporation of new fluid, Te and As became the most active chemically in the Py III, which was the main elements precipitation stage, and As dominantly substituted for S in the lattice of pyrite, due to the more reducing condition. The authors propose Au was in form of invisible gold, and the incorporation of gold can be considered as post-pyrite event, while the Au-bearing minerals were result of post incorporation of gold in arsenian pyrite.     

Gravity and magnetic field characteristics and regional ore prospecting of the Yili ancient continent,West Tianshan,Xinjiang Uygur Autonomous Region,China

Gold, iron, copper, lead-zinc and other mineral exploration in West Tianshan, Xinjiang Uygur Autonomous Region, has made remarkable progress in recent years. However, due to the dispute on the tectonic division of West Tianshan, the ore-controlling factors and the regional metallogenic laws are controversial. The authors analyze regional gravity data and notice that the high-value region corresponds to the Yili ancient continent, thus the southeastern boundary of the Yili ancient continent is delineated. Comparative analysis of gravity, aeromagnetic and geologic data reveals that the Tulasu basin, where some medium to large epithermal gold deposits locate, lies above the Yili ancient continent; the Yili Carboniferous-Permian rift extends in E-W direction, numbers of copper deposits have been found in the mid-west section of the rift which lies above the Yili ancient continent, whereas few copper deposits have been discovered in the east section which is outside the Yili ancient continent. Accordingly, the Yili ancient continent may he rich in gold, copper and other metal elements; the metal-bearing hydrothermal solution moves up with the activity of magmatism, and deposits in the favorable places (the Tulasu basin and the Yili Carboniferous-Permian rift), forming numerous small and medium gold, copper deposits, as well as some large and super-large gold deposits. Therefore, the tectonic-magmatic hydrothermal zone above the Yili ancient continent should be the prospective area for epithermal gold and copper polymetallic deposits.     

内蒙古察哈尔右翼中旗大清河金矿地质特征及成因探讨

内蒙古察哈尔右翼中旗大清河金矿床类型属于变质-热液型中低温矿床,产出于太古代乌拉山群,矿石类型主要为含金硫化物石英脉和蚀变岩型金矿石。本次工作总结了矿体地质特征及分布规律;结合相关元素测试分析及相邻典型矿床地质特征,综合研究认为区内金元素的物源区主要为太古代乌拉山群,其次为岩浆岩;矿床整体形成于古生代末期至二叠纪中晚期,早期成岩成矿作用形成原始矿床或初始矿源层,晚期受二叠纪中晚期多期次热液流体影响,萃取、活化、迁移金元素形成含金热液流体,并在有利成矿部位充填沉淀,成矿严格受二叠纪花岗闪长岩中NE向及NEE向压扭性构造裂隙控制,矿体具有隐伏再现和雁列式侧伏展布特征。     

玲珑金矿黄铁矿热电性与微量元素标型及深部金矿化评价

在前人对玲珑金矿矿体浅部的研究基础之上,通过对矿体深部黄铁矿的热电性测试与分析,得出：西山矿区380m—90m中段,黄铁矿导型以P—N型（空穴型-电子型导电）为主;东山矿区50m—850m标高范围内,黄铁矿导型以P—N或N—P（电子型-空穴型导电）混合型为主。东、西山矿区的P型出现率在垂向上呈高-低-高的韵律式脉冲变化...     

滇西北衙金矿蚀变斑岩中的流体包裹体研究

位于爆破角砾岩筒边缘的接触带矿化斑岩中早期流体包裹体以CO2-H2O包裹体为主,而岩体内无或弱矿化斑岩中对应的流体包裹体以高盐度H2O-NaCl包裹体为主,反映来源于富碱岩浆的流体在它的早期阶段即分异出富碳相和盐水相,富碳相位于流体的外层,成矿元素主要在富碳相中迁移。因此,外接触带及其附近的围岩是成矿的有利部位。岩体内部蚀变岩石样品石英斑晶中的次生流体包裹体可大致划分为4个阶段。根据显微测温结果、形成温度和压力的估算及均一温度-盐度关系,结合H2O-NaCl体系P-T投影图,包裹体的4个阶段反映了环境条件的变化过程及相关的地质过程。