A summary of sulfur dioxide emission rate measuremnts from Guatemalan volcanoes

Measurements of the sulfur dioxide (SO₂) emission rate from three Guatemalan volcanoes provide data which are consistent with theoretical and laboratory studies of eruptive and shallow magma chamber processes. In particular, unerupted magma makes a major contribution to the measured SO₂ emission rates at Santiaguito, a continuously erupting dacitic volcanic dome. Varying shallow magma convection rates can explain the variations in SO₂ emission rates at Santiaguito. At Fuego, a basaltic volcano currently in repose, SO₂ emission rate measurements are consistent with a high level magma body that is crystallizing and releasing volatiles. At Pacaya, a continuously erupting basaltic volcano, recent SO₂ emission rate measurements support laboratory simulation studies of strombolian eruptions; these studies indicate that the majority of gas escapes during eruptions and little gas escapes between eruptions.Average SO₂ emission rates over the last 20 years for Santiaguito, Fuego and Pacaya are 80, 160 and 260 Mg/d, respectively. On a global scale, these three volcanoes account for 1% of the annual global volcanic output of SO₂. Santiaguito and Pacaya, together, emit 6% of the total annual SO₂ emitted by continuously erupting volcanoes.Even though SO₂ measurements at these volcanoes have been made infrequently and by different investigators, the collective data help to establish a useful baseline by which to judge future changes. A more complete record of SO₂ emission rates from these volcanoes could lead to a better understanding of their eruption mechanisms and reduce the impact of their future eruptions on Guatemalan society.     

补偿校正系数XRFS法七个主量元素测定的探讨

用补偿校正系数法校正X荧光光谱分析中基体效应的影响,对岩石中七个主量元素的测定结果表明该方法准确、可靠。     

Tensile strength of rock by the double-punch method

Summary This paper presents an experimental study of the newly developed double-punch test method for determination of the tensile strength of rocks. The method for preparation of test specimens and test procedure is reported and discussed. Comparisons of tensile strength determined from double-punch and split-cylinder tests are also presented.With 5 Figures     

卡尼期湿润幕：气候- 环境变化与海洋生态效应研究新进展

晚三叠世卡尼期湿润幕（Carnian Pluvial Episode, CPE）是近年来最受瞩目的地质事件之一。此次事件以卡尼中期全球不同纬度环境湿度显著上升为主要标志。CPE的发生不仅对全球各地沉积格局产生重大改变，也对三叠纪生物演化产生了深远影响。海洋生物群在跨越CPE期间发生了不同程度的灭绝与演替，大部分海洋无脊椎动物和部分脊椎动物的多样性在CPE之后出现明显的降低，著名的关岭生物群也受到了CPE的明显影响，并开始显现出危机。CPE之后，恐龙类群开始逐步占据陆地生态的主导地位，早中生代和现代生物的先祖开始在这一时期纷纷出现。CPE的发生揭开了现生生物演化史新的一页，并最终开创了早中生代和现生生物黎明。有关CPE的触发机制主要包括以下2个方面：① 晚三叠世巨型季风环流在卡尼期达到鼎盛并区域上影响了大气降水量；② 板块活动造成大规模火山喷发引发全球气候扰动。由于上述2种解释还未能与我国其他地质记录较好匹配，因而CPE在特提斯东缘的发生次序和发展过程并不清晰。这其中，对CPE触发机制的探讨，需要将全球板块变化与古气候模拟纳入其研究范畴。不同于晚二叠世生物大灭绝后生物类群缓慢重启和生态逐步复苏，CPE期间的生物演化与革新在短时间内促成了现代生物类群的形成。在我国，上三叠统卡尼阶分布广泛、发育齐全，且保存有各门类丰富的动植物化石，是开展卡尼期气候- 环境变化与生态效应研究的重要场所。然而目前国内有关CPE研究还十分有限，一些基础的地质工作仍然有待开展。位于特提斯东缘的我国地质记录有助于深刻理解CPE过程和环境- 生物协同演化关系，尤其在现代生物多样性起源和当代生态系统结构成型的研究过程中需要提供更多中国的对比方案。     

Cold seep deposits of Beauvoisin (Oxfordian; southeastern France) and Marmorito (Miocene; northern Italy): microbially induced authigenic carbonates

The relation of two well-known ancient carbonate deposits to hydrocarbon seepage was confirmed by this study. Archaea are found to be associated with the formation of Oxfordian seep carbonates from Beauvoisin and with a Miocene limestone from Marmorito ("tube-worm limestone"). Carbonates formed due to a mediation by archaea exhibit extremely positive or extremely negative δ¹³C_carbonate values, respectively. Highly positive values (+15‰) reflect the use of ¹³C-enriched CO₂ produced by methanogenesis. Low δ¹³C values of the Marmorito carbonates (–30‰) indicate the oxidation of seepage-derived hydrocarbons. Likewise, the δ¹³C content of specific tail-to-tail linked isoprenoids, biomarkers for archaea, was found to be strikingly depleted in these samples (as low as –115‰). The isotopic signatures corroborate that archaea were involved in the cycling of seepage-derived organic carbon at the ancient localities. Another Miocene limestone ("Marmorito limestone") shows a strong imprint of methanotrophic bacteria as indicated by δ¹³C values of carbonate as low as –40‰ and biomarker evidence. Epifluorescence microscopy and field-emission scanning electron microscopy revealed that bacterial biofilms were involved in carbonate aggregation. In addition to lucinid bivalves previously reported from both localities, we infer that sponges from Beauvoisin and tube worms from Marmorito depended on chemosynthesis as well. Low δ¹³C values of nodules related to sponge taphonomy (–27‰) indicate that sponges might have been linked to an enhanced hydrocarbon oxidation. Tube worm fossils from Marmorito closely resemble chemosynthetic pogonophoran tube worms from Recent cold seeps and are embedded in isotopically light carbonate (δ¹³C –30‰). Received: 13 October 1998 / Accepted: 5 February 1999     

Effects of groundwater flow on mineral diagenesis, with emphasis on carbonate aquifers

 This article provides a critical synopsis of the effects of groundwater flow on mineral diagenesis. Emphasis is placed on those aspects and processes that change porosity and permeability in carbonate aquifers, because they are of particular importance to human societies as sources of supplies of water for human consumption (drinking, irrigation) and of crude oil and natural gas. Diagenetic settings in carbonates as well as clastics are generally ill defined. This paper proposes a new comprehensive classification of diagenetic settings into near-surface, shallow-, intermediate-, and deep-burial diagenetic settings; hydrocarbon-contaminated plumes; and fractures. These settings are defined on the basis of mineralogy, petroleum, hydrogeochemistry, and hydrogeology. This classification is applicable to all sedimentary basins. Diagenesis is governed by various intrinsic and extrinsic factors that include thermodynamic and kinetic constraints, as well as microstructural factors that may override the others. These factors govern diagenetic processes, such as dissolution, compaction, recrystallization, replacement, and sulfate–hydrocarbon redox-reactions. Processes such as cementation, dissolution, and dolomitization require significant flow of groundwater driven by an externally imposed hydraulic gradient. Other processes, such as stylolitization and thermochemical sulfate reduction, commonly take place without significant groundwater flow in hydrologically nearly or completely stagnant systems that are geochemically "closed." Two major effects of groundwater flow on mineral diagenesis are enhancement and reduction of porosity and permeability, although groundwater flow can also leave these rock properties essentially unchanged. In extreme cases, an aquifer or hydrocarbon reservoir rock can have highly enhanced porosity and permeability due to extensive mineral dissolution, or it can be plugged up due to extensive mineral precipitation. Received, April 1998 · Revised, July 1998 · Accepted, September 1998     

Palynofacies investigation of Callovian (Middle Jurassic) sediments from DSDP Site 534, Blake-Bahama Basin,Western Central Atlantic

During the extension of Deep Sea Drilling Project (DSDP) Leg 76 a new and previously unpenetrated lithological unit composed mainly of claystones was cored above basalt basement at Site 534 in the Blake-Bahama Basin. The Callovian part of the new unit contains interbedded ‘black shales’ which were hitherto unexpected in this part of the section. This Paper presents a brief palynological examination of lithofacies-kerogen relationships in these sediments and shows that their organic content is almost entirely a function of the re-deposition of terrestial and marine organic matter versus the ambient redox conditions of the depositional environment. Allochthonous organic matter inputs are highest in the interbedded turbidites and decline progressively toward the pelagic black shales in which marine organic matter is comparatively well preserved. The significance of various kerogen and palynomorph indices are discussed. The study emphasizes the absolute necessity for sedimentologically-aware sampling in all palynological and geochemical work on lithologically heterogeneous sequences.     

Characteristics of melt inclusions in skarn minerals from Fe,Cu(Au) and Au(Cu) ore deposits in the region from Daye to Jiujiang

The skarns and skarn deposits are widely distributed at home and abroad. The skarn deposits include many kinds of ores and higher ore grade. Some of them are broad in scale. Scientists of ore deposits from different countries have paid and are paying grea…     

Chemostratigraphy of Lago Albano sediments (Central Italy):geochemical evidence of palaeoenvironmental changes in lateQuaternary

The results of the geochemical investigation on bulk sediment fromthree cores collected in Albano crater lake (Central Italy) are reported, andthe main markers of the palaeoenvironmental changes in the last 26ka are discussed. The sediment of Lago Albano consists of greysilt and mud, and is made of volcanogenic, calcareous, siliceous and organicmaterial. Some tephra layers provide a chronological framework for thesequence. The chemical features of the sediments are strongly impacted by theAlban Hills volcanism (Roman volcanic area), but there are also strong changesof organic/inorganic matter ratios, owing to variations in biologicalproductivity and terrigeous supply from the catchment. Six chemostratigraphiczones record the main steps of the transition from the cold and dry climate ofGlacial Maximum to the warmer and more humid Holocene climate. The most usefulgeochemical indices are: biogenic silica, CO₂, Br and organiccontent (OM) for biological productivity; Al, Y, CIA (Chemical Index ofAlteration), Al/Rb, Ti/Zr and Y/Al ratios for terrigenous clasticmaterial; OM/Al ratio for organic/terrigenous ratio; S/Fe andMo/Fe ratios and Authigenic U for redox diagenetic conditions of the lakesediment. The geochemical records agree rather well with those of thelithological and paleomagnetic studies, and despite the information obtainedare less detailed than those acquired by the study of biological remains, thepalaeoenvironmental significance inferred is consistent. A comparison of thechemostratigraphic results of Lago Albano with those obtained on coevalsediments from Central and Southern Italy lakes supports the role of thegeochemical investigation as important complement to more sophisticatedtechniques in the palaeoenvironmental reconstructions.     

重庆合川自流井组植物化石的发现

描述了发现于合川自流井组东岳庙段的三种似木贼植物化石,即Equisetites flus Harris,E．1ateralis(Phillips)和E．columnaris(Brongn．)Phillips。标本保存良好,依据植物和双壳类化石的分布关系,提出自流井组东岳庙段的时代为早侏罗世晚期至中侏罗世早期。同时,分析了东岳庙段的岩相特征和沉积环境。