昌宁-孟连结合带牛井山早古生代埃达克岩锆石U-Pb年龄、岩石成因及其地质意义

昌宁-孟连结合带是西南三江地区重要的古特提斯结合带,本文报道该带牛井山蛇绿混杂岩带内的早古生代英云闪长岩的锆石U-Pb年龄和Hf同位素、全岩地球化学特征,探讨其岩石成因,揭示早古生代(原)特提斯演化过程和恢复古地理格局。利用LA-ICP-MS对英云闪长岩进行锆石U-Pb定年,获得~(206)Pb/~(238)U加权平均年龄为468±2Ma(MSWD=1.4,n=22),代表岩浆岩结晶时代。对锆石进行原位微区Hf同位素分析获得锆石ε_(Hf)(t)=+1.6~+2.8。牛井山英云闪长岩具有高的SiO_2(61.6%~67.16%),Al_2O_3(15.4%~17.64%),Na_2O(2.93%~3.25%)含量,高的Na_2O/K_2O(3.9~5.4)比值。微量元素具有高Sr(469×10~(-6)~533×10~(-6)),低Yb(0.66×10~(-6)~1.22×10~(-6))和Y(8.5×10~(-6)~16.3×10~(-6)),Eu正异常(1.01~1.37)的特征。此外,在同等SiO 2条件下,还具有相对高的Mg~#和MgO(Mg~#=50~51,MgO=2.84%~3.58%)。这些特征表明英云闪长岩具有高镁埃达克岩的性质。岩石成因研究表明牛井山高镁埃达克岩很可能是俯冲洋壳加上部分大洋沉积物部分熔融并与上覆地幔橄榄岩反应的产物。早古生代洋壳俯冲成因的埃达克岩的发现证明昌宁-孟连特提斯洋演化历史可追溯至约468Ma。昌宁-孟连结合带早古生代岩浆作用与龙木错-双湖结合带早古生代洋壳残片的时代一致、构造属性相似,我们认为昌宁-孟连结合带与木错-双湖结合带可对比,它们代表了一个统一的古生代特提斯大洋残余。     

扬子西缘乡城-丽江结合带燕山期斑岩Mo多金属矿床成矿系统

位于扬子陆块西缘与西南三江造山带结合部位的乡城-丽江地区,北起四川乡城经云南格咱南至丽江地区,在印支期斑岩铜矿带上新发现叠加了燕山期斑岩Mo多金属成矿作用,形成乡城-丽江斑岩Mo矿带。受印支期古特提斯洋盆闭合后地壳缩短与加厚的影响,燕山晚期下地壳发生拆沉作用,导致后碰撞型花岗质岩浆侵位,发育了Mo多金属成矿作用,并构成斑岩成矿系统。岩石地球化学特征表明,燕山晚期含矿斑岩具高硅(SiO_2=66.29%~79.36%)、高碱(K_2O+Na_2O=5.07%~9.24%)、富钾(K_2O/Na_2O=0.71~2.13)的特点,属于高钾钙碱性岩石系列。岩石富集轻稀土元素(LREE),具有负δEu异常;微量元素具富集大离子亲石元素K、U、Th、Rb,亏损高场强元素Nb、Ta、P、Ti的特征;大离子亲石元素的富集和Nb、Ta等高场强元素的亏损,表明形成这些岩体的岩浆主要来自地壳,具有造山带花岗岩的地球化学特征。区内代表性含矿斑岩相似的地球化学组成及分布特征表明,乡城-丽江结合带燕山晚期的成矿斑岩是由同源岩浆分异演化而来。成矿系统的分析表明,燕山晚期主要含矿斑岩成矿物质以壳源为主,但具有少量地幔物质的加入,成岩成矿物质来源具有相似或一致的源区特征。在成矿元素的组合上,由成矿斑岩体向外带表现出W、Mo→W、Mo、Cu→Pb、Zn、Ag的演化趋势。研究表明,本区燕山晚期花岗岩浆的侵入及Mo多金属成矿作用并不是独立或个别的成矿事件,而是纵跨义敦岛弧、甘孜-理塘结合带及扬子西缘的带状成矿活动,属于区内与燕山晚期岩浆侵入作用相关的统一斑岩成矿系统。     

延庆千家店地区硅化木赋存层位及形成时代分析

北京延庆千家店土城子组中的硅化木自发现以来,得到了众多学者的关注,但关于硅化木的赋存层位和形成时代一直未有定论,目前主流观点认为硅化木广泛发育于土城子组一段和二段的下部,关于其形成时代则自侏罗纪早期至白垩纪早期的论述均有,这种争论显然不利于木化石的保护、科普和进一步深化认识。在千家店土城子组进行的考察结果展现出与前人观点不同的线索。实地考察、剖面测量和年龄测试结果显示:原位埋藏硅化木形成时代应为晚侏罗世早期,赋存层位为土城子组一段下部,而土城子组二段下部的沉积特征反应出当时水位频繁升降,水体能量剧烈变化,火山活动暂时陷入沉寂的沉积环境,较难满足形成木化石的基本要求。     

Late mesozoic A-Type granitoids in se China and paleo-pacific plate subduction and slab rollback北大核心CSCD

This study has reviewed the distribution and pedogenesis of late Mesozoic A-Type granitoids in SE China. These A-Type granitoids belong to four belts ( S Jiangxi-SW Fujian belt, Xiang-Gui-Yue belt, Can-Hang belt and coastal belt) due to their temporal-spatial distribution. Based on the comparative analysis of chronology, geochemistry and magmatic association, this study has discussed the formation of A-Type granitoids and the subduction and slab rollback process of paleo-Pacific plate beneath SE China.     

Origin of organic matter and paleoenvironment conditions of the Late Jurassic organic-rich shales from shabwah sub-basin (western Yemen): Constraints from petrology and biological markers

Late Jurassic organic-rich shales from Shabwah sub-basin of western Yemen were analysed based on a combined investigations of organic geochemistry and petrology to define the origin, type of organic matter and the paleoenvironment conditions during deposition. The organic-rich shales have high total sulphur content values in the range of 1.49–4.92 wt. %, and excellent source rock potential is expected based on the high values of TOC (>7%), high extractable organic matter content and hydrocarbon yield exceeding 7000 ppm. The high total sulphur content and its relation with high organic carbon content indicate that the Late Jurassic organic-rich shales of the Shabwah sub-basin were deposited in a marine environment under suboxic-anoxic conditions. This has been evidenced from kerogen microscopy and their biomarker distributions. The kerogen microscopy investigation indicated that the Late Jurassic organic-rich shales contain an abundant liptinitic organic matter (i.e., alginite, structureless (amorphous organic matters)). The presence of alginite with morphology similar to the lamalginite alga and amorphous organic matter in these shale samples, further suggests a marine origin. The biomarker distributions also provide evidence for a major contribution by aquatic algae and microorganisms with a minor terrigenous organic matter input. The biomarkers are characterized by unimodal distribution of n-alkanes, low acyclic isoprenoids compared to normal alkanes, relatively high tricyclic terpanes compared to tetracyclic terpanes, and high proportion of C₂₇ and C₂₉ regular steranes compared to C₂₈ regular sterane. Moreover, the suboxic to anoxic bottom water conditions as evidenced in these Late Jurassic shales is also supported based on relatively low pristane/phytane (Pr/Ph) ratios in the range of 0.80–1.14. Therefore, it is envisaged here that the high content of organic matter (TOC > 7 wt.%) in the analysed Late Jurassic shales is attributed to good organic matter (OM) preservation under suboxic to anoxic bottom water conditions during deposition.     

A late Holocene winter monsoon record inferred from the palaeo-aeolian sand dune in the southeastern Mu Us Desert, northern China

The variation of the Asian winter monsoonal strength has seriously affected the climate and environmental conditions in the Asian monsoonal region, and even in marginal islands and the ocean in the East Asian region. However, relevant understanding remains unclear due to the lack of suitable geological materials and effective proxies in the key study areas. Here, we present a grain-size record derived from the palaeo-aeolian sand dune in the southeastern Mu Us Desert, together with other proxies and OSL dating, which reflect a relatively detailed history of the winter monsoon and abrupt environmental events during the past 4.2 ka. Our grain-size standard deviation model indicated that >224 μm content can be considered as an indicator of the intensity of Asian winter monsoon, and it shows declined around 4.2-2.1 ka, enhanced but unstable in 2.1-0.9 ka, and obviously stronger since then. In addition, several typical climate events were also documented, forced by the periodic variation of winter monsoonal intensity. These include the cold intervals of 4.2, 2.8, 1.4 ka, and the Little Ice Age (LIA), and relatively warm sub-phases around 3.0, 2.1, 1.8 ka, and the Medieval Warm Period (MWP), which were roughly accordant with the records of the aeolian materials, peat, stalagmites, ice cores, and sea sediments in various latitudes of the Northern Hemisphere. Combined with the previous progresses of the Asian summer monsoon, we preliminarily confirmed a millennial-scale anti-correlation of Asian winter and summer monsoons in the Late Holocene epoch. This study suggests that the evolution of the palaeo-aeolian sand dune has the potential for comprehending the history of Asian monsoon across the desert regions of the modern Asian monsoonal margin in northern China.     

全球早古生代造山带(Ⅱ):俯冲-增生型造山

全球早古生代增生造山带极其发育,主要分布在古亚洲洋南北两侧、Iaeptus洋南侧、Rheic洋北侧和环冈瓦纳大陆地带,其中原特提斯洋封闭的产物主要发育在中国境内,大量微陆块在早古生代可能都是冈瓦纳北缘的俯冲-增生带中的重要组成。增生造山带中组成复杂,具有沟-弧-盆体系、海山、洋壳等残存记录,尤以榴辉岩发育为特征,增生造山成为早古生代古亚洲洋和特提斯洋构造体系的显著独特特征。早古生代末中亚早古生代造山带多为微陆块增生造山阶段,沟-弧-盆体系发育,具有增生-软碰撞造山的特点,发生时限较晚,为早古生代末;原特提斯洋中的西昆仑、东昆仑、柴达木北缘、南阿尔金、北阿尔金与北祁连、北秦岭等围限或夹杂的微陆块在早古生代具有相同的增生造山过程,整体是向南俯冲线性增生到冈瓦纳大陆北缘,现今多次重复是早古生代弯山构造所致。400 Ma左右,南部古特提斯洋和北部勉略带的打开,导致其北漂,经复杂变形改造,它们现今为一巨型弯山构造横亘在中国中部,对中国构造格局影响最为重要。     

西藏改则县多不扎地区上侏罗统对望山组的建立及意义

对望山组是发育在羌南板块南缘的一套岩石组合,以安山岩、流纹岩、玄武质凝灰岩为主,有少量的玄武安山岩夹层,具有明显的岩浆喷出相和沉积相韵律分布的特点。利用LA-ICP-MS同位素定年技术对对望山组安山岩中的锆石进行了U-Pb同位素测年,获得锆石的~(206)Pb/~(238)U年龄加权平均值为150.5±0.6Ma,表明对望山组的形成时代为晚侏罗世中晚期,在详细剖面测制和区域对比的基础上建立了对望山组。对望山组的建立对完善班公湖-怒江缝合带的地层系统、探讨班公湖-怒江洋的晚侏罗世构造演化具有重要的地质意义。     

全球早古生代造山带(Ⅲ):华南陆内造山

华南早古生代加里东期变形、岩浆、沉积等特征表现为陆内造山带特征。通过对加里东期角度不整合分布、褶皱、断裂逆冲极性等特征的分析,发现大明山、大瑶山地区EW轴向的寒武系褶皱不对称性和角度不整合空间上向北的拓展变新规律,指示晚寒武世—早奥陶世的由南向北推覆挤压可能是云开、滇—桂北越地块依次向北推挤的结果;从全球背景看,可能和华南陆块南部一些地块与冈瓦纳大陆北缘依次碰撞接触导致的远程陆内效应有关。然而,湘赣边境、桂北元宝山及越城岭地区的早古生代NE向褶皱不对称性指示向西拓展,这可能是由于华夏地块与扬子地块在晚奥陶世—早志留世沿郴州临武断裂陆内收缩挤压的结果,其全球背景可能和华南陆块顺时针旋转与冈瓦纳全面碰撞相关。总之,加里东期构造运动总体由南向北、由东向西渐新,变形强度由强到弱的特征,反映华南陆内碰撞造山事件的根本原因是其与冈瓦纳北缘碰撞的远程效应。450~420 Ma华南已经属于冈瓦纳北缘一部分。     

全球早古生代造山带(Ⅳ):板块重建与Carolina超大陆

古元古代与显生宙的板块构造特征和旋回演化过程具有明显区别,反映出地质记录为两种不同的板块构造体制。早古生代为这两个时期的过渡阶段,其构造过程研究与板块重建是地球板块构造旋回机制和周期分析的关键。本文采用综合集成的方法,在总结对比罗迪尼亚超大陆裂解以来全球早古生代主要碰撞造山带的地质事件基础上,分析早古生代碰撞造山带的演化特征,总结出与冈瓦纳大陆拼合、劳俄大陆拼合、古中华陆块群增生相关的7期碰撞-增生造山事件群:Brasiliano、东非、Kuunga、东亚与原特提斯洋和古亚洲洋演化相关的的加里东期造山事件、经典加里东造山、中欧加里东造山、Appalachian造山。再在这7期造山事件群基础上,结合古地磁、古生物、古地理等资料,重建了新元古代-早古生代末全球板块的拼合过程:罗迪尼亚超大陆从新元古代的~950 Ma开始经历了3个阶段裂解,此时存在泛大洋、莫桑比克洋和古太平洋3个大洋,随后615~560 Ma Iapetus洋打开,~560 Ma波罗的陆块与西冈瓦纳裂离导致狭窄的Ran洋打开;~540 Ma南半球Brasiliano、东非和Kuunga造山运动导致冈瓦纳大陆分阶段最终完成拼贴;~500 Ma冈瓦纳大陆北缘西段的微陆块群局部向北裂离,导致Rheic洋和Tornquist洋打开,并于~420 Ma随经典加里东造山带和中欧缝合带形成导致Iapetus洋闭合,此时斯瓦尔巴特和英国可能位于格陵兰地盾东南缘,同时冈瓦纳大陆北缘东段华北为代表的微陆块基本拼合在冈瓦纳大陆北缘;此外,虽然425 Ma西伯利亚板块有远离聚合了的劳俄大陆的趋势,但晚奥陶世-早泥盆世南美和北美板块靠近,北美板块与环冈瓦纳北缘西段的地体拼合碰撞。在大约400 Ma时,南、北美洲的混合生物群和古地理重建显示两者非常接近,因此,推测此时存在一个初始的逐步稳定的超大陆的可能,本文称为Carolina超大陆,因为Carolina造山带是这个超大陆最终拼合的地带。并据此判断超大陆旋回为7亿年。