内蒙古巴林右旗晚二叠世埃达克质火山岩特征及其地质意义

内蒙古东南部巴林右旗地区发育晚二叠世埃达克质火山岩,岩石组合为安山岩、粗安岩、英安岩及辉石安山岩,其LA-ICP-MS锆石U-Pb测年结果为256.7±2.7Ma,指示其形成于晚二叠世。地球化学特征显示,该套火山岩属准铝质-弱铝质中钾钙碱性岩石系列,具富Si(SiO_256%)、高Al(Al_2O_315%)、富Na、贫K、高Sr、低Yb和Y等特征,Na_2O/K_2O值为2.33~3.90,Mg~#值为35.3~60.8;稀土元素总量为96.69×10~(-6)~192.4×10~(-6)、轻重稀土元素分馏较明显((La/Yb)_N值为6.27~13.82),具正的Eu(δEu=1~1.67)异常,在原始地幔标准化蛛网图中,富集大离子亲石元素Rb、Ba、U,亏损高场强元素Nb、Ta,为O型(大洋型)埃达克质火山岩地球化学特征。综合区域资料,巴林右旗埃达克质火山岩是残留在地幔中的古亚洲洋残余洋壳部分熔融并受到地幔橄榄岩混染形成的,暗示晚二叠世存在古亚洲洋向华北板块俯冲消亡事件。     

A highstand oolitic sequence and associated facies from a Late Triassic lake basin, south-west England

High energy, lake‐shoreline carbonate sequences are rarely documented in the geological record. However, one example occurs in the Upper Triassic Mercia Mudstone Group (MMG) of southern Britain. The MMG is one of a number of thick, non‐fossiliferous mudstone deposits associated with North Atlantic Mesozoic rift basins. The origin of the MMG mudstones is the subject of current debate, with marine, playa‐lacustrine and alluvial–aeolian models having been proposed. Shoreline features have been documented from the northern margin of the basin, but the rarity of such features elsewhere in the MMG has led many workers to doubt a lacustrine origin for the mudstones. Wave‐dominated, lake‐shoreline deposits have been recognized in several sections from the southern basin margin in the Clevedon area of the Bristol Channel in south‐west England. These deposits provide evidence for the development of a sizeable perennial to semi‐perennial hypersaline lake in which the MMG mudstones accumulated. Shoreline sediments overlie alluvial stream and sheet‐flood deposits, and pass from transgressive gravel–conglomerate beach units with bioclasts, influenced by shore‐normal waves (deposited under semi‐humid conditions), to lower gradient, highstand oolitic sands affected by more varied wave approach (deposited under progressively more arid conditions), which culminated in lowstand, oolitic strand‐plain deposits overlain by a playa‐mudflat unit. Shoreline deposits record a simple shallowing‐upward transgressive–highstand–lowstand sequence. However, a change from a reflective (transgressive) to dissipative (highstand) shoreline is believed to represent a climatically induced change in prevailing wind direction. Shoreline features recognized in the MMG are similar to those of recent playa‐lacustrine basins of the western United States. Ooids display a variety of size, fracture and dissolution features in addition to beachrock fabrics, suggesting that they were originally composed of radial aragonite, similar to modern ooids from the Great Salt Lake, Utah.     

临汾盆地晚冰期至中全新世黄土-古土壤序列的风化特征及指示的气候意义

了解中国北方晚冰期和全新世时期的气候环境变化及其驱动机制,有助于预测未来气候变化的可能情景。基于黄土高原东南缘临汾盆地的黄土-古土壤剖面,在3个AMS14C年代的支持下,通过粒度、磁化率、土壤有机碳以及地球化学元素等指标,重建了临汾盆地晚冰期至中全新世晚期的气候变化历史。结果表明：宋村沟剖面的黄土和古土壤分别处于初等和中等化学风化阶段,而不同地区风成堆积物的化学风化强度存在明显差异,主要受控于东亚夏季风的区域变化。多指标综合分析表明,晚冰期以来临汾盆地的气候演变经历了4个阶段：晚冰期东亚冬季风较强,气候干冷;早全新世东亚夏季风强化,气候向暖湿转变;早中全新世东亚夏季风达到峰值,为最暖湿的适宜期;中全新世晚期东亚夏季风减弱,气候再次转向干冷;临汾盆地的气候变化主要受控于北半球太阳辐射强度和冰量的变化。     

Composition, porosity, and reservoir potential of the Middle Jurassic Kashafrud Formation, northeast Iran

In the Kopet-Dagh Basin of Iran, deep-sea sandstones and shales of the Middle Jurassic Kashafrud Formation are disconformably overlain by hydrocarbon-bearing carbonates of Upper Jurassic and Cretaceous age. To explore the reservoir potential of the sandstones, we studied their burial history using more than 500 thin sections, supplemented by heavy mineral analysis, microprobe analysis, porosity and permeability determination, and vitrinite reflectance.The sandstones are arkosic and lithic arenites, rich in sedimentary and volcanic rock fragments. Quartz overgrowths and pore-filling carbonate cements (calcite, dolomite, siderite and ankerite) occluded most of the porosity during early to deep burial, assisted by early compaction that improved packing and fractured quartz grains. Iron oxides are prominent as alteration products of framework grains, probably reflecting source-area weathering prior to deposition, and locally as pore fills. Minor cements include pore-filling clays, pyrite, authigenic albite and K-feldspar, and barite. Existing porosity is secondary, resulting largely from dissolution of feldspars, micas, and rock fragments, with some fracture porosity. Porosity and permeability of six samples averages 3.2% and 0.0023 mD, respectively, and 150 thin-section point counts averaged 2.7% porosity. Reflectance of vitrinite in eight sandstone samples yielded values of 0.64-0.83%, in the early mature to mature stage of hydrocarbon generation, within the oil window.Kashafrud Formation petrographic trends were compared with trends from first-cycle basins elsewhere in the world. Inferred burial conditions accord with the maturation data, suggesting only a moderate thermal regime during burial. Some fractures, iron oxide cements, and dissolution may reflect Cenozoic tectonism and uplift that created the Kopet-Dagh Mountains. The low porosity and permeability levels of Kashafrud Formation sandstones suggest only a modest reservoir potential. For such tight sandstones, fractures may enhance the reservoir potential.     

晚更新世以来山东半岛北部沿海地区的构造抬升速率

根据构造地貌与新构造特征,推算了晚更新世以来山东半岛北部沿海地区的构造抬升速率。结果表明,晚更新世以来不同地段平均构造抬升速率不同,金牛山断裂以东地区为０．１５ｍｍ／ａ,断裂以西地区为０．５０ｍｍ／ａ,龙口盆地２．４万年前后曾发生过幅度７￣９ｍ的断陷。此外,同一地段不时段的抬升速率也有差异,但非常接近平均速率。     

Petroleum retention in the Mandal Formation,Central Graben,Norway

Upper Jurassic organic matter-rich, marine shales of the Mandal Formation have charged major petroleum accumulations in the North Sea Central Graben including the giant Ekofisk field which straddles the graben axis. Recent exploration of marginal basin positions such as the Mandal High area or the Søgne Basin has been less successful, raising the question as to whether charging is an issue, possibly related to high thermal stability of the source organic matter or delayed expulsion from source to carrier.The Mandal Formation is in part a very prolific source rock containing mainly Type II organic matter with <12 wt.-% TOC and HI < 645 mg HC/g TOC but Type III-influenced organofacies are also present. The formation is therefore to varying degrees heterogeneous. Here we show, using geochemical mass balance modelling, that the petroleum expulsion efficiency of the Mandal Formation is relatively low as compared to the Upper Jurassic Draupne Formation, the major source rock in the Viking Graben system. Using maturity series of different initial source quality from structurally distinct regions and encompassing depositional environments from proximal to distal facies, we have examined the relationship between free hydrocarbon retention and organic matter structure. The aromaticity of the original and matured petroleum precursors in the Mandal source rock plays a major role in its gas retention capacity as cross-linked monoaromatic rings act on the outer surface of kerogen as sorptive sites. However, oil retention is a function of both kerogen and involatile bitumen compositions. Slight variations in total petroleum retention capacities within the same kerogen yields suggest that texture of organic matter (e.g. organic porosity) could play a role as well.     

High resolution characterization of a core from the Lower Jurassic Gordondale Member,Western Canada Sedimentary Basin

The Gordondale Member is a hydrocarbon source rock and potential unconventional reservoir that extends across northeastern British Columbia and central-northwestern Alberta. It is an organic-rich, calcareous, fossiliferous mudstone with a median total organic carbon value of 6.0 wt%. A total of 230 samples were collected from approximately 25 m of Gordondale Member core for organic matter analysis using Rock-Eval 6 analysis and organic petrology. Detailed core logging provides sedimentological context for organic matter characterization. The predominant organic material in the samples is solid bitumen and liptinite with lesser zooclast and inertinite. Most kerogen is Type II, autochthonous marine biomass, with minimal dilution by inert organic carbon. Rock-Eval T_max values and random reflectance measurements of solid bitumen indicate the samples are within the oil generation window. Solid bitumen contributes a substantial amount of hydrocarbon potential to the interval. A micro-reservoir structure within the core is produced by thin intervals of impermeable displacive calcite that act as barriers to the upward migration of free hydrocarbons. These free hydrocarbon accumulations could make excellent targets for horizontal wells within the Gordondale Member.     

有孔虫初房特征变化在珠江三角洲晚全新世东亚夏季风降雨研究中的应用

研究中国降雨格局变化对理解东亚夏季风演化意义重大。本文分析了珠江三角洲柱状样ZJK03-Z中浅水底栖有孔虫常见种Rotalidium annectens的平均初房大小、微球型/显球型比值和壳体δ18O值,以及底栖有孔虫组合中瓷质壳的百分含量,探讨它们对由夏季风降雨引起的河口水体盐度变化的响应,得到了珠江三角洲3114—1260a BP季风降雨的强度变化,识别出了这期间14次季风降雨减少的偏干期。与南美洲Cariaco海盆的钛含量记录对比,二者一致的结果表明,珠江三角洲晚全新世的东亚夏季风降雨与热带辐合带(ITCZ)的南北移动密切相关:夏季风降雨减少,对应于ITCZ纬度位置的南移。     

Biomarkers of Middle to Late Jurassic marine sediments from a canonical section: New records from the Yanshiping area,northern Tibet

The Yanshiping section, which includes the Quemo Co, Buqu, Xiali, Suowa and Xueshan Formations (Yanshiping Group) exposes organic-rich Middle to Late Jurassic deposits in the Qiangtang Basin of northern Tibet. The biostratigraphic data, from bivalves, brachiopods as well as dinoflagellate cysts, define a Bajocian to Tithonian age. This study focuses on the biomarkers present in these mudstones and limestones to determine the sources, thermal maturity and depositional environment of the organic matter. Most samples show a clear dominance of short-chain (C₁₅–C₂₀) n-alkanes with a maximum at C₁₉ or C₁₉ with a secondary maximum at C₂₃ except for the sample BP01(22)S1 where the predominant range is C₂₂ to C₂₆ with a maximum at C₂₄, significant CPI and odd-to-even predominance. The hopanoids and steroids suggest that the sources of organic matter were dominated by phytoplankton, especially algae, as the primary source. Furthermore, the Pr/Ph, Pr/nC₁₇ and Ph/nC₁₈, with relatively low values plus high abundance of 17α(H)-hopanes, support deposition in dysoxic to reducing, relatively shallow-water depositional settings, and the presence of gammacerane indicates normal marine salinity and/or water-column stratification. All samples are fairly mature with respect to petroleum generation, a conclusion supported by maturity parameters such as C₃₁ 22S/(22S + 22R) hopanes and C₂₉ ααα20S/(20S + 20R) steranes.