岩矿中稀土元素离子交换分离富集的改进及ICP—AES测定

本文通过对离子交换柱的规格改进,提高了分离效率,加快了分离速度(流速v/(ml·min~(-1)))可达1.0—1.5.结合分离富集条件的选择及ICP-AES测定方法的联用,使本法不分析周期短、所耗试剂省,且检测限低、精密度和准确度较高.经标样检验和矿样实测对比,其结果均令人满意.     

743离子交换快速分离—等离子体光谱法同时测定十五个稀土元素

本文研制了适用于地质样品中15个稀土元素分析的快速方法。样品经碱熔沉淀分离和743阳离子交换树脂分离富集将稀土元素制备成溶液用等离子体光谱法(ICP-AES)进行测量。方法检出限为0.002-0.3μg/g,当稀土元素含量为0.5-80,μg/g时,方法相对标准偏差为15％-2％。本方法经过多年的样品分析考验以及不断的改进和完善,证明方法简便快速,分析数据稳定可靠,能很好地满足地质样品中15个稀土分量测定的要求。     

2005年11月26日九江--瑞昌5.7级地震浅析

2005年11月26日,在江西省九江县与瑞昌市交界处发生5.7级地震,震源深度10km。宏观震中在九江县港口乡。震中烈度Ⅶ度,极震区为北东向的椭圆,烈度分布受瑞昌盆地内地形地貌条件的控制;5.7级地震的最大余震为ML5.3级,序列类型为主震—余震型,余震较丰富,余震区长轴为北西向。此次地震经历了较长期的应力应变积累过程,发生在江西分宜—黄海北部北东向ML≥4.0级地震活动带和湖北西部—江西南昌ML≥3.0级地震活动带的交汇部位,与大区域地震活动性中长期异常相关。     

2005年10月8日巴基斯坦7.8级地震热红外异常

收集了2005年巴基斯坦7.8级地震区Noaa17/AVHRR的2004-2005年的热红外遥感资料,并进行地表温度反演,得到了以震中为中心7°×7°范围的地表温度值。经热红外图像解译与构造关系对比分析,表明热红外解译图像与构造分布具有一致性。震源区地表温度时间序列显示:震前大约3个月内震源区存在明显的热红外异常。     

Characteristics of the Variation of Cross Fault Short-Baseline and Short-Range Leveling in Western Yunnan Earthquake Test Site Before Lijiang M_S7.0 Earthquake

Results of analysis of variation of cross fault short-baseline and short-range leveling in Western Yunnan Earthquake Test Site (WYETS), results show that among five observation stations of cross fault short-baseline and short-range leveling in WYETS before the Lijiang MS7.0 Earthquake occurred in February 1996 only Yongsheng observation station (epicentral distance 82 km) located at Chenghai fault shows great variation about one year before the earthquake. And the nearest observation station, Lijiang (epicentral distance 42 km); presents great coseismic variation, but does not show obvious anomalous variation before the earthquake. There are no significant variations related to the earthquake at the other three observation stations. Two methods are used in analysis of the observed data and some valuable results have been obtained.     

Evolution of the near-infrared in rich galaxy clusters

We present the K -band (2.2 μm) luminosity functions (LFs) of the X-ray-luminous clusters MS1054–0321 ( z  = 0.823), MS0451–0305 ( z  = 0.55), Abell 963 ( z  = 0.206), Abell 665 ( z  = 0.182) and Abell 1795 ( z  = 0.063) down to absolute magnitudes M _K  = −20. Our measurements probe fainter absolute magnitudes than do any previous studies of the near-infrared LFs of clusters. All the clusters are found to have similar LFs within the errors, when the galaxy populations are evolved to redshift z  = 0. It is known that the most massive bound systems in the Universe at all redshifts are X-ray-luminous clusters. Therefore, assuming that the clusters in our sample correspond to a single population seen at different redshifts, the results here imply that not only had the stars in present-day ellipticals in rich clusters formed by z  = 0.8, but that they existed in as luminous galaxies then as they do today.   Additionally, the clusters have K -band LFs which appear to be consistent with the K -band field LF in the range −24 <  M _K  < −22, although the uncertainties in both the field and cluster samples are large.     

2021年5月云南漾濞MS 6.4地震序列发震构造及破裂过程初探

北京时间2021年5月21日21时48分36秒,云南省大理州漾濞县发生M_S 6.4地震。利用云南数字地震台网2021年5月18日至8月22日的震相报告,采用双差地震定位法,对漾濞M_S 6.4地震序列进行重新定位。重新定位结果显示序列呈NW向优势分布,破裂长约20 km,宽约7 km,对重新定位结果进行误差分析,水平方向定位误差约为0.8 km,垂直方向定位误差约为1.0 km,定位结果具有较好的稳定性。依据震中分布的走向将序列划分为NW向的主断层与NNW向的分支断层,主断层存在较为明显的分段现象,分支断层呈雁列状分布。根据小震丛集性发生在大震断层面及其附近的原则,利用重新定位后的小震震源位置反演得到漾濞M_S 6.4序列主断层走向约320°,倾角约89°,深度范围3～13 km。根据拟合得到的断层在地表的投影位置,推测本次地震的发震断层为维西-乔后断裂西侧的草坪断裂。基于断层滑动量分布识别出3个凹凸体,结合序列时空演化特征,分析了漾濞M_S 6.4地震序列的破裂过程,结果显示断层中段的凹凸体发生初始破裂...     

塔尔塔格铁矿床——新疆阿吾拉勒铁成矿带内首例IOA型铁矿床的厘定及意义

塔尔塔格铁矿是新疆西天山阿吾拉勒海相火山岩型铁成矿带内的一处中型铁矿床,其铁矿体呈透镜状产于粗安玢岩内顶部,在揭示海相火山岩中铁矿床与侵入岩关系方面具有重要意义。该铁矿床发育典型的磁铁矿 磷灰石组合,基本不含硫化物,矿石以似斑状、浸染状、球粒状和晶洞等构造类型为特色,磁铁矿内发育由条带状或叶片状钛铁矿和钛氧化物构成的出溶结构,并有少量的榍石、钍石、萤石等副矿物与之共生,矿床地质特征表明该矿床为典型的与富碱、中性侵入岩有关的IOA（iron oxide apatite）型铁矿床。该矿床围岩英安岩、赋矿粗安玢岩与成矿后正长花岗岩的锆石SHRIMP U Pb同位素加权平均年龄分别为311. 3±1. 4 Ma、304. 7±2. 9 Ma和301. 1±2. 8 Ma,铁矿石样品中与磁铁矿共生的榍石的LA ICP MS U Pb同位素加权平均年龄为302. 3±4. 0 Ma和303. 7±4. 2 Ma,成岩成矿年龄高度吻合,进一步确定其在晚石炭世晚期成矿。本文根据地质特征认为该矿床矿石是由粗安玢岩顶部富铁挥发分聚集而形成的,并初步提出“超浅成侵入岩顶部富挥发分囊体”成矿模型,即富碱、中性岩体超浅成侵位导致挥发分在岩体顶部迅速聚集形成多处富铁和挥发分的囊体,岩体冷凝固结的同时磁铁矿快速结晶成矿。塔尔塔格“IOA型”型铁矿的成因厘定,不仅表明海相火山岩型铁矿与IOA型铁矿可能存在成因联系,还暗示了海相火山岩型铁成矿带内具有寻找IOA型铁矿的潜力。     

Chronology, Geochemistry and Tectonic Settings of the Hadamiao Granodiorite on the Northern Margin of the North China Platform

<正>The Hadamiao granodiorite,located on the northern margin of the North China platform and acting as the country rock of gold deposits in the Hadamiao region,was formed in the same age and similar tectonic settings with the Hadamiao gold deposit and the large-scale Bilihe gold deposit in the same area.By using the LA-ICP-MS method,the U-Pb age obtained is 267±1.3 Ma,which represents the crystallized age of the granodiorite,and that of the xenolithic zircon is 442.8±5 Ma. Base on the main elements,it exhibits the features of calc-alkaline to high-potassium calc-alkaline series,low silicon,and quasi-aluminous I-type granites,and with high magnesium(Mg~#=0.45-0.57) and high sodium contents(Na_2O/K_2O=0.98-2.29).The SREE values(81.6-110.15 ppm) are relatively low,the fractionations between LREE and HREE are obvious,showing a right-inclined dispersion in the REE distribution diagram.Compared with the primitive mantle,the rock is relatively rich in LREE(La and Ce),LILE(K,Sr,and Th),and intensively depleted in HFSE(Ti,P,Nb and Ta).The ratios of Sr/Y and(La/Yb)_N and the contents of Rb,Nb and Y are relatively low,the Sr values are high (436.35-567.26 ppm),and the Yb contents of most samples are low(1.25-1.8),which indicate the features of typical continental margin arc and adakitic rocks.According to the values ofε_(Nd)(t)(-2.4 to +0.2) and I_(Sr)(0.7028-0.7083),and variations of the La/Sm ratios,the Hadamiao granodiorite was formed from mixing of the thickened molten lower crust and the mantle wedge substances.The rock was related to the southward subduction and accretion of the Paleo-Asia Ocean in the Late Paleozoic, being Late Paleozoic magma of the continental margin arc formed on the basement of the Early Paleozoic accretion complexes,and showing a trend of turning into adakitic rocks,which indicates their great metallogenic(Au) potential.     

Geochronology,geochemistry and Hf isotope of Late Triassic magmatic rocks of Qingchengzi district in Liaodong peninsula,Northeast China

The initiation timing and mechanism of lithospheric thinning of the North China Craton (NCC) was still controversial. Late Triassic igneous rocks especially mantle derived mafic rocks would provide constrains on Early Mesozoic lithospheric mantle geodynamics and initiation of lithospheric thinning. This paper reports Late Triassic magmatic rocks, including lamprophyre, diorite dykes and biotite monzogranite cropped out in Qingchengzi district of Liaodong peninsula, northeastern NCC. LA–ICPMS zircon U–Pb dating yield ages of 210–227 Ma and 224 Ma for lamprophyres and biotite monzogranite respectively. Lamprophyre is ultrapotassic, strongly enriched in REE and LILEs, depleted in HFSEs, and negative Hf isotopes, which are discriminating signatures of crustal source, but distinguishingly high compatible element contents indicate the primary magma originated from mantle source—a fertile one. Lamprophyre derived from partial melting of an enriched lithospheric mantle, which was modified by slab-derived hydrous fluids/melts associated with deep subduction between the Yangtze Craton and the NCC. The diorite displays distinct features with relatively enriched Nb, Ta, HREE and depleted Th, U, which suggest it derived from a relatively depleted source. The depletion was caused by break-off of the Yangtze slab during deep subduction introducing asthenospheric mantle into the source. The biotite monzogranite shows adakitic affinity, and originated from partial melting of the thickened lower crust with addition of small proportion of mantle material. The recognition of Late Triassic magmatism implies extensional tectonic settings in Liaodong peninsula and suggests initiation of lithospheric thinning of North China Craton in eastern segment might begin early in Late Triassic.