地磁场子夜均值逐日动态演化特征及与汶川大地震关系研究

利用我国地磁台网每天的“子夜均值”资料,应用高性能计算技术,建立中国地磁场动态演化模式,研究汶川5．12地震前后中国地磁异常场逐日演化特征。结果表明：地震前后地磁异常场变化特性较明显,在时间上有显著的阶段性特征,这可能反映了地震不同孕育阶段的特征。     

武都地电阻率在岷县5.2级地震前的异常变化

2003年11月岷县5.2级地震前武都台地电阻率资料出现了明显前兆异常, N85°E测道电阻率资料出现了典型的“勺形”变化, N73°W测道电阻率自2002年5月打破正常年变化形态, 2003年8月开始急剧升高。 研究结果认为, 从出现地电阻率异常到发震, 两测道各向异性变化明显, 各向异性度S′最大变化量超过了正常年变化的二倍。     

Characterization of high molecular weight biomarkers in crude oils

High-temperature gas chromatography (HTGC) has enhanced our ability to characterize hydrocarbons extending to C₁₂₀ in crude oils. As a result, hydrocarbons in waxes (> C₂₀) have been observed to vary significantly between crude oils, even those presumed to originate from the same source. Prior to this development, microcrystalline waxes containing hydrocarbons above C₄₀ were not characterized on a molecular level due to the analytical limitations of conventional gas chromatography. Routine screenings of high pour-point crude oils by high-temperature gas chromatography has revealed that high molecular weight hydrocarbons (> C₄₀) are very common in most oils and may represent 2% of the crude oil. Precise structures, origins, and significance of these high molecular weight compounds remain elusive. As a preliminary step to expand our knowledge of these compounds their general molecular structures and formulas have been investigated in this study. Initial results suggest that the major high molecular weight compounds include a homologous series of n-alkanes, methylbranched alkanes, alkylcyclopentanes, alkylcyclohexanes, alkylbenzenes and alkylcycloalkanes.     

A new series of steryl chlorin esters: pheophorbide a steryl esters in an oxic surface sediment

Investigation of chlorins in the oxic surface sediment of a small eutrophic alpine lake (Motte lake) revealed the presence of a new series of steryl chlorin esters containing the pheophorbide a nucleus, together with their pyropheophorbide a steryl ester counterparts previously observed in the anoxic surface sediment of the same lake. Identification of the pheophorbide a steryl esters was based on comparison of spectroscopic, chromatographic and mass spectrometric characteristics of the compounds with those of a synthetic standard and of pyropheophorbide a steryl esters. Combined liquid chromatography-mass spectrometry analysis confirmed the absence of pheophorbide a steryl esters in the anoxic sediment but allowed their detection in traces in the water column, indicating that pheophorbide a steryl esters are, like their pyropheophorbide a analogs, formed in the water column. The distribution of sterols released by hydrolysis of the pheophorbide a steryl esters shows close similarities to that of the free sterols in the water column and of the sterols of the pyropheophorbide a steryl esters. It appears that, like their pyropheophorbide a counterparts, pheophorbide a steryl esters incorporate mainly sterols of phytoplanktonic origin. Their formation probably involves the same mechanism as for pyropheophorbide a steryl ester formation, i.e. metabolism by zooplankton grazing on phytoplankton. The presence of pheophorbide a steryl esters in the oxic sediment and their absence from the anoxic sediment is probably due to a lower stability of compounds containing a carbomethoxy substituent in the anoxic environment.     

等离子体发射光谱法测定大气颗粒物中的无机元素

建立了用等离子体发射光谱（ＩＣＰ－ＡＥＳ）测定大气颗粒物中无机元素的分析方法,包括样品消解体系的选择,仪器的操作条件及采样滤膜的选择,产对自行采样分析测得的无机元素数据作了初步的讨论。实验结果表明：采用ＨＮＯ３－ＨＣｌＯ４消解体系,操作方便,样品消解较完全;选用石英滤膜查减低空白值,保证测定质量以及同时在一张滤膜上测定大气颗粒物中的有机碳、元素碳及无机元素;内标法可有效降低由于仪器漂移等因素对测定     

2021年四川泸县MS6.0地震震源性质及震前区域应力场特征

为了解2021-09-16四川泸县M_S6.0地震的发震机理,加强对四川盆地内地震活动性的认识,基于四川及周边地区地震台网的宽频带地震资料,利用CAP方法反演获得泸县地震的震源机制解和矩心深度;同时,基于震前四川盆地内155个震源机制解,利用MSATSI程序反演得到泸县地震震前四川盆地内的构造应力场。结果显示,泸县地震矩心深度为3 km,矩震级为M_W5.3,滑动性质为纯逆冲。震中附近震前构造应力最大主压应力和中间主压应力都近乎水平,最大主压应力在震中附近走向101°,此构造应力状态下,优势滑动断层为纯逆冲性质,与泸县地震震源机制一致。根据震源位置和性质、震前构造应力场及震中附近的断层性质推测,泸县地震发震断层不是华蓥山断裂,而是其分支和余脉之间极浅的盖层滑脱型断层。     

2008年汶川MS8.0地震电离层图像信息长时程演化初探

应用改进的图像信息方法, 结合DEMETER电磁卫星的电子温度数据, 对2008年汶川M_S8.0地震进行了长时程的回溯性预测研究。 与以往的地震电离层演化图像提取异常的研究相比, 将其回溯的时程延长至震前近11个月, 并向震后延长48 d。 在长期连续的异常扰动演化图中, 出现了两个明显的异常时段, 且在震前2个月短期内异常扰动明显减弱并趋于背景值。 两个时段出现的异常扰动分布位置及其形态以及持续时间皆不重复, 这体现了前兆异常的不易确定, 难以定性及定量识别的特点。 电离层异常扰动特征的长时程研究, 有评估其预测参数和模型可靠性的实际作用, 也为应用中国卫星观测数据服务于地震预报等研究积累经验, 具有借鉴意义。     

New aromatic biomarkers and possible maturity indicators found in New Albany Shale extracts

Aromatic hydrocarbons from benzene extracts of New Albany Shale were characterized. A biomarker that has a molecular weight of 546 and a structural configuration consistent with that of an alkyl-aromatic hydrocarbon (C₄₀H₆₆) was tentatively identified. It was found that the relative concentrations of the biomarker are indicative of differing levels of thermal maturity of the shale organic matter. A 40-carbon bicyclic carotenoid (C₄₀H₄₈) is proposed as the geochemical precursor of this biomarker. Thermal maturity of the shale organic matter can also be differentiated by observing differences in “fingerprints” as obtained by field-ionization mass spectrometry on the aromatic hydrocarbon fraction. Using this technique, we found that the more mature shale samples from southeastern Illinois contain more low molecular weight extractable aromatic hydrocarbons and the less mature shale samples from northwestern Illinois contain more high molecular weight extractable aromatic hydrocarbons. It was demonstrated that field-ionization and tandem mass spectrometric techniques through fingerprint and individual compound identification, are useful for shale aromatic hydrocarbon fraction characterization and for thermal maturation interpretation.     

碱熔沉淀-等离子体质谱法测定地质样品中的多元素

采用过氧化钠焙融或偏硼酸锂熔融分解样品，将提取液碱性沉淀，通过过滤分离掉大量熔剂，再将沉淀用酸复溶后用等离子体质谱测定26个元素。通过对比，偏硼酸锂熔融—酸提取—碱性沉淀的方案，空白低，易操作，成本低，大多数元素测定结果的相对误差＜10％，相对标准偏差＜5％(n＝10)，与标准值相吻合。     

辽东半岛～2．2 Ga 岩浆事件及其地质意义

本文报道了辽东半岛古元古代胶—辽—吉活动带内辽河群变质火山岩和辽吉花岗岩的锆石LA-ICP-MS U-Pb年代学和地球化学数据。变质安山岩的锆石具典型的岩浆振荡环带结构和较高的Th/U值(0.5),锆石U-Pb年龄为(2 182±6)Ma和(2 229±22)Ma,该年龄可代表安山岩的形成年龄。辽吉花岗岩的锆石同样具有典型的岩浆振荡环带结构和较高的Th/U值(0.3),锆石U-Pb年龄为(2 199±10)Ma,代表花岗岩的侵位时代,在误差范围内与辽河群火山岩喷发时代一致,表明辽吉花岗岩并不是辽河群的基底,二者可能为同一次岩浆作用过程的产物。辽东半岛~2.2Ga岩浆事件的识别及性质,对于正确认识古元古代胶—辽—吉活动带的属性至关重要。结合前人有关辽东半岛前寒武纪岩石的研究成果,本文研究认为胶—辽—吉活动带的形成演化可能与弧-陆碰撞有关。