地幔流体及其成矿作用

高灵敏度、高精密度、低检出限、多元素同时检测并可提供同位素组成比值信息的等离子体质谱与高空间分辨率的紫外激光采样技术结合 ,可定量地测定单个流体包裹体中常、微量元素含量 ,为成矿流体的研究提供了一个新的研究手段。文中简要地介绍了激光剥蚀电感耦合等离子体质谱 (LA ICP MS)分析仪器的发展 ,结合实验室的研究工作 ,就激光剥蚀池的设计、单个流体包裹体的剥蚀方法、元素的分馏效率、定量校正技术及其在成矿成因物理化学机制研究中的应用等进行评述 ,并阐述单个流体包裹体元素组成的LA ICP MS分析技术存在的局限和发展趋势。     

浙江南部沿岸产卵场春、夏季鱼卵、仔稚鱼种类组成与分布

根据2011年4月、5月与6月对浙江南部沿岸产卵场进行的共3个航次的调查资料,对该海域的鱼卵、仔稚鱼的种类组成和数量分布进行了分析,结果表明,共发现鱼卵、仔稚鱼72个种类,分别隶属11目38科48属。其中鱼卵29种,分别隶属6目18科24属;仔稚鱼55种,分别隶属10目29科40属。4—6月仔稚鱼数量呈逐月递减的趋势,而鱼卵数量6月最多,5月最少。鱼卵优势种4月以斑鰶、棱鱚、小黄鱼与蓝点马鲛为主,5月以斑鰶、鳀、龙头鱼、银鲳、蓝点马鲛与石首鱼科为主,6月以鳀、龙头鱼、多鳞鱚与鲱科鱼类为主;仔稚鱼优势种4月以虾虎鱼类、褐菖鲉与平鲉科为主,5月以鳀、虾虎鱼类、棱鱚、斑鰶与长鳍篮子鱼为主,6月以鳀与虾虎鱼类为主。斑鰶、鲳鱼、小黄鱼、棱鱚、蓝点马鲛与褐菖鲉的产卵盛期为4月,而鳀与龙头鱼的产卵盛期为6月。     

Chronology, Geochemistry and Tectonic Settings of the Hadamiao Granodiorite on the Northern Margin of the North China Platform

<正>The Hadamiao granodiorite,located on the northern margin of the North China platform and acting as the country rock of gold deposits in the Hadamiao region,was formed in the same age and similar tectonic settings with the Hadamiao gold deposit and the large-scale Bilihe gold deposit in the same area.By using the LA-ICP-MS method,the U-Pb age obtained is 267±1.3 Ma,which represents the crystallized age of the granodiorite,and that of the xenolithic zircon is 442.8±5 Ma. Base on the main elements,it exhibits the features of calc-alkaline to high-potassium calc-alkaline series,low silicon,and quasi-aluminous I-type granites,and with high magnesium(Mg~#=0.45-0.57) and high sodium contents(Na_2O/K_2O=0.98-2.29).The SREE values(81.6-110.15 ppm) are relatively low,the fractionations between LREE and HREE are obvious,showing a right-inclined dispersion in the REE distribution diagram.Compared with the primitive mantle,the rock is relatively rich in LREE(La and Ce),LILE(K,Sr,and Th),and intensively depleted in HFSE(Ti,P,Nb and Ta).The ratios of Sr/Y and(La/Yb)_N and the contents of Rb,Nb and Y are relatively low,the Sr values are high (436.35-567.26 ppm),and the Yb contents of most samples are low(1.25-1.8),which indicate the features of typical continental margin arc and adakitic rocks.According to the values ofε_(Nd)(t)(-2.4 to +0.2) and I_(Sr)(0.7028-0.7083),and variations of the La/Sm ratios,the Hadamiao granodiorite was formed from mixing of the thickened molten lower crust and the mantle wedge substances.The rock was related to the southward subduction and accretion of the Paleo-Asia Ocean in the Late Paleozoic, being Late Paleozoic magma of the continental margin arc formed on the basement of the Early Paleozoic accretion complexes,and showing a trend of turning into adakitic rocks,which indicates their great metallogenic(Au) potential.     

Geochronology,geochemistry and Hf isotope of Late Triassic magmatic rocks of Qingchengzi district in Liaodong peninsula,Northeast China

The initiation timing and mechanism of lithospheric thinning of the North China Craton (NCC) was still controversial. Late Triassic igneous rocks especially mantle derived mafic rocks would provide constrains on Early Mesozoic lithospheric mantle geodynamics and initiation of lithospheric thinning. This paper reports Late Triassic magmatic rocks, including lamprophyre, diorite dykes and biotite monzogranite cropped out in Qingchengzi district of Liaodong peninsula, northeastern NCC. LA–ICPMS zircon U–Pb dating yield ages of 210–227 Ma and 224 Ma for lamprophyres and biotite monzogranite respectively. Lamprophyre is ultrapotassic, strongly enriched in REE and LILEs, depleted in HFSEs, and negative Hf isotopes, which are discriminating signatures of crustal source, but distinguishingly high compatible element contents indicate the primary magma originated from mantle source—a fertile one. Lamprophyre derived from partial melting of an enriched lithospheric mantle, which was modified by slab-derived hydrous fluids/melts associated with deep subduction between the Yangtze Craton and the NCC. The diorite displays distinct features with relatively enriched Nb, Ta, HREE and depleted Th, U, which suggest it derived from a relatively depleted source. The depletion was caused by break-off of the Yangtze slab during deep subduction introducing asthenospheric mantle into the source. The biotite monzogranite shows adakitic affinity, and originated from partial melting of the thickened lower crust with addition of small proportion of mantle material. The recognition of Late Triassic magmatism implies extensional tectonic settings in Liaodong peninsula and suggests initiation of lithospheric thinning of North China Craton in eastern segment might begin early in Late Triassic.     

Geochemistry,and zircon U–Pb and molybdenite Re–Os geochronology of Jilongshan Cu–Au deposit,southeastern Hubei Province,China

The Jilongshan skarn Cu–Au deposit is located at the Jiurui ore cluster region in the southwestern part of the Middle–Lower Yangtze River valley metallogenic belt. The region is characterized by NW‐, NNW‐ and EW‐trending faults and the mineralization occurs at the contact of lower Triassic carbonate rocks and Jurassic granodiorite porphyry intrusions. The intrusives are characterized by SiO₂, K₂O, and Na₂O concentrations ranging from 61.66 to 67.8 wt.%, 3.29 to 5.65 wt.%, and 2.83 to 3.9 wt.%, respectively. Their A/CNK (A/CNK = n(Al₂O₃)/[n(CaO) + n(Na₂O) + n(K₂O)]) ratio, δEu, and δCe vary from 0.77 to 1.17, 0.86 to 1, and 0.88 to 0.96, respectively. The rocks show enrichment in light rare earth elements ((La/Yb)_N = 7.61–12.94) and large ion lithophile elements (LILE), and depletion in high field strength elements (HFSE), such as Zr, Ti. They also display a peraluminous, high‐K calc‐alkaline signature typical of intrusives associated with skarn and porphyry Cu–Au–Mo polymetallic deposits. Laser ablation inductively coupled plasma spectrometry (LA‐ICP‐MS) zircon U–Pb age indicates that the granodiorite porphyry formed at 151.75 ± 0.70 Ma. A few inherited zircons with older ages (677 ± 10 Ma, 848 ± 11 Ma, 2645 ± 38 Ma, and 3411 ± 36 Ma) suggest the existence of an Archaean basement beneath the Middle–Lower Yangtze River region. The temperature of crystallization of the porphyry estimated from zircon thermometer ranges from 744.3 °C to 751.5 °C, and 634.04 °C to 823.8 °C. Molybdenite Re–Os dating shows that the Jilongshan deposit formed at 150.79 ± 0.82 Ma. The metallogeny and magmatism are correlated to mantle–crust interaction, associated with the subduction of the Pacific Plate from the east. Copyright © 2013 John Wiley & Sons, Ltd.     

湘东南—赣西地区加里东期沉积演化特征

通过对研究区加里东期沉积物的野外地质调查、剖面横向对比和岩相古地理编图,发现研究区加里东期主要发育五种沉积相类型,分别为碳酸盐岩陆棚相、碎屑岩—碳酸盐岩混积陆棚相、冰海相、欠补偿型硅质岩—页岩盆地相和补偿型浊积岩盆地相。剖面横向对比显示,研究区加里东期沉积物由西向东为连续相变沉积,横向上各种沉积相指状交叉、相互过渡;岩相古地理研究表明,加里东期湘东南—赣西地区主要发育硅质岩—页岩盆地相和浊积岩盆地相两大相带,从南华纪—奥陶纪时期两大相带的发育规模略有差异,在两大相带的结合部往往发育两种沉积相的交叉过渡带。笔者认为该区沉积相的过渡性质对探讨华南洋加里东期属性的问题有重要意义。     

湖南锡田岩体的岩浆混合成因:岩相学､岩石地球化学和U-Pb 年龄证据

南岭中段的锡田岩体燕山期岩石以斑状黑云母二长花岗岩为主,岩体中广泛发育暗色微粒包体?暗色微粒包体为岩浆结构,大多数具有塑性外形,发育淬冷边?反向脉,存在多种不平衡结构和矿物组合,如钾长石环斑?石英眼斑?针状磷灰石等,显示岩浆混合特征?岩石地球化学方面,暗色微粒包体具有比寄主岩贫硅?贫碱,富K?Fe?Mg?Ca?Ti 特征;暗色微粒包体及寄主岩富集轻稀土元素(LREE/HREE=2.6~8.8),具有中-强的铕负异常(δEu=0.09~0.74)以及具有相似的稀土元素配分曲线和微量元素蛛网图;在主要氧化物含量Harker 图解中投点多呈直线变异趋势,反映了两者具有密切的亲缘关系,利用共分母和不共分母图解进行判别,暗色微粒包体与寄主岩具岩浆混合特征,在MgO-TFeO判别图解中也指示包体为岩浆混合成因?上述岩相学和元素地球化学特征表明暗色微粒包体是基性岩浆侵入到酸性岩浆中淬冷形成的,指示锡田岩体存在两种岩浆的混合作用?通过LA-ICP-MS锆石U-Pb 定年,得到寄主岩形成年龄(150.04±0.52)Ma,暗色包体形成年龄(145.09±0.63)Ma,二者年龄在测试误差范围内一致,显示岩浆混合作用发生的时间大致为晚侏罗世?     

1637—1643年华北地区极端干旱事件中的粮食危机

粮食作为自然生态系统与社会经济系统的关联点,能够有效地揭示极端干旱事件对自然-经济-社会复合生态系统影响的过程和机理。以粮价异动为切入点,通过粮价通胀指数和“无透雨”的持续时间,分析农业旱情及其对粮食生产的影响,对1637—1643年华北地区极端干旱事件中的粮食安全进行深入剖析。结果显示:华北地区无透雨天数超过150 d,年降水量与5—9月降水量的距平值均≤-30%,水分异常短缺,土壤严重失墒,危及粮食生产安全。因此,降水量距平值≤-30%是华北地区粮食生产安全的临界阈值。此次极端干旱事件是历史同类事件之最,连续无透雨日数最长,地表径流枯竭记录最多,水资源的短缺导致伴生灾害相继发生,超过生态系统的忍耐极限,粮食生长期缩短,减产歉收,绝产绝收,粮食供给链条断裂。粮价通胀指数最低9.50,最高26.70;货币发行与粮食供给失衡,通货膨胀严重,粮价飞涨,市场倒闭,粮食安全体系崩塌,自然-经济-社会复合生态系统发生质变成为历史必然。     

张家口—渤海地震带岩石圈磁场时空变化特征

利用2016—2018年3期华北地区流动地磁矢量原始测量资料, 经数据计算获得2期华北地区和张家口—渤海地震活动带及邻区岩石圈磁场时空变化模型。 研究结果显示: 张家口—渤海地震带岩石圈磁场变化空间分布不均匀, 具有明显的分区特征, 在张家口段(西段)与北京段(中西段)分界处和北京段(中西段)与唐山段(中东段)分界处岩石圈磁场各要素具有明显的异常变化, 如水平矢量存在转向和幅值变化, 磁偏角与磁倾角具有正负异常高梯度带的特征, 这与张家口—渤海地震带构造分段性特征密切相关。 张家口—渤海地震带位于燕山块体与华北平原块体之间, 两者运动的平动速率之差是张家口—渤海地震带左旋走滑的直接动力来源, 而各断裂带左旋走滑速率之差很可能是岩石圈磁场空间变化分段性分布的主要原因。     

黑龙江多宝山——大新屯地区铜金多金属成矿作用及找矿方向

黑龙江省多宝山—大新屯地区,铜矿以中—晚加里东期多宝山式斑岩型、燕山早期三矿沟式矽卡岩型为主,晚古生界海底火山岩有关喷发—沉积型铜锌矿床,具优越的成矿潜力,不同时期、类型铜矿床在空间分布上明显受古生代海相火山岩—碳酸盐岩建造控制,并具有"上金下铜"的斑岩—热液型铜金矿成矿系统的特征。金矿以燕山晚期三道湾子式浅成低温热液型金成矿作用强烈为特点;持续时间由早石炭世—早—中侏罗世的韧性剪切—走滑作用、中侏罗世为主要伸展期的变质核杂岩有关的金成矿作用,以及奥陶纪浊积岩(卡林型)有关金成矿作用,以中—小规模金矿床(点)为主;金矿受北西向、北东向的火山构造、变质核杂岩构造和韧性剪切—走滑作用控制,显示出良好的金找矿前景;结合近期的铜金矿重大勘查进展和成果,总结成矿规律,梳理了制约着铜金多金属矿找矿突破的关键地质问题,提出找矿方向和今后勘查工作部署建议。