江西赣县大埠钨多金属矿田成岩成矿时空结构与找矿预测

大埠矿田位于南岭成矿带东段,是于都-赣县钨多金属矿集区重要组成,区内已发现钨多金属矿床（点）五十余处,矿床类型包括石英脉型、矽卡岩型、云英岩型和细脉浸染型等,各类矿化主要围绕大埠复式花岗岩体产出。然而,大埠矿田岩浆作用具有明显的多期次、多阶段的特点,各期次成岩成矿时代尚缺乏系统研究,各类岩浆岩与矿化关系争议较大。文章在岩体地质和矿床地质调查基础上,通过LA-(MC)-ICP-MS锆石U-Pb定年、锆石微量元素和Hf同位素分析,精确厘定了大埠花岗岩的成岩时代,探讨了多期次岩浆活动对区内成矿作用的贡献。锆石U-Pb定年结果分别为(429.1±4.7)Ma、(430.0±5.8) Ma、(431.8±4.7) Ma和(158.3±4.1) Ma,结合岩体地质填图信息,笔者认为大埠复式花岗岩基由加里东期和燕山期两部分组成。两期花岗岩均属于高钾钙碱性、过铝质S型花岗岩系列,两者均出现Eu负异常,燕山早期Eu负异常更明显。两期岩体锆石的ε_Hf(t)值分别为-6.3~-1.3与-11.4~-7.1,对应二阶段模式年龄为1.49~1.82 Ga与1.66~1.93 Ga,指示其母岩浆为中元古代的地壳部分熔融形成。锆石微量元素特征显示,两期花岗岩均为陆壳源区、具有相近的结晶温度,燕山早期花岗岩相对于加里东期有更高的结晶分异程度,有更高的氟含量,与钨成矿具有更强的相关性。大埠矿田钨多金属成矿时代集中在159~155 Ma,紧随燕山早期花岗质岩浆侵位而形成。基于大埠矿田成岩成矿时代格架研究,结合花岗岩成矿专属性和成矿地质条件分析,构建了区内钨多金属矿勘查模型,指明了大埠矿田细脉浸染型、云英岩型、内带石英脉型钨矿的找矿方向,预测大埠岩体东北部的燕山早期隐伏岩体具有寻找“合龙式”石英大脉型和细脉-云英岩型钨矿的潜力。     

海南三亚中元古代变质砾岩的发现及其对Columbia超大陆裂解的指示

海南岛中元古代沉积记录对于探讨华南陆块早期大陆演化过程起关键作用。对海南三亚三郎岭地区奥陶系干沟村组砂岩-板岩组合中的变砾岩形成时代进行了重新厘定。碎屑锆石U-Pb同位素年龄分析结果表明,65颗锆石207Pb/206U年龄范围为2691~1350 Ma,且分成2691~2444 Ma、1838~1632 Ma、1540~1350 Ma三组,形成约1699 Ma、约1440 Ma 2个主要峰值和约2461 Ma的1个次要峰值。基于最年轻锆石年龄为1350 Ma,且没有出现海南岛常见的1250~1100 Ma和1000~900 Ma年龄记录,将该套变质砾岩沉积时代限定在1350~1250 Ma,而并非前人划属的奥陶纪,这是海南岛首次发现中元古代的砾岩建造。该套变砾岩砾石成分成熟度高、结构成熟度中等,表现为裂谷盆地高密度的碎屑流沉积特征,是研究区Columbia超大陆裂解晚期的沉积响应。变质砾岩与劳伦大陆西部的Belt-Purcell超群下部沉积地层具有相似的碎屑锆石年龄组成和年龄谱特征,暗示中元古代哥伦比亚超大陆中,海南岛与劳伦西部靠近。     

90年代中国省级区域经济与环境协调度分析

在阐述经济环境协调度理论的基础上,建立了环境承载力与经济发展水平之间的协调度模型。并通过对90年代我国省级区域的实证分析,发现我国空间区域经济环境协调度基本符合“U”型曲线,区域经济发展模式大多以牺牲环境为代价,特别是中西部地区的问题比较严重。     

紫菜特征挥发性物质分析

应用顶空固相微萃取和气相色谱-质谱联用技术,对坛紫菜(Porphyra haitanensis)、条斑紫菜(Porphyra yezoensis)与其一个突变品系的生长藻体挥发性物质进行分析,共分离鉴定出66种挥发性组分,3个紫菜试样中分别含有36、44和45种.鉴定组分中有21种为紫菜共有挥发性物质,其中8-十七烯和...     

Identification of Pb sources in Yellow Sea sediments using stable Pb isotope ratios

Rapid economic developments in East Asian countries have inevitably resulted in environmental degradation in the surrounding seas, and concern for both the environment and protection from pollutants is increasing. Identification of sources of contaminants is essential to environmental pollution management. In this study, the provenance of anthropogenic lead (Pb), a major pollutant of Yellow Sea sediments, was determined for river mouth sediments, including those of the Changjiang, Huanghe, Han, and Geum Rivers, and for age-determined shelf core sediments through the measurement of Pb isotope ratios in the HCl-leached fraction using multi-collector inductively coupled plasma-mass spectrometry (MC ICP/MS). Anthropogenic Pb has accumulated in shelf core sediments since 1910, and its isotope ratios were estimated as 0.863–0.866 and 2.119–2.125 for ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁸Pb/²⁰⁶Pb, respectively, from the mixing relationships of the two endmembers. River mouth sediments exhibited enough distinction in anthropogenic Pb isotope ratios to be discriminated: 0.874 (2.144) in the Huanghe, 0.856 (2.129) in the Han, 0.857 (2.122) in the Geum, and 0.854 (2.101) in the Changjiang for ²⁰⁷Pb/²⁰⁶Pb (²⁰⁸Pb/²⁰⁶Pb), respectively. Although isotope ratios of geogenic Pb in sediments dating before 1910 showed narrow ranges (0.842–0.845 and 2.088–2.100 for ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁸Pb/²⁰⁶Pb, respectively), distinct isotope ratios in each core permitted source identification of sediments in the Yellow Sea based on geographic locations and the geogenic Pb of each river. By comparing the isotope ratios of the estimated anthropogenic Pb to source-related materials, the provenances of anthropogenic Pb in Chinese river sediments were presumed to be Chinese coal or ore, which is also a major source of atmospheric particulate Pb. The anthropogenic Pb in the shelf core sediments in the northern Yellow Sea originated from northern Chinese cities such as Beijing and Tianjin through atmospheric pathways. Pb isotope ratios indicated that Pb in Korean river sediments was characteristic of local Korean ores.     

江南造山带仙霞复式岩体的成因研究

仙霞复式岩体位于江南造山带东北部,是该区出露面积最大的复式岩体之一。本文在野外地质调查的基础上,对仙霞复式岩体不同期次岩浆岩开展了锆石U-Pb年代学和全岩地球化学分析,结果显示该复式岩体侵位分为早、中、晚三阶段,岩性分别为二长花岗岩(143.0±3.5Ma)、花岗闪长岩(140.0±2.0Ma)和钾长花岗岩(138.6±3.5Ma),是江南造山带燕山期早期(146～135Ma)岩浆作用的产物。仙霞复式岩体三阶段岩浆岩均为高碱、弱过铝质岩石,具有相似的稀土元素配分模式,微量元素均呈Rb、Ba、U、K、Pb等大离子亲石元素(LILE)富集, Nb、Ta、P、Ti等高场强元素(HFSE)亏损的特征,锆石εHf(t)同位素为负值(–15.54～–1.03)。综合分析显示,仙霞复式岩体的岩浆起源于下地壳物质为主的壳幔混合源区,在岩浆上升演化过程中经历了显著的结晶分异作用,形成于早白垩世(146～135 Ma)古太平洋板块向西俯冲的背景下。     

Study on the relationship between speciation of heavy metals and their ecotoxicity

Heavy metal is a main pollutant in the marine ecosystem, so study on the effect of heavy metal on phytoplankton is important. Algae (Chaetoceros sp.,Dunaliella sp.,Dicrateria zhanjiangenis Hu. var. sp.) were laboratory cultured to observe the effect of heavy metals on their growth. The effect of different metal ion concentration, the detoxication effect of complexation agents and the growth of algae in different media and different nutrition levels were studied to evaluate the effect of metal speciation. It is proved that trace amount of heavy metals can stimulate the growth of algae cells but that high concentration is lethal. The sequence of toxicity is Cd²⁺>Zn²⁺>Pb²⁺. In ordinary nutrition conditions, the detoxication sequence of complexation agents toChaetoceros sp. is EDTA >sodium salicylate>sodium oxalate >sodium citrate>sulfanilic acid>O-phenanthroline. This is in good conformity with the stability constant sequence of these agents with copper and good evidence that toxicity of metal ion is related to its activity and not to its total concentration. Project supported by the Fund of Excellent Young Teachers of State Educational Commission of China.     

Zircon and whole-rock Nd-Pb isotopic provenance of Middle and Upper Ordovician siliciclastic rocks, Argentine Precordillera

Graptolite‐bearing Middle and Upper Ordovician siliciclastic facies of the Argentine Precordillera fold‐thrust belt record the disintegration of a long‐lived Cambro‐Mid Ordovician carbonate platform into a series of tectonically partitioned basins. A combination of stratigraphic, petrographic, U‐Pb detrital zircon, and Nd‐Pb whole‐rock isotopic data provide evidence for a variety of clastic sediment sources. Four Upper Ordovician quartzo‐lithic sandstones collected in the eastern and central Precordillera yield complex U‐Pb zircon age spectra dominated by 1·05–1·10 Ga zircons, secondary populations of 1·22, 1·30, and 1·46 Ga, rare 2·2 and 1·8 Ga zircons, and a minor population (<2%) of concordant zircons in the 600–700 Ma range. Archaean‐age grains comprise <1% of all zircons analysed from these rocks. In contrast, a feldspathic arenite from the Middle Ordovician Estancia San Isidro Formation of the central Precordillera has two well‐defined peaks at 1·41 and 1·43 Ga, with no grains in the 600–1200 Ma range and none older than 1·70 Ga. The zircon age spectrum in this unit is similar to that of a Middle Cambrian quartz arenite from the La Laja Formation, suggesting that local basement rocks were a regional source of ca 1·4 Ga detrital zircons in the Precordillera Terrane from the Cambrian onwards. The lack of grains younger than 600 Ma in Upper Ordovician units reinforces petrographic data indicating that Ordovician volcanic arc sources did not supply significant material directly to these sedimentary basins. Nd isotopic data (n = 32) for Middle and Upper Ordovician graptolitic shales from six localities define a poorly mixed signal [ɛ_Nd(450 Ma) = −9·6 to −4·5] that becomes more regionally homogenized in Upper Ordovician rocks (−6·2 ± 1·0; T_DM = 1·51 ± 0·15 Ga; n = 17), a trend reinforced by the U‐Pb detrital zircon data. It is concluded that proximal, recycled orogenic sources dominated the siliciclastic sediment supply for these basins, consistent with rapid unroofing of the Precordillera Terrane platform succession and basement starting in Mid Ordovician time. Common Pb data for Middle and Upper Ordovician shales from the western and eastern Precordillera (n = 15) provide evidence for a minor (<30%) component that was likely derived from a high‐μ (U/Pb) terrane.     

Petrogenesis and tectonic setting of granite porphyry in Keyouzhongqi area,Inner Mongolia

The authors studied the geochemistry,zircon U-Pb ages,Hf isotope of the granite porphyry and its petrogenesis and tectonic setting in the studied area． The zircon U-Pb dating indicates the formation of the gran- ite porphyry is in Early Cretaceous (125． 1 ±1． 5 Ma)． The granite porphyry has high-SiO2and alkali-rich fea- tures,which belongs to high-K calc-alkaline series rocks (A/CNK = 0． 95%--1． 25%)． The analyses of trace elements show the characteristics of a swallow-shaped ＲEE distribution pattern with enrichment in LＲEEs and most of LILEs and HFSEs,depletion in Ba,Sr,Nb,P and Ti,and especially strong depletion in Eu,which indicates the granite porphyry belongs to the aluminous A-type granite． Their εHf(t)range from 5． 94 to 8． 80 with Hf two-stage model ages (TDM2) of 620 Ma to 803 Ma． Combining with the regional tectonic background, we conclude that the source of the rocks is the new crust materials accreted from depleted mantle in Neoprotero- zoic and is the product of partial melting of middle and lower crustal rocks,which may be suffered from the dual impact of the subduction of the Palaeo-Pacific Ocean and the closure of the Mongol-Okhotsk Ocean．