Diagenetic fluid evolution and water-rock interaction model of carbonate cements in sandstone: An example from the reservoir sandstone of the Fourth Member of the Xujiahe Formation of the Xiaoquan-Fenggu area,Sichuan Province,China

Carbonate cement is the most abundant cement type in the Fourth Member of the Xujiahe Formation in the Xiaoquan-Fenggu area of the West Sichuan Depression. Here we use a systematic analysis of carbonate cement petrology, mineralogy, carbon and oxygen isotope ratios and enclosure homogenization temperatures to study the precipitation mechanism, pore fluid evolution, and distribution of different types of carbonate cement in reservoir sand in the study area. Crystalline calcite has relatively heavy carbon and oxygen isotope ratios(δ13C = 2.14‰, δ18O = -5.77‰), and was precipitated early. It was precipitated directly from supersaturated alkaline fluid under normal temperature and pressure conditions. At the time of precipitation, the fluid oxygen isotope ratio was very light, mainly showing the characteristics of a mixed meteoric water-seawater fluid(δ18O = -3‰), which shows that the fluid during precipitation was influenced by both meteoric water and seawater. The calcite cement that fills in the secondary pores has relatively lighter carbon and oxygen isotope ratios(δ13C = -2.36‰, δ18O = -15.68‰). This cement was precipitated late, mainly during the Middle and Late Jurassic. An important material source for this carbonate cement was the feldspar corrosion process that involved organic matter. The Ca2+, Fe3+ and Mg2+ ions released by the clay mineral transformation process were also important source materials. Because of water-rock interactions during the burial process, the oxygen isotope ratio of the fluid significantly increased during precipitation, by about 3‰. The dolomite cements in calcarenaceous sandstone that was precipitated during the Middle Jurassic have heavier carbon and oxygen isotope ratios, which are similar to those of carbonate debris in the sandstone(δ13C = 1.93‰, δ18O = -6.11‰), demonstrating that the two are from the same source that had a heavier oxygen isotope ratio(δ18O of about 2.2‰). The differences in fluid oxygen isotope ratios during cement precipitation reflect the influences of different water-rock interaction systems or different water-rock interaction strengths. This is the main reason why the sandstone containing many rigid particles(lithic quartz sandstone) has a relatively negative carbon isotope ratio and why the precipitation fluid in calcarenaceous sandstone has a relatively heavier oxygen isotope ratio.     

新疆喀什西部新一代天气雷达产品的冰雹预警指标研究

2010年以来喀什地区冰雹频繁,严重危害当地农业生产. 通过整理分析2009-2012年喀什新一代天气雷达监测资料,结合我国中东部地区基于雷达监测的冰雹预警指标,经过对喀什西部的18次冰雹天气过程中新一代天气雷达监测预警指标的分析,归纳出了喀什西部新一代雷达产品的冰雹预警指标：（1）组合反射率≥50 dBz;（2）回波顶高≥9 km;（3）云体垂直液态水含量≥20 kg·m^-2. 根据该预警指标对喀什西部2011-2012年冰雹过程进行回报预警,准确率达到84.6%. 以有详细降雹时间记录的14次冰雹过程为例,分析喀什西部基于雷达监测产品的冰雹预警时效,14次个例中冰雹预警时效平均为27 min. 选取2012年5月13日、5月23日和2013年6月18日3次强冰雹过程个例,分析冰雹出现前后喀什新一代天气雷达的连续监测资料表明：3次过程中降雹开始时间对应雷达监测值达到最大（高）值时刻;组合反射率与回波顶高首先达到预警指标,垂直液态含水量达到预警指标的时间滞后11~19 min;3项雷达产品均达到冰雹预警指标的时间比实际发布冰雹预警时间早7~17 min,喀什西部冰雹预警时效潜力可以增加到30 min以上. 在喀什西部,应用新一代天气雷达监测产品开展冰雹实时预警业务是可行的,对提高当地冰雹灾害防御能力提供了有力的技术支持.     

陆相断陷盆地可容空间转换特征

陆相断陷盆地具有构造活动影响大、沉积物供给不均衡、湖盆范围小、物源多等特点。由于自身的局限性,这些因素对层序发育的控制作用更加明显,而直接影响湖盆可容空间的因素为构造沉降、沉积物供给和湖盆水体,三者的相互关系不仅使湖盆在演化过程中可容空间、水深和相对湖平面具有一致的变化,同时其变化又存在非统一性。构造沉降和水体为主控因素时,往往形成欠补偿沉积,相对湖平面和可容空间统一增加;构造沉降和沉积物供给为主控因素时,相对湖平面增加,可容空间在盆地的不同部位其变化不一致,在盆地中心可容空间增加,边缘可容空间减小,而在其间存在一个稳定区,即可容空间转换带。东营凹陷古近系沙河街组三段中亚段层序由湖进体系域和湖退体系域组成,湖进体系域为构造主控,相对湖平面和可容空间在盆地统一增加;湖退体系域沉积物供给的影响比较明显,可容空间在盆地缓坡中部和陡坡中部不变,形成可容空间转换带,该带外侧可容空间减小,内侧可容空间增加。     

东濮凹陷古近系沙三段、沙四段介形类生物地层及界线

根据十余口探井微体古生物分析结果和对多年来积累的大量微体古生物分析资料的复查 ,将东濮凹陷古近系沙河街三段 (ES3)和四段 (ES4 )的介形类化石群自下而上分为 3个组合和 3个亚组合 :Cyprinotus igneus组合 ,分布于沙四段下亚段 ;Cyprinotus altilis- Cyprinotus jiyangensis组合 ,分布于沙四段上亚段 ;H uabeinia sinensis组合 ,分布于沙三段 ,其中 H uabeinia obscura- H uabeinia costatispinata亚组合分布于沙三段下亚段 ,H uabeiniasinensis- Candona binxianensis亚组合分布于沙三段中亚段 ,H uabeinia huidongensis- Cyprinotus dongmingensis亚组合分布于沙三段上亚段。各化石组合特征比较清楚 ,为东濮凹陷沙三段、沙四段的划分以及与渤海沿岸盆地的对比提供了依据。虽然东濮凹陷缺少渤海沿岸盆地沙四段顶界的标志性化石 Austrocypris,但该区沙三段、沙四段介形类化石组合整体面貌与整个渤海沿岸盆地相比仍然具有可对比性 ,从介形类化石组合方面来确定本区沙三段、沙四段的界线仍然是可行的     

Application of Gravitational Methods to Prospecting Salt(Potash) Rocks in the Kuqa Depression

正The Kuqa depression deposited thick rock salt,which has a lower density than surrounding rocks.When salt bodies form a certain scale,obvious negative gravity anomalies can be detected in the surface.Therefore,gravitational method can quickly obtain the shape,plane distribution of deep-seated salt bodies and overall tectonic morphology of the basin.     

济阳坳陷沾化凹陷罗家地区古近系沙河街组页岩储集特征分析*

利用岩石薄片和扫描电镜分析等测试技术, 可以将济阳坳陷罗家地区古近系沙河街组页岩段储集空间分为孔隙和裂缝两大类。孔隙又可以分为黏土矿物晶间孔、碳酸盐矿物晶间孔、黄铁矿晶间微孔、碎屑颗粒溶孔和砂质粒间微孔5个亚类;裂缝分为成岩裂缝和构造裂缝两大类, 成岩裂缝又可以分为层间裂缝和粒缘裂缝两类。裂缝与基质孔隙之间, 存在一个微米尺度的重合带, 反映了储集空间发育继承性的特点, 油气聚集在以层间裂缝为中心, 粒缘裂缝等次级裂缝和较大的碳酸盐晶间孔为骨架, 以各类晶间孔隙、黏土微孔和溶蚀孔隙为基质的储集空间网络中。储集空间发育与岩性关系密切, 纹层状泥质灰岩物性较好, 相应的页岩物性具有基质渗透率极低和裂缝导流能力较强的特点。     

渤海湾盆地济阳拗陷沙三段页岩气地质条件分析

沙河街组三段的湖相富有机质泥页岩是济阳拗陷常规油气的主力烃源岩,也是该拗陷页岩气勘探的重点研究层系.分析沙三段暗色泥页岩的地球化学指标、页岩储层特征、含气性等,探讨济阳拗陷沙河街组湖相泥页岩形成页岩气的地质条件.结果表明:沙河街组湖相泥页岩沉积厚度大,平均大于200m;有机碳含量高,干酪根类型好,以Ⅰ型为主,Ⅱ1和Ⅱ2为辅;成熟度以成熟—高熟为主,与美国产气页岩和中国南方上扬子地区海相富有机质页岩地球化学特征具有可比性.湖相泥页岩脆性矿物质量分数高,石英与碳酸盐岩所占比例大,黏土矿物质量分数为10%～30%,页岩储层裂缝类型多样.由于砂泥岩互层频繁,粉砂或砂质夹层孔隙可以有效改善页岩储层储集性能,为页岩气提供有效的储集空间.泥页岩层段气测显示异常,指示其良好的含气性.沙三段富有机质泥页岩是济阳拗陷页岩气勘探的优选层系,具有良好的页岩气勘探潜力.     

松辽盆地徐家围子断陷深层异常高孔带分布特征与成因分析

为了解松辽盆地低孔低渗背景下优质储集层的形成和分布,文中应用岩心实测孔隙度、测井孔隙 度以及铸体薄片等资料,研究了松辽盆地徐家围子断陷异常高孔带的分布特征及其成因。结果表明,松辽盆地 北部纵向上发育3个异常高孔带（ⅰ-ⅲ）, 其深度分布范围分别为600~2350m、2500~3500m、3600~4400m,对应的孔隙度分别为12%~35%,6%~28%,5%~20%。第ⅰ高孔带主要发育在中浅层, 主要由Ⅰ、 Ⅱ型干酪根形成的有机酸溶蚀砂岩储集层形成;第ⅱ、ⅲ异常高孔带发育在深层,主要由Ⅲ型干酪根产生的大 量有机酸溶蚀砂砾岩储集层和火山岩储集层形成,大气水淋滤作用也有一定贡献。此外,裂缝和岩相对徐家围 子断陷深层异常高孔带的形成具有特别重要的意义。     

Urban locations and Black Metropolis resilience in the Great Depression

Motivated by theoretical arguments about ethnicity and economics and by historical research on urban black communities in the United States, this paper investigates the resilience of the early twentieth-century Black Metropolis. The study tests hypotheses about changes during the Great Depression (1930–1940) in the advantages of various cities as locations of black communities’ ethnic economies, analyzing Census data on blacks’ representation in occupations reflecting the Black Metropolis’s professional, entrepreneurial, and cultural media pursuits. There is mixed support for the hypothesis that the nationally dominant urban centers of New York, Chicago, and Philadelphia had the most resilient Black Metropolises, a finding that casts doubt on claims that black communities in such key places enjoyed exceptionally favorable locational advantages. Yet, the results support the hypothesis that northern cities were, overall, more resilient locations than southern cities, particularly for black professionals and entrepreneurs, affirming the argument that the urban North’s Black Metropolises were vital economic opportunity centers for these black communities’ upper- and middle-classes.     

锑矿石化学物相分析方法选择性分离条件验证及准确度评估

目前我国矿石化学物相分析方法,除少数方法具有较广泛的适应性外,多数方法均是针对某一具体矿区的样品而制定,在实际应用中无法确认分析结果的准确性和选择性分离流程的适应范围。验证化学物相分析方法的选择性分离流程及方法准确度是该领域必须解决的问题。本文以我国具有代表性的锑矿类型——单锑硫化矿为研究对象,通过岩矿鉴定确定锑的主要矿物相,从试验样品中挑选验证选择分离条件所需的单矿物,在无法获得锑华单矿物的情况下,通过价态分析确定了锑华与锑酸盐混合物中锑华的比例,并通过系列单矿物选择分离对比条件试验和X射线衍射分析,确定了锑华、辉锑矿和锑酸盐等锑物相的选择性分离条件。结果表明:对于硫化锑含量大于35%的样品,锑硫化相的选择浸出时间从传统的30 min调整为40 min,硫化锑的浸出率提高了4%~6%,硫化锑相对于锑酸盐的串相率降低了45%~70%,硫化锑相浸出完全,提高了硫化锑和黄锑矿相分析的准确度。该方法适用于不同地区、不同类型(氧化矿、硫化矿)锑矿石样品的锑化学物相分析。