贵州古风化壳沉积型铝土矿的沉积方式和成矿作用

铝土矿沉积方式为胶体沉积及碎屑沉积,古红土化及沼泽化是形成铝土矿的主要成矿作用,地下潜水面以下200 m不是铝土矿深部找矿的红线。     

Comparison of Fused Glass Beads and Pressed Powder Pellets for the Quantitative Measurement of Al,Fe, Si and Ti in Bauxite by Laser‐Induced Breakdown Spectroscopy

Due to matrix interference and sample particle size effects, some of the most important and difficult issues in laser‐induced breakdown spectroscopy (LIBS) analysis are the calibration and quantitative measurement of a complex matrix. This study proposes the use of borate fusion as an alternative sample preparation procedure for the quantitative measurement of Al, Fe, Si and Ti in bauxite by LIBS. Analytical calibration curves were made using bauxite certified reference materials (CRM), and the precision and accuracy of the methods were evaluated by analysing an additional bauxite CRM, using two different approaches: pressed powder pellets and fused glass beads. The borate fusion method was the most suitable sample preparation technique, since particle size effects and matrix interference could be minimised, obtaining better linearity on the analytical calibration curves (r²), and more accurate and more precise results for bauxite analysis.     

中国铝土矿资源现状和潜力分析

按照矿床模型综合地质信息矿产预测方法,在中大比例尺勘探数据的基础上,全国各省分预测工作区对不同矿产预测类型分别按500m和1000m的预测深度,对全国铝土矿圈定成矿远景区,使用地质参数体积法估算潜在资源量。以此为基础,按照单位面积查明资源量及预测资源量定量统计,分析全国重要的铝土矿潜力区,为铝土矿找矿勘查部署提出参考建议。     

玻璃熔片制样X射线荧光光谱法测定矾土中主次量组分

建立了玻璃熔片-X射线荧光光谱测定进出口矾土中主、次量组分的分析方法,用可变α系数校正元素基体效应,同时进行谱线重叠校正。利用高纯化学试剂配制合成标准参考物质,球磨机混匀,熔融玻璃片法制备系列校准样片,用X射线荧光光谱法对样品中的二氧化硅、三氧化二铁、三氧化二铝、氧化钙、氧化镁、氧化钾、五氧化二磷、二氧化钛进行测定。方法回收率为98.1%~111.0%,经国家铝矾土标准物质GBW 07178、GBW 07179验证,结果与标准值基本一致。建立的方法解决了测试过程中标准样品种类和数量不足的难题。     

滇东南铝土矿床地球化学特征及成矿物质来源研究

滇东南地区铝土矿资源丰富。本文以滇东南沉积型铝土矿为对象,研究了铝土矿的地球化学特征,进而对其成矿物质来源进行了讨论。含铝岩系之中富含稀土元素、分散元素镓、黑色金属元素钛和稀土金属元素铌,均已达到工业开采要求。含铝岩系的稀土总量总体较高,但样品之间稀土总量差别较大;具中等程度的铕负异常;铈异常较为复杂,具铈正异常和铈负异常;稀土配分曲线均为向右倾斜的弱"V"字型曲线,斜率不等,反映稀土元素分馏程度不等;稀土配分曲线特征与下伏咸宁组灰岩的稀土曲线特征一致,说明含铝岩系与下伏威宁组灰岩关系密切。含铝岩系明显富集大离子亲石元素Li、U、高场强元素Nb、Ta、Zr、Hf、Th、过渡元素V、Cr、Ti和分散元素Ga,其余元素则明显亏损。野外观察发现含铝岩系直接在风化壳上沉积,含铝岩系具复杂的铈异常和中等的Th/U比值(3~7)、高的Sr/Ba比值(1)以及高钛率值(3.41~44.02)。这些特征说明滇东南铝土矿的成矿物质主要来源于下伏威宁组灰岩风化形成的风化壳,沉积作用起到了对风化壳上成矿物质的改造作用。     

贵州省三联铝土矿床地质特征及控矿因素浅析

贵州省三联铝土矿位于黔北隆起区,是近年在遵义-息烽铝土矿成矿区探明的小型矿床之一。通过系统分析该矿床的地质特征,查明控矿因素,总结了找矿标志,探讨了矿床成因。研究表明:①三联铝土矿含矿岩系为下石炭统九架炉组中下部,铝土矿呈层状产于上寒武统-下奥陶统娄山关组碳酸盐岩古侵蚀面之上,与上覆下石炭统上司组呈整合接触,矿床成因类型为古风化壳沉积型;②含矿岩系中元素Sr/Cu比值与化学蚀变指数(CIA)特征显示铝土矿主要形成于气候温暖、潮湿的陆相沉积环境;③矿石自然类型主要为豆鲕状、砾状结构,铝土矿物主要为一水硬铝石、三水铝石;④矿床的形成主要受地层岩性、背斜构造、古地貌、古气候等因素控制;⑤找矿标志:地层标志、岩性标志、古侵蚀间断面标志、褶皱构造标志等。     

Microgeomorphology and its control on the Early Carboniferous Tournaisian bauxite deposits in Longli area of Guizhou Province

In the Longli area of Guizhou,the Early Carboniferous Tournaisian “Fengyuan layer” bauxite was developed. In this paper,based on the geological boreholes,measured profiles and exploration geological point data in study area,the thickness of the aluminous rock series and the ore was calculated. The data of volume thickness,ore grade,and Al/Si ratio were used by Surfer⁸.0 mapping software and the method of microgeomorphology mapping to restore the paleogeomorphology of the Early Carboniferous Tournaisian aluminous rock series. Two paleokarst depressions were found in this area. Fengyuan layer bauxite was produced in paleokarst depressions along the Shuichang-Bimeng-Caoyuan-Gaopo area. Further research on microgeomorphology shows that the high-grade clastic and bean oolitic bauxite is located in the center of paleokarst depressions,while the low-grade dense bauxite is distributed in the center and margin. The paleogeographic research shows that the formation environment of bauxite aluminous rock series in the Fengyuan strata of the Early Carboniferous Tournaisian is a continent-marine transitional facies,including continental facies,paleokarst depression facies and marine facies from north to south. The karst bottomland provides a favorable depositional site for the formation of Fengyuan layer bauxite.     

桂西铝土矿中火山灰特征及其地质意义

岩溶型铝土矿中火山物质参与成矿的直接证据需要进一步明确。通过线路调查和剖面研究，在桂西大范围内的铝土矿及其早期的铝土质岩中观察到大量的火山灰，含量大于30%；火山灰种类有岩屑、晶屑、玻屑和火山尘，塑性—半塑性变形及刚性爆裂显著，自由降落为主，属原地—准原地沉积；火山灰易于分解为水铝石、高岭石、赤铁矿等微细矿物，屑状火山灰相对尘状火山灰更易于矿化，大量火山灰主要以直接铝土矿化作用成矿。元素地球化学特征显示铝土矿和铝土质岩具有亲岩浆性，不活动元素图解判别及铝土矿测年数据显示火山灰原岩浆以碱性玄武岩为主，与岛弧火山岩一致，主要来自于哀牢山—松马造山带的二叠纪岛弧，铝土矿层具有穿时性，部分火山灰可来源于峨眉山火成岩。铝土矿层中的火山灰丰富，跨度长，可能是瓜德鲁普统末生物灭绝的肇凶。     

桂西铝土矿中火山灰特征及其地质意义

岩溶型铝土矿中火山物质参与成矿的直接证据需要进一步明确。通过线路调查和剖面研究，在桂西大范围内的铝土矿及其早期的铝土质岩中观察到大量的火山灰，含量大于30%；火山灰种类有岩屑、晶屑、玻屑和火山尘，塑性—半塑性变形及刚性爆裂显著，自由降落为主，属原地—准原地沉积；火山灰易于分解为水铝石、高岭石、赤铁矿等微细矿物，屑状火山灰相对尘状火山灰更易于矿化，大量火山灰主要以直接铝土矿化作用成矿。元素地球化学特征显示铝土矿和铝土质岩具有亲岩浆性，不活动元素图解判别及铝土矿测年数据显示火山灰原岩浆以碱性玄武岩为主，与岛弧火山岩一致，主要来自于哀牢山—松马造山带的二叠纪岛弧，铝土矿层具有穿时性，部分火山灰可来源于峨眉山火成岩。铝土矿层中的火山灰丰富，跨度长，可能是瓜德鲁普世末生物灭绝的肇凶。